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Synthesis and Structural Characterization of Isomers of Ru-Substituted Keggin-Type Germanotungstate with dmso Ligand

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Abstract

We found that three isomers of mono-Ru substituted Keggin-type germanotungstate with a dmso ligand, [GeW11O39RuII(dmso)]6−, could be formed by a reaction of α-Keggin-type mono-lacunary germanotungstate, [α-GeW11O39]8−, with Ru(dmso)4Cl2. The main isomer is an α-isomer, and the others are β2-isomer and β3-isomer, which were confirmed by 1H NMR, cyclic voltammetry, IR, and single crystal X-ray structure analysis.

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Acknowledgments

This research was supported by the JST, PRESTO program.

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Authors and Affiliations

  1. Department of Applied Chemistry, Graduate School of Engineering, Hiroshima University, 1-4-1 Kagamiyama, Higashi-Hiroshima, 739-8527, Japan

    Noriko Shimizu, Tsuneji Sano & Masahiro Sadakane

  2. PRESTO, Japan Science and Technology Agency (JST), 4-1-8 Honcho, Kawaguchi, Saitama, 332-0012, Japan

    Masahiro Sadakane

  3. Department of Chemistry and Materials Science, Tokyo Institute of Technology, 2-12-1, O-okayama, Meguro-ku, Tokyo, 152-8551, Japan

    Tomoji Ozeki & Hideyasu Shikama

Authors
  1. Noriko Shimizu
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  2. Tomoji Ozeki
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  3. Hideyasu Shikama
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  4. Tsuneji Sano
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  5. Masahiro Sadakane
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Correspondence to Masahiro Sadakane.

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Shimizu, N., Ozeki, T., Shikama, H. et al. Synthesis and Structural Characterization of Isomers of Ru-Substituted Keggin-Type Germanotungstate with dmso Ligand. J Clust Sci 25, 755–770 (2014). https://doi.org/10.1007/s10876-013-0641-9

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