Results of investigation of new-generation semicommercial arc plants for fullerene production are described. Increase in the operating efficiency of the plants is attained through their modification, in particular, by using a system of two-sided gas feed. Increase in the electrode diameter and rise in the working pressure make it possible to organize fullerene synthesis with a substantially smaller carbon loss. A qualitative and calculated interpretation of the results is given.
Similar content being viewed by others
References
W. Kratchmer, L. D. Lamb, K. Fostiropoulos, and D. R. Huffman, Solid C60: a new form of carbon, Nature, 347, 354–359 (1990).
V. D. Shimanovich, I. P. Smyaglikov, and A. I. Zolotovskii, Arc discharge in synthesis of fullerenes, Inzh.-Fiz. Zh., 71, No. 4, 669–674 (1998).
A. Goel, P. Hebgen, and J. B. Vander, Combustion synthesis of fullerenes and fullerenic nanostructures, Carbon, 40, No. 2, 177–182 (2002).
R. P. Rodgers, P. T. Reilly, W. B. Whitten, and J. M. Ramsey, Soot-free synthesis of C60, Carbon, 41, No. 4, 687–692 (2003).
D. V. Afanas’ev, I. O. Blinov, A. A. Bogdanov, G. A. Dyuzhev, V. I. Karataev, and A. A. Kruglikov, Formation of fullerenes in an arc discharge, Zh. Tekh. Fiz., 64, Issue 10, 76–85 (1994).
D. V. Afanas’ev, A. A. Bogdanov, G. A. Dyuzhev, V. I. Karataev, and A. A. Kruglikov, Formation of fullerenes in an arc discharge. II, Zh. Tekh. Fiz., 67, Issue 2, 125–132 (1997).
D. V. Afanas’ev, G. A. Dyuzhev, and A. A. Kruglikov, Carbon flows from a gas discharge in regimes optimal for obtaining fullerenes, Zh. Tekh. Fiz., 71, Issue 5, 134–135 (2001).
D. V. Afanas’ev, G. A. Dyuzhev, and A. A. Kruglikov, Influence of gas flows on the process of the formation of fullerenes, Zh. Tekh. Fiz., 71, Issue 7, 137–139 (2001).
N. I. Alekseev and G. A. Dyuzhev, Statistical model of the formation of fullerenes on the basis of quantumchemical calculations. II. Substantiation of the model and the kinetics of transformation into a fullerene, Zh. Tekh. Fiz., 71, Issue 5, 71–76 (2001).
N. I. Alekseev and G. A. Dyuzhev, Arc discharge with an evaporating anode (Why does the kind of a buffer gas influence the formation of fullerenes?), Zh. Tekh. Fiz., 71, Issue 10, 41–50 (2001).
N. I. Alekseev and G. A. Dyuzhev, Kinetics of carbon clusters in an arc discharge from atoms to fullerenes, Zh. Tekh. Fiz., 72, Issue 5, 121–129 (2002).
N. I. Alekseev and G. A. Dyuzhev, Calculation of a gas-plasma jet formed by an arc in the arc method of production of fullerenes, Zh. Tekh. Fiz., 75, Issue 11, 32–39 (2005).
N. I. Alekseev and G. A. Dyuzhev, Influence of the discharge chamber geometry on the efficiency of the arc technique of production of fullerenes. I. Axisymmetric case, Zh. Tekh. Fiz., 75, Issue 12, 16–25 (2005).
N. I. Alekseev and G. A. Dyuzhev, Influence of the discharge chamber geometry on the efficiency of the arc technique of production of fullerenes. II. Two-sided supply of a gas and consideration of the three-dimensional geometry, Zh. Tekh. Fiz., 75, Issue 12, 26–32 (2005).
G. A. Dyuzhev and V. I. Karataev, Where are the fullerenes formed in an arc discharge?, Fiz. Tverd. Tela, 34, Issue 9, 2795–2799 (1994).
G. A. Dyuzev, I. V. Basargin, B. M. Filippov, N. I. Alekseyev, and A. A. Bogdanov, Patent 7153398 USA, MPK C01B31/00. WO02/RU02/00083. Method for producing fullerene-containing carbon and device for carrying out the method, Published 26.12.2006.
A. G. Ryabenko, Mechanisms of Formation and Interaction of Carbon Nanoclusters, Doctoral Dissertation (in Physics and Mathematics), Chernogolovka (2008).
N. I. Alekseev, F. Chibante, and G. A. Dyuzhev, On the transformation of a carbon vapor in the gas jet of an arc discharge, Zh. Tekh. Fiz., 71, Issue 6, 122–130 (2001).
G. N. Abramovich, Theory of Turbulent Jets [in Russian], Nauka, Moscow (1984).
G. I. Sukhinin and I. A. Nerushev, The mechanism underlying the formation of fullerenes in carbon vapor, Prikl. Mekh. Tekh. Fiz., 38, No. 4, 140–154 (1997).
S. Ramakroshnan, A. D. Stokes, and J. J. Lowke, An approximate model for high-current free burning arc, J. Phys. D.: Appl. Phys., 11, 2267–2280 (1978).
J. O. Hirschfelder, Ch. F. Curtiss, and R. B. Bird, Molecular Theory of Gases and Liquids [Russian translation], IL, Moscow (1961).
N. I. Alekseyev and N. A. Charykov, Mechanism of selection of perfect fullerenes in arc synthesis, Russ. J. Phys. Chem., 82, No. 13, 18–26 (2008).
Author information
Authors and Affiliations
Corresponding author
Additional information
Translated from Inzhenerno-Fizicheskii Zhurnal, Vol. 84, No. 5, pp. 1008–1018, September–October, 2011.
Rights and permissions
About this article
Cite this article
Alekseev, N.I., Filippov, B.M., Basargin, I.V. et al. Investigation of semicommercial arc plants for fullerene-production. J Eng Phys Thermophy 84, 1087–1098 (2011). https://doi.org/10.1007/s10891-011-0570-0
Received:
Revised:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10891-011-0570-0