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The crystal structure of 1-phenyl-3-methyl-4(salicylaldehyde hydrazone)-propenylidene-5-pyrazolone

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Abstract

The crystal structure of 1-phenyl-3-methyl-4-(salicylaldehyde hydrazone)-propenylidene-5-pyrazolone (PMPP-SH) was characterized by the single-crystal X-ray diffraction method. The cell parameters of PMPP-SH in the monoclinic P21/c space group are a = 10.851(1) Å, b = 11.679 (1) Å, c = 14.043 (2) Å and β = 91.89 (1)∘. Analyzing the molecular structure suggest that, in the solid state, the title compound exists mainly in enaminopyrazolone form, which is stabilized by intramolecular hydrogen bonding, rather than NH-form.

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Authors and Affiliations

  1. Institute of Applied Chemistry, Xinjiang University, Urumqi, 830046, People’s Republic of China

    Guangfei Liu, Lang Liu & Dianzeng Jia

  2. Chengdu Institute of Organic Chemistry, Chinese Academy of Sciences, Chengdu, 610041, People’s Republic of China

    Kaibei Yu

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  1. Guangfei Liu
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  2. Lang Liu
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  3. Dianzeng Jia
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  4. Kaibei Yu
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Correspondence to Dianzeng Jia.

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Liu, G., Liu, L., Jia, D. et al. The crystal structure of 1-phenyl-3-methyl-4(salicylaldehyde hydrazone)-propenylidene-5-pyrazolone. J Chem Crystallogr 35, 497–501 (2005). https://doi.org/10.1007/s10870-005-2443-x

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  • DOI: https://doi.org/10.1007/s10870-005-2443-x

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