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Structural and magnetic properties of Sr0.15Ca0.3La0.55Fe11.65-xCo0.35ZnxO19 ferrites synthesized through the ceramic process

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Abstract

In this study, Zn2+-substituted Sr0.15Ca0.3La0.55Fe11.65−xCo0.35ZnxO19 (0 ≤ x ≤ 0.15) ferrites were synthesized by the ceramic method. The effects of Zn2+ substitution on the structural and magnetic performance of samples were studied. The X-ray diffraction results show that ferrite samples with the high purity M-type phase can be obtained when the substitution amount of Zn2+ is x = 0–0.1. Further increasing the Zn content to x = 0.15, the impurity soft magnetic phase of ZnFe2O4 is detected, which harms the hard magnetic properties. The Mössbauer results show that Zn2+ ions enter the crystal lattice of the M-type phase and solely occupy the 4f1 site, thereby promoting the conversion of Fe2+ to Fe3+ at the 2a position. It is observed that the particle size of the sintered samples slightly increases as x increases from 0 to 0.1, but decreases when x = 0.15. Ultimately, we achieved an optimal magnetic performance with the highest maximum energy product of 5.75 MGOe, which is highly competitive within the ferrite family.

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Acknowledgements

This research is supported by the ten thousand talents project of Zhejiang Province (2019R52056).

Funding

This work was supported by ten thousand talents project of Zhejiang Province [2019R52056].

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All authors contributed to the study conception and design. Material preparation, data collection and analysis were performed by LY, ZY, ZZ, and HJ. The first draft of the manuscript was written by LY, and all authors commented on previous versions of the manuscript. All authors read and approved the final manuscript.

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Correspondence to Li Yuping.

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Yuping, L., Yujing, Z., Zhen, Z. et al. Structural and magnetic properties of Sr0.15Ca0.3La0.55Fe11.65-xCo0.35ZnxO19 ferrites synthesized through the ceramic process. J Mater Sci: Mater Electron 34, 1859 (2023). https://doi.org/10.1007/s10854-023-11317-6

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