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A Novel Zeotype Vanadoarsenate [NH4VO(AsO4)]n with ETS-10-like Topological Framework

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Abstract

A ETS-10-like topological vanadoarsenate [NH4VO(AsO4)]n 1 has been hydrothermally synthesized and structurally characterized by X-ray diffraction. The molecule structural analysis reveals that 1 is constructed by helical [–V–O–]n chains and AsO4 tetrahedra. Crystal data for 1: Orthorhombic, with space group Pnna, a = 13.212(3) Å, b = 10.753(2) Å, c = 6.6266(13) Å, V = 941.4(3) Å3, Z = 8, R1 = 0.0515 and wR2 = 0.1144.

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Acknowledgements

This work was supported by Chongqing Basic and Frontier Research Project (cstc2016jcyjA0256), Chongqing Education Commission Science and Technology Research Project (KJ1400919), and National Natural Research Program of China (21406023).

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Authors and Affiliations

  1. College of Chemistry and Chemical Engineering, Chongqing University of Technology, Chongqing, 400054, People’s Republic of China

    Guangpeng Zhou, Xuebu Hu, Guiying Xu & Bingying Jiang

  2. Jiulongpo Vocational Education Center, Chongqing, 401329, People’s Republic of China

    Hui Li

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  1. Guangpeng Zhou
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Correspondence to Guangpeng Zhou.

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Zhou, G., Hu, X., Xu, G. et al. A Novel Zeotype Vanadoarsenate [NH4VO(AsO4)]n with ETS-10-like Topological Framework. J Clust Sci 29, 15–20 (2018). https://doi.org/10.1007/s10876-017-1315-9

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  • DOI: https://doi.org/10.1007/s10876-017-1315-9

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