Skip to main content
Log in

C-Dots dispersed nematic liquid crystal as tunable retarder

  • Published:
Journal of Materials Science: Materials in Electronics Aims and scope Submit manuscript

Abstract

In the present work, carbon quantum dot (C-Dots) has been dispersed in a nematic liquid crystal (NLC) in three different concentrations and NLC-QDs composites are prepared. Measurement of birefringence has been done with the help of Phase Modulation technique. Contrast ratio and threshold voltage have also been measured for pristine and doped NLC. Textures of pristine and NLC-QDs composites were studied using POM with exposure time of 100 ms. Dielectric studies of pristine as well as NLC-QDs composites with the variation of temperature and frequency have also been done. From these investigations we have observed an increase in dielectric permittivity and contrast ratio and decrease in birefringence and threshold voltage with the increasing concentration of QDs in LC. The birefringence of the pristine NLC has been measured which is found to be 0.19 which decreases for the NLC-QDs composites. Contrast ratio is also found to be increased with 12.5%, i.e., 97%, and threshold voltage has been decreased up to 0.2 V from 0.8 V for dispersed system. The outcomes of the studies are suitable for the liquid crystal displays and may also be useful in opto-electronic devices which require low birefringence, such as tunable retarder or variable waveplate.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8

Similar content being viewed by others

Data availability

The datasets generated and analyzed during the current study are available from the corresponding author on reasonable request.

References

  1. J.H. Deuling, Deformation of nematic liquid crystals in an electric field. Mol. Cryst. Liq. Cryst. 19, 123–131 (2007)

    Article  Google Scholar 

  2. C. Huang, C. Hu, H. Pan, K. Loi, Electrooptical responses of carbon nano-tube doped liquid crystal devices. Jpn. J. Appl. Phys. 44, 8077–8081 (2005)

    Article  CAS  Google Scholar 

  3. A.G. Chen, D.J. Brady, Real-time holography in azo-dye-doped liquid crystals. Opt. Lett. 17, 441–443 (1992)

    Article  CAS  Google Scholar 

  4. P. Blake, P.D. Brimicombe, R.R. Nair, T.J. Booth, D. Jiang, F. Schedin, L.A. Ponomarenko, S.V. Morozov, H.F. Gleeson, E.W. Hill, A.K. Geim, K.S. Novoselov, Graphene-based liquid crystal device. Nano Lett. 8, 1704–1708 (2008)

    Article  Google Scholar 

  5. M. Schadt, Nematic liquid crystals and twisted-nematic LCDs. Liq. Cryst. 2015, 1–7 (2015)

    Article  Google Scholar 

  6. C.J. Hsu, B.P. Singh, M. Antony, P. Selvaraj, R. Manohar, C.Y. Huang, Liquid crystal lens with doping of rutile titanium dioxide nanoparticles. Opt. Express 28, 22856–22866 (2020)

    Article  CAS  Google Scholar 

  7. B.P. Singh, G. Pathak, A. Roy, G. Hegde, P.K. Tripathi, A. Srivastava, R. Manohar, Investigation of dielectric and electro-optical properties of nematic liquid crystal with the suspension of biowaste-based porous carbon nanoparticles. Liq. Cryst. 2019, 1–12 (2019)

    Google Scholar 

  8. G. Yadav, M. Kumar, A. Srivastava, R. Manohar, SiO2 nanoparticles doped nematic liquid crystal system: an experimental investigation on optical and dielectric properties. Chin. J. Phys. 2018, 1 (2018)

    CAS  Google Scholar 

  9. G. Pathak, G. Hegde, V. Prasad, Octadecylamine-capped CdSe/ZnS quantum dot dispersed cholesteric liquid crystal for potential display application: investigation on photoluminescence and UV absorbance. Liq. Cryst. 2020, 1–9 (2020)

    Google Scholar 

  10. A.L. Rodarte, F. Cisneros, J.E. Hein, S. Ghosh, L.S. Hirst, Quantum dot/liquid crystal nanocomposites in photonic devices. Photonics 2015, 855–864 (2015)

    Article  Google Scholar 

  11. L.S. Hirst, J. Kirchhoffa, R. Inmana, S. Ghosha, Quantum dot self-assembly in liquid crystal media. Proc. SPIE 7618, 92–98 (2010)

