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Crystal Structure of Cs4[{(C6H6)Ru}2Nb6O19]·8MeOH·2H2O. Structural Overview of Hybrid Organometallic Hexametalates of Niobium and Tantalum: Alkali Metal Coordination Behavior

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Abstract

Reaction of Cs8[Nb6O19]·14H2O with [(C6H6)RuCl2]2 leads to the formation of trans-[{(C6H6)Ru}2Nb6O19]4− (1). Evaporation of the reaction solution and extraction into methanol (MeOH) yielded Cs4[{(C6H6)Ru}2Nb6O19]·8MeOH·2H2O (1a) as main product together with a small amount of Cs4[{(C6H6)Ru}2Nb6O19]·4MeOH·6H2O (1b), both characterized by X-ray analysis. These structures complete a set of known organometallic polyoxoniobate or polyoxotantalate complexes [{Cp*M′}xM6O19]n− and [{(C6H6)Ru}xM6O19]n− (M = Nb, Ta; M′ = Rh, Ir; x = 1, 2; n = 6, 4; Cp* = η5-C5(CH3)5) and give additional information about the importance of cation–anion interactions in the crystal structures of such complexes.

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Acknowledgements

The reported study was supported by Russian Science Foundation, Grant No. 14-13-00645.

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Authors and Affiliations

  1. Nikolaev Institute of Inorganic Chemistry SB RAS, 3 Akad. Lavrentieva Ave, 630090, Novosibirsk, Russia

    Pavel A. Abramov, Tatiana P. Zemerova & Maxim N. Sokolov

  2. Novosibirsk State University, ul. Pirogova 2, 630090, Novosibirsk, Russia

    Pavel A. Abramov, Tatiana P. Zemerova & Maxim N. Sokolov

  3. Kazan Federal University, 18 ul. Kremlyovskaya, 420008, Kazan, Russia

    Maxim N. Sokolov

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  1. Pavel A. Abramov
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  2. Tatiana P. Zemerova
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  3. Maxim N. Sokolov
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Correspondence to Pavel A. Abramov.

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Abramov, P.A., Zemerova, T.P. & Sokolov, M.N. Crystal Structure of Cs4[{(C6H6)Ru}2Nb6O19]·8MeOH·2H2O. Structural Overview of Hybrid Organometallic Hexametalates of Niobium and Tantalum: Alkali Metal Coordination Behavior. J Clust Sci 28, 725–734 (2017). https://doi.org/10.1007/s10876-016-1116-6

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