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Electrodeposited cobalt and nickel selenides as high-performance electrocatalytic materials for dye-sensitized solar cells

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Abstract

One-step electrodeposition technique is considered as an effective approach to synthesize selenides on various conductive substrates. Now, cobalt and nickel selenides (Co-Se and Ni-Se) have been successfully fabricated on fluorine-doped tin oxide (FTO) glass by using a potential reversal (PR) and potentiostatic (PS) electrodeposition techniques. The main difference between PR and PS techniques is the application of anodic electrodeposition bias, resulting in the distinguished difference of crystalline structure and electrocatalytic performance of Co-Se and Ni-Se. The morphology analysis indicates that Co-Se (Ni-Se) films are composed of Co-Se (Ni-Se) crystalline nanoparticles by PR technique, which is beneficial to supply the more electrocatalytic active sites for the I3− reduction. The as-fabricated Co-Se (Ni-Se) film by PR technique displays the higher electrocatalytic activity than the corresponding film by PS technique. Then, the Co-Se (Ni-Se) film is used as counter electrode (CE) of dye-sensitized solar cells (DSCs). The power conversion efficiency (PCE) of the DSC assembled from Co-Se (Ni-Se) CE by PR technique is up to 6.91% (6.68%), which is larger than those of DSC with platinum (Pt) CE (6.30%), Co-Se CE (5.84%) and Ni-Se CE (2.91%) by PS technique.

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References

  1. M. Freitag, J. Teuscher, Y. Saygili, X. Zhang, F. Giordano, P. Liska, J. Hua, S.M. Zakeeruddin, J.E. Moser, M. Grätzel, A. Hagfeldt, Dye-sensitized solar cells for efficient power generation under ambient lighting. Nat. Photon. 11, 372–378 (2017)

    Article  Google Scholar 

  2. Q.W. Tang, J. Wang, B. He, P. Yang, Can dye-sensitized solar cells generate electricity in the dark. Nano Energy 33, 266–271 (2017)

    Article  Google Scholar 

  3. F. Hao, P. Dong, Q. Luo, J. Li, J. Lou, H. Lin, Recent advances in alternative cathode materials for iodine-free dye-sensitized solar cells. Energy Environ. Sci. 6, 2003–2019 (2013)

    Article  Google Scholar 

  4. J. Han, H. Kim, D.Y. Kim, S.M. Jo, S.Y. Jang, Water-soluble polyelectrolyte-grafted multiwalled carbon nanotube thin films for efficient counter electrode of dye-sensitized solar cells. ACS Nano 4, 3503–3509 (2010)

    Article  Google Scholar 

  5. J. Gao, Y. Yang, Z. Zhang, J. Yan, Z. Lin, X. Guo, Bifacial quasi-solid-state dye-sensitized solar cells with poly (vinyl pyrrolidone)/polyaniline transparent counter electrode. Nano Energy 26, 123–130 (2016)

    Article  Google Scholar 

  6. M. Wu, X. Lin, Y. Wang, L. Wang, W. Guo, D. Qi, X. Peng, A. Hagfeldt, M. Gratzel, T.L. Ma, Economical Pt-free catalysts for counter electrodes of dye-sensitized solar cells. J. Am. Chem. Soc. 134, 3419–3428 (2012)

    Article  Google Scholar 

  7. G.R. Li, J. Song, G.L. Pan, X.P. Gao, Highly Pt-like electrocatalytic activity of transition metal nitrides for dye-sensitized solar cells. Energy Environ. Sci. 4, 1680–1683 (2011)

    Article  Google Scholar 

  8. Y. Hou, D. Wang, X.H. Yang, W.Q. Fang, B. Zhang, H.F. Wang, G.Z. Lu, P. Hu, H.J. Zhao, H.G. Yang, Rational screening low-cost counter electrodes for dye-sensitized solar cells. Nat. Commun. 4, 1583 (2013)

