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Synthesis, Crystal Structure and Circular Dichroism Property of a Homochiral Ni-MOF Based on D-Camphorate-Derived Enantiopure Ligand

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Abstract

A homochiral metal-organic framework, [Ni(D-L)(py)2(H2O)2]n (1) [D-H2L = 4,4′-[[(1R,3S)-1,2,2-trimethylcyclopentane-1,3-dicarbonyl]bis-(azanediyl)]dibenzoic acid], has been successfully synthesized based on D-camphorate-derived enantiopure ligand. 1 was characterized by single-crystal X-ray diffraction (SCXRD), powder X-ray diffraction (PXRD), Fourier transform infrared spectral analysis (FTIR), thermogravimetric analysis (TGA) and the circular dichroism (CD) spectrum. The experimental results show that 1 features a homochiral triple helix and is formed a 3D supramolecular framework by supramolecular interactions. In addition, the circular dichroism (CD) spectrum verifies the chirality introduction from the ligand to crystal. The successful preparation of the homochiral Ni-MOF provides more possibilities of employing the chiral ligand to produce various chiral MOFs.

Graphical Abstract

A homochiral Ni(II)-MOF 1 was prepared by using D-camphorate-derived enantiopure ligand under solvothermal condition, in which the chirality of 1 was confirmed by the circular dichroism (CD) spectrum

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Data Availability

CCDC 2272233 contains supplementary crystallographic data for complex 1. The data can be obtained free of charge via http://www.ccdc.cam.ac.Uk/deposit, or from the Cambridge Crystallographic Data Centre, 12 Union Road, Cambambridge CB2 1EZ, UK; fax: (+ 44) 1223-336-033; or e-mail: deposit@ccdc.cam.ac.uk

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Acknowledgements

This work was supported by the National Natural Science Foundation of China (Grant no. 21771096).

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Authors and Affiliations

  1. College of Chemistry and Chemical Engineering, Liaocheng University, Liaocheng, 252059, China

    Mengying Liu, Yang Shi & Qingfu Zhang

  2. Key Laboratory of Evidence Identification in Universities of Shandong Province, Shandong University of Political Science and Law, Jinan, Shandong, 250014, China

    Mingyuan Lei

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  1. Mengying Liu
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  2. Mingyuan Lei
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  3. Yang Shi
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  4. Qingfu Zhang
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Contributions

Conceptualization: Mingyuan Lei; synthesis and characterization: Mengying Liu; analysis: Yang Shi; writing-original draft preparation: Mengying Liu; writing-review and editing: Mengying Liu and Mingyuan Lei; supervision and funding acquisition: Qingfu Zhang.

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Correspondence to Mingyuan Lei or Qingfu Zhang.

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Liu, M., Lei, M., Shi, Y. et al. Synthesis, Crystal Structure and Circular Dichroism Property of a Homochiral Ni-MOF Based on D-Camphorate-Derived Enantiopure Ligand. J Chem Crystallogr (2024). https://doi.org/10.1007/s10870-024-01017-2

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