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Fabrication methods of lead titanate glass ceramics and dielectric characteristics: a review

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Abstract

Lead titanate (PbTiO3) glass and glass ceramics (GCs) are technologically very useful materials that played significant role in various applications due to attractive optical and electrical properties. Based on its structural comparability with the perovskite barium titanate (BaTiO3) lattice, PbTiO3 was the first reported ferroelectric material in 1950. High Curie temperature (490 °C) exhibited by PbTiO3 has led to its utilization for high-temperature applications. The high molecular mass of lead also raises the density of the material, considering its mass of 207.2 g/mol, versus 40.08 g/mol for calcium. Thus, lead-based GCs also have an advantageous use to protect from the highly penetrating X-rays, γ-rays radiations, and high energy storage in barrier layer capacitors. Dielectric behavior of the GCs mainly depends on its doping with numerous oxides such as La2O3, Bi2O3, CrO3, Nb2O5, the heat treatment processes, and their respective soaking times. Herein, we report the different methods of the synthesis of PbTiO3 glass and GCs which showed distinct optical, structural, dielectric, and mechanical properties. Moreover, this review emphases on the past and recent dielectric characteristics of the various PbTiO3 glass ceramics.

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Acknowledgements

The authors are gratefully acknowledged all publishers for cited contributions of generous consent to highlight their previous work for academic purposes. One of the authors A.M. is also highly acknowledged and thankful to the Council of Scientific & Industrial Research (CSIR), New Delhi (India), for providing the financial aid underneath Senior Research Fellowship (SRF) no. 09/107(0380)/2016-EMR-I (Ack. No. 124250/2K15/1-EMR-I). C.R.G. also admiringly recognized the SERB-DST, New Delhi, for sanctioning the financial help (File No. EEQ/2018/000647) to complete this work.

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  1. Advanced Glass and Glass Ceramics Research Laboratory, Department of Physics, University of Lucknow, Lucknow, 226007, India

    Chandkiram Gautam

  2. Department of Physics, Babu Banarasi Das Group of Educational Institutions, Lucknow, 226028, India

    Abhishek Madheshiya

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Gautam, C., Madheshiya, A. Fabrication methods of lead titanate glass ceramics and dielectric characteristics: a review. J Mater Sci: Mater Electron 31, 12004–12025 (2020). https://doi.org/10.1007/s10854-020-03831-8

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