    Article  Google Scholar 

  9. S. Shukla, N.H. Loc, P.P. Boix, T.M. Koh, R.R. Prabhakar, H.K. Mulmudi, J. Zhang, S. Chen, C.F. Ng, C.H.A. Huan, N. Mathews, T. Sritharan, Q.H. Xiong, Iron pyrite thin film counter electrodes for dye-sensitized solar cells: high efficiency for iodine and cobalt redox electrolyte cells. ACS Nano 8, 10597–10605 (2014)

    Article  Google Scholar 

  10. I.A. Ji, H.M. Choi, J.H. Bang, Metal selenide films as the counter electrode in dye-sensitized solar cell. Mater. Lett. 123, 51–54 (2014)

    Article  Google Scholar 

  11. J. Wan, G.J. Fang, H. Yin, X. Liu, D. Liu, M. Zhao, W. Ke, H. Tao, Z. Tang, Pt–Ni alloy nanoparticles as superior counter electrodes for dye-sensitized solar cells: experimental and theoretical understanding. Adv. Mater. 26, 8101–8106 (2014)

    Article  Google Scholar 

  12. S. Anantharaj, S.R. Ede, K. Sakthikumar, K. Karthick, S. Mishra, S. Kundu, Recent trends and perspectives in electrochemical water splitting with an emphasis on sulfide, selenide, and phosphide catalysts of Fe, Co, and Ni: a review. ACS Catal. 6, 8069–8097 (2016)

    Article  Google Scholar 

  13. T. Liu, Y. Zhao, J. Duan, B. He, J. Zheng, Q.W. Tang, Transparent ternary alloy counter electrodes for high-efficiency bifacial dye-sensitized solar cells. Sol. Energy 170, 762–768 (2018)

    Article  Google Scholar 

  14. A. Sarkara, A.K. Chakraborty, S. Bera, NiS/rGO nanohybrid: an excellent counter electrode for dye sensitized solar cell. Sol. Energy Mater. Sol. Cells 182, 314–320 (2018)

    Article  Google Scholar 

  15. J. Huo, M. Zheng, Y. Tu, J. Wu, L. Hu, S. Dai, A high performance cobalt sulfide counter electrode for dye-sensitized solar cells. Electrochim. Acta 159, 166–173 (2015)

    Article  Google Scholar 

  16. X. Wang, Y. Xie, B. Bateer, K. Pan, X. Zhang, J. Wu, H.G. Fu, CoSe2/N-doped carbon hybrid derived form ZIF-67 as high-efficiency counter electrode for dye-sensitized solar cells. ACS Sustain. Chem. Eng. 7, 2784–2791 (2018)

    Article  Google Scholar 

  17. Z. Pang, Z. Chen, R. Wen, Y. Zhao, A. Wei, J. Liu, L. Tao, D. Luo, Y. Yang, Y. Xiao, Z. Xiao, J. Li, Colloidally synthesized MoSe2 nano-flowers anchored on three-dimensional porous reduced graphene oxide thin films as advanced counter electrode for dye-sensitized solar cells. J. Mater. Sci. Mater. Electron. 28, 15418–15422 (2017)

    Article  Google Scholar 

  18. Z. Pang, A. Wei, Y. Zhao, J. Liu, L. Tao, Y. Xiao, Y. Yang, D. Luo, Direct growth of Cu2ZnSnS4 on three-dimensional porous reduced graphene oxide thin films as counter electrode with high conductivity and excellent catalytic activity for dye-sensitized solar cells. J. Mater. Sci. 53, 2748–2757 (2018)

    Article  Google Scholar 

  19. H. Sun, L. Zhang, G. Zhou, Z.S. Wang, CoSe hollow spheres with dual functions for efficient dye-sensitized solar cells. Part. Part. Syst. Charact. 33, 729–733 (2016)

    Article  Google Scholar 

  20. X. Wang, Y. Xie, K. Pan, J. Wu, Y. Xiao, P. Yu, W. Zhou, H.G. Fu, Morphology effect of NiSe hierarchical microspheres on the performance of dye-sensitized solar cells. ACS Appl. Nano Mater. 1, 4900–4909 (2018)

