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Transformation of corn cob waste into mesoporous carbon by template-free method and construction of TiO2-mesoporous carbon nanocomposite for MO dye degradation

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Abstract

In this investigation, transformation of agricultural corn cob waste into mesoporous carbon nanoparticles (MCNPS) by template-free method. This synthesized MCNPs are used for the construction of Titanium dioxide-Mesoporous carbon (TMC) nanocomposites by precipitation and calcination method. Synthesized samples were confirmed by various characterization techniques. The photocatalytic behavior of the TMC nanocomposites was checked by the degradation of Methyl Orange (MO) in the presence of UV light. The optimized TMC21 composite shows 92% degradation efficiency towards MO dye within 80 min under UV light than the bare TiO2 and also shows excellent stability and recyclability after five runs. The histo-toxicological studies are done by using freshwater Lobeo Rohita fish organs such as kidney and ovary. The results show that MO dye-containing solution damages the internal structure of kidney and ovary tissues whereas the photo-degraded product of MO dye exhibited no variations in their typical structure similar to the control group indicating that the MO-degraded solution is non-toxic.

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Acknowledgements

Author SBS is thankful to BARTI/ Fellowship/ BANRF-2018/19-20/3036.

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Authors and Affiliations

  1. Medicinal Material Research Laboratory, Department of Chemistry, Shivaji University, Kolhapur, Maharashtra, 416004, India

    Sachin B. Shinde, Sneha R. Bhosale, Alfredi A. Moyo & Prashant V. Anbhule

  2. Fluorescence Spectroscopy Research Laboratory, Department of Chemistry, Shivaji University, Kolhapur, Maharashtra, 416004, India

    Omkar S. Nille & Govind B. Kolekar

  3. Department of Chemistry, Balwant College, Vita, Maharashtra, 415311, India

    Anita B. Shinde

  4. Department of Zoology, Shivaji University, Kolhapur, Maharashtra, 416004, India

    Nagesh B. Birajdar

  5. Department of Chemistry, Yashwantrao Mohite College of Arts, Science and Commerce, Pune, Maharashtra, 411038, India

    Ajinkya D. Mandake

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  1. Sachin B. Shinde
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Contributions

SBS has prepared graphical abstract, investigation, and writing of the manuscript. OSN and GBK have provided Instrument facility. SRB has provided Instrument facility. ABS, AAM and ADM have provided characterization facility. NBB has provided cytotoxicity study. Conceptualization, formal analysis, and manuscript writing were reviewed under the guidance of PVA. All authors have seen and approved the final version of the manuscript being submitted. We warrant that the article is the authors’ original work, has not received prior publication, and is not under consideration for publication elsewhere.

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Correspondence to Prashant V. Anbhule.

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Shinde, S.B., Nille, O.S., Shinde, A.B. et al. Transformation of corn cob waste into mesoporous carbon by template-free method and construction of TiO2-mesoporous carbon nanocomposite for MO dye degradation. J Mater Sci: Mater Electron 35, 43 (2024). https://doi.org/10.1007/s10854-023-11687-x

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