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Synthesis, Crystal Structure, Vibrational and Optical Properties of (Hdea)4(V7O19F)∙0.42H2O, an Original (V7O19F)4− Cluster Oxyfluoride

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Abstract

Synthesis, crystal structure, IR and Raman spectroscopies and optical analysis are reported for a new fluorovanadate with organic cations (Hdea)4(V7O19F)∙0.42H2O (dea: diethylamine). The title compound crystallizes in orthorhombic system, space group P212121, a = 11.486 (5) Å, b = 14.779 (5) Å, c = 23.243 (5) Å, Z = 4, V = 3,946 (2) Å3, R = 0.025 with 6,936 reflections. The atomic arrangement can be described as an alternation of inorganic and organic layers. The anionic layer is built up of original clusters (V7O19F)4− which are composed of three VO5F octahedra and four VO4 tetrahedra combined via shared edges and corners. The cohesion between the fluorovanadate groups, organic cations and water molecules is provided by a network hydrogen-bonding. The IR and Raman spectra exhibit characteristic bands of all groups present in the structure. The optical band gap is determined to be 2.5 eV by UV–Vis-T90+ diffuse reflectance spectra, which revealed the nature of semiconductor.

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Acknowledgments

The crystal data collection of the title compound was done in the “Department of Chemistry, Faculty of Sciences of Sfax, University of Sfax, BP 1171, 3038 Sfax, Tunisia”. We are grateful to Abdelhamid Ben Salah who supervised this experiment.

The spectrum Raman was done in “Laboratory of ferroelectric materials, Faculty of Sciences of Sfax, University of Sfax, BP 1171, 3038 Sfax, Tunisia. We grateful to Hamadi Khemkhem who supervised this experiment.

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Authors and Affiliations

  1. Laboratoire physico-chimie de l’état solide, Faculté de Sciences, Université de Sfax, BP 1171, 3038, Sfax, Tunisia

    Issam Omri & Tahar Mhiri

  2. Laboratoire de Matériaux et Cristallochimie, Faculté des Sciences, Université de Tunis El Manar, El Manar, 2092, Tunis, Tunisia

    Mohsen Graia

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  1. Issam Omri
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Correspondence to Issam Omri.

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Omri, I., Graia, M. & Mhiri, T. Synthesis, Crystal Structure, Vibrational and Optical Properties of (Hdea)4(V7O19F)∙0.42H2O, an Original (V7O19F)4− Cluster Oxyfluoride. J Clust Sci 26, 815–825 (2015). https://doi.org/10.1007/s10876-014-0768-3

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