    Google Scholar 

  12. R. Basu, G.S. Iannacchione, Evidence for directed self-assembly of quantum dots in a nematic liquid crystal. Phys. Rev. E 80, 1–4 (2009)

    Article  Google Scholar 

  13. M.M.S. Sanad, A.Y. Shenouda, Impact of sulphur-containing compounds on the electrochemical capabilities of spinel carbon-coated Sb2SnS4 nano-sheets as alternative anodes in lithium ion batteries. J. Mater. Sci. Mater. Electron. 32, 20489–20498 (2021)

    Article  CAS  Google Scholar 

  14. M.M.S. Sanad, M.H. El-Sadek, Porous niobium carbide as promising anode for high performance lithium-ions batteries via cost-effective processing. Diam. Relat. Mater. 121, 108722 (2022)

    Article  CAS  Google Scholar 

  15. F. Hamidouche, M.M.S. Sanad, Z. Ghebache, N. Boudieb, Effect of polymerization conditions on the physicochemical and electrochemical properties of SnO2/polypyrrole composites for supercapacitor applications. J. Mol. Struct. 1251, 131964 (2022)

    Article  CAS  Google Scholar 

  16. A. Rastogi, G. Hegde, T. Manohar, R. Manohar, Effect of oil palm leaf based carbon quantum dot on nematic liquid crystal and its electro-optical effects. Liq. Cryst. 2020, 1–20 (2020)

    Google Scholar 

  17. H. Eskalen, Influence of carbon quantum dots on electro-optical performance of nematic liquid crystal. Appl. Phys. A 126, 1–10 (2020)

    Article  Google Scholar 

  18. P. Mahesh, A. Shah, K. Swamynathan, D.P. Singh, R. Doualib, S. Kumar, Carbon dot-dispersed hexabutyloxytriphenylene discotic mesogens: structural, morphological and charge transport behavior. J. Mater. Chem. C 8, 9252–9261 (2020)

    Article  CAS  Google Scholar 

  19. P. Govind, Effect of nano particles fluorescent dye and polymers on the optical electro optical and dielectric parameters of liquid crystals (2019). http://hdl.handle.net/10603/272979

  20. G. Pathak, G. Hegde, V. Prasad, Investigation of electro-optical and dielectric properties of nematic liquid crystal dispersed with biowaste based porous carbon nanoparticles: Increased birefringence for display applications. J. Mol. Liq. 2020, 1–26 (2020)

    Google Scholar 

  21. C. Hsu, L. Lin, M. Huang, C. Huang, Electro-optical effect of gold nanoparticle dispersed in nematic liquid crystals. Crystals 287, 1–10 (2017)

    Google Scholar 

  22. A. Sharma, P. Malik, R. Dhar, P. Kumar, Improvement in electro-optical and dielectric characteristics of ZnO nanoparticles dispersed in a nematic liquid crystal mixture. Indian Acad. Sci 42, 1–9 (2019)

    Google Scholar 

Download references

Acknowledgements

The authors are thankful to APJ Abdul Kalam center for innovation and for providing the required experimental facilities. One of the author Govind Pathak is thankful to CSIR, New Delhi, India (File No. 09/0107(12335)/2021-EMR-I) for financial assistance in the form of Research Associate fellowship. Prof. Rajiv Manohar is thankful to the Science and Engineering Research Board (SERB) for providing the research grant with File No. CRG/2021/006430.

Funding

The authors have not disclosed any funding.

Author information

Authors and Affiliations

Authors

Contributions

KY contributed to writing of the original draft and formal analysis, GP contributed to methodology and visualization, SA contributed to acquisition of data, ST contributed to reviewing and editing of the manuscript, SK contributed to synthesis and characterization of Q-Dots, AS contributed to reviewing of the manuscript and supervision, RM contributed to guidance and resources.

Corresponding author

Correspondence to Rajiv Manohar.

Ethics declarations

Conflict of interest

The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper.

Additional information

Publisher's Note

Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.

Rights and permissions

Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Yadav, K., Pathak, G., Agarwal, S. et al. C-Dots dispersed nematic liquid crystal as tunable retarder. J Mater Sci: Mater Electron 34, 1978 (2023). https://doi.org/10.1007/s10854-023-11359-w

Download citation

  • Received:

  • Accepted:

  • Published:

  • DOI: https://doi.org/10.1007/s10854-023-11359-w

Navigation