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Synthesis and Structures of Silver(I) and Copper(I) 3,5-Dipentyl-1,2,4-Triazolates

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Abstract

The Ag(I) and Cu(I) complexes of 4-amino-3,5-dipentyl-4H-1,2,4-triazole (4-NH2-3,5-(C5H11)2tz) and 3,5-dipentyl-1H-1,2,4-triazole (3,5-(C5H11)2tzH) have been synthesized and characterized. X-Ray analysis shows that {Ag4[4-NH2-3,5-(C5H11)2tz]6}(BF4)4 is a tetranuclear complex featuring an Ag4tz6 cluster; {Ag[3,5-(C5H11)2tz]}n exhibits a 3D structure of lvt-a topology; and {Cu2[3,5-(C5H11)2tz]Br}n is a Cu4Br4-cluster based 3D complex with the dia topology.

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Acknowledgments

This work has been supported by the NSF of China (No. 21071126 and No. J0830412) and a research grant for undergraduate students of Zhengzhou University.

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Authors and Affiliations

  1. Department of Chemistry, Zhengzhou University, Zhengzhou, 450001, China

    Wen-Hua Zhang, Ya-Wei Li & Guang Yang

  2. The Centre of Supervision and Inspection of Quality and Technique at Sanmenxia, Sanmenxia, 472000, China

    Yong-Hui Wang

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  1. Wen-Hua Zhang
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  2. Yong-Hui Wang
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  4. Guang Yang
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Correspondence to Guang Yang.

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Zhang, WH., Wang, YH., Li, YW. et al. Synthesis and Structures of Silver(I) and Copper(I) 3,5-Dipentyl-1,2,4-Triazolates. J Clust Sci 23, 411–420 (2012). https://doi.org/10.1007/s10876-012-0445-3

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