Abstract
A novel 3,4,7,8-tetrachloro-1,10-phenanthroline (Cl4phen) Zn(II) complex has been synthesized. The complex, [Zn(Cl4phen)2(H2O)2](NO3)2·CH3CH2OH (1), has been identified and characterized by single crystal X-ray diffraction, elemental analysis, FT-IR, thermogravimetric analysis and photoluminescence studies. Single crystal X-ray diffraction analysis reveals that complex (1) belongs to the monoclinic system, space group P2(1)/c, a = 10.061(2) Å, b = 18.924(4) Å, c = 18.189(4) Å, β = 100.94(3)°, and Z = 4. Complex (1) consists of cationic species [Zn(Cl4phen)2(H2O)2]2+, NO3 − and CH3CH2OH. The zinc atom displays a distorted cis-N4O2 octahedral geometry. Via extended Zn–O–H···O–N–O···H–O–Zn bridge, every mononuclear unit is linked with other ones to form one-dimensional (1D) infinite chain of hydrogen bond system. Three-dimensional (3D) polymeric network arrangement was built via weak C–H···O and π-stacking interactions between Cl4phen moieties. A solvent-dependency effect of complex (1) was observed in spectroscopic properties.
Graphical Abstract
Three-dimensional (3D) polymeric network arrangement was built via weak C–H···O and π-stacking interactions between Cl4phen moieties.
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Li ZQ, Wu FJ, Gong Y, Hu CW, Zhang YH, Gan MY (2007) Chin J Chem 25:1809
d’Angelo J, Morgant G, Ghermani NE, Desmaele D, Fraisse B, Bonhomme F, Dichi E, Sghaier M, Li Y, Journaux Y, Sorenson JRJ (2008) Polyhedron 27:537
Kovala-Demertzi D, Yadav PN, Wiecek J, Skoulika S, Varadinova T, Demertzis MA (2006) J Inorg Biochem 100:1558
Travnicek Z, Krystof V, Sipl M (2006) J Inorg Biochem 100:214
Casas JS, Castellano EE, Couce MD, Ellena J, Sanchez A, Sordo J, Taboada C (2006) J Inorg Biochem 100:124
Di Vaira M, Bazzicalupi C, Orioli P, Messori L, Bruni B, Zatta P (2004) Inorg Chem 43:3795
Tarushi A, Psomas G, Raptopoulou CP, Kessissoglou DP (2009) J Inorg Biochem 103:898
Chen L, Qiao J, Xie JF, Duan L, Zhang DQ, Wang LD, Qiu Y (2009) Inorg Chim Acta 362:2327
Ngan TW, Ko CC, Zhu NY, Yam WW (2007) Inorg Chem 46:1144
Klein A, Kaim W, Waldhör E, Hausen HD (1995) J Chem Soc Perkin Trans 2:2121
Ernst S, Vogler C, Klein A, Kaim W, Zalis S (1996) Inorg Chem 35:1295
Joshi HS, Jamshidi R, Yitzhak T (1999) Angew Chem Int Ed 38:2721
Delaney S, Pascaly M, Bhattacharya PK, Han K, Barton JK (2002) Inorg Chem 41:1996
Titze C, Kaim W (1997) Inorg Chem 36:2505
Xu XX, Lu Y, Wang EB, Ma Y, Bai XL (2007) Inorg Chim Acta 360:455
Yamada MA, Nakamura Y, Hasegawa IA et al (1992) Bull Chem Soc Jpn 65:2007
Sheldrick GM (1997) SHELX-97 Structure Solution and Refinement Package. University of Gottingen, Germany
Arif M, Nazir S, Iqbal MS, Anjumc S (2009) Inorg Chim Acta 362:1624
Chen XF, Cheng P, Liu X, Zhao B, Liao DZ, Yan SP, Jiang ZH (2001) Inorg Chem 40:2652
Curtis NF, Curtis YM (1965) Inorg Chem 4:804
Schäfer B, Görls H, Meyer S, Henry W, Johannes GV, Rau S (2007) Eur J Inorg Chem 25:4056
Mahata P, Natarajan S (2005) Eur J Inorg Chem 11:2156
Zhang CG, Janiak C (2001) J Chem Cryst 31:29
George E, Kostakis NordlanderE, Hadjiliadis N, Haukka M, Plakatouras JC (2006) Inorg Chem Comm 9:915
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Zheng, CG., Qian, QL., Liu, YF. et al. Synthesis, Crystal Structure and Characterizations of New 3,4,7,8-Tetrachloro-1,10-Phenanthroline Zn(II) Complex. J Chem Crystallogr 40, 19–24 (2010). https://doi.org/10.1007/s10870-009-9598-9
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DOI: https://doi.org/10.1007/s10870-009-9598-9