    Article  Google Scholar 

  21. H. Yuan, Q. Jiao, J. Liu, X. Liu, Y. Li, D. Shi, Q. Wu, Y. Zhao, H. Li, Facile synthesis of Co0.85Se nanotubes/reduced graphene oxide nanocomposite as Pt-free counter electrode with enhanced electrocatalytic performance in dye-sensitized solar cells. Carbon 122, 381–388 (2017)

    Article  Google Scholar 

  22. Z. Zhang, S. Pang, H. Xu, Z. Yang, X. Zhang, Z. Liu, X. Wang, X. Zhou, S. Dong, X. Chen, L. Gu, G.L. Cui, Electrodeposition of nanostructured cobalt selenide films towards high performance counter electrodes in dye-sensitized solar cells. RSC Adv. 3, 16528–16533 (2013)

    Article  Google Scholar 

  23. Q.S. Jiang, R. Chen, X. Guo, Y. Zhu, W. Cheng, W. Li, X. Yang, H.C. Chen, Potentiostatic deposition of cobalt nickel selenides on FTO for advanced dye-sensitized solar cells. Sol. Energy 179, 59–66 (2019)

    Article  Google Scholar 

  24. H. Sun, D. Qin, S. Huang, X. Guo, D. Li, Y. Luo, Y. Meng, Dye-sensitized solar cells with NiS counter electrodes electrodeposited by a potential reversal technique. Energy Environ. Sci. 4, 2630–2637 (2011)

    Article  Google Scholar 

  25. Q.S. Jiang, J. Gao, L. Yi, G. Hu, J. Zhang, Enhanced performance of dye-sensitized solar cells based on P25/Ta2O5 composite films. Appl. Phys. A 122, 442 (2016)

    Article  Google Scholar 

  26. Z. Jin, M. Zhang, M. Wang, C. Feng, Z.S. Wang, Cobalt selenide hollow nanorods array with exceptionally high electrocatalytic activity for high-efficiency quasi-solid-state dye-sensitized solar cells. J. Power Sources 378, 475–482 (2018)

    Article  Google Scholar 

  27. X. Zhang, Y. Yang, S. Guo, F. Hu, L. Liu, Mesoporous Ni0.85Se nanospheres grown in situ on graphene with high performance in dye-sensitized solar cells. ACS Appl. Mater. Interfaces 7, 8457–8464 (2015)

    Article  Google Scholar 

  28. Y.H. Lee, Y.H. Yun, V.H.V. Quy, S.H. Kang, H. Kim, E. Vijayakumar, K.S. Ahn, Preparation of nickel selenide by pulsed-voltage electrodeposition and its application as a highly-efficient electrocatalyst at counter electrodes of quantum-dot sensitized solar cells. Electrochim. Acta 296, 364–371 (2019)

    Article  Google Scholar 

  29. Y. Duan, Q.W. Tang, B. He, R. Li, L. Yu, Transparent nickel selenide alloy counter electrodes for bifacial dye-sensitized solar cells exceeding 10% efficiency. Nanoscale 6, 12601–12608 (2014)

    Article  Google Scholar 

  30. Y. Duan, Q.W. Tang, J. Liu, B. He, L. Yu, Transparent metal selenide alloy counter electrodes for high-efficiency bifacial dye-sensitized solar cells. Angew. Chem. Int. Ed. 53, 1–7 (2014)

    Article  Google Scholar 

  31. K.J. Babu, T.R. Kumar, D.J. Yoo, S.M. Phang, G.G. Kumar, Electrodeposited nickel cobalt sulfide flowerlike architectures on disposable cellulose filter paper for enzyme-free glucose sensor applications. ACS Sustain. Chem. Eng. 6, 16982–16989 (2018)

    Article  Google Scholar 

  32. B. Yu, Y. Hu, F. Qi, X. Wang, B. Zheng, K. Liu, W. Zhang, Y. Li, Y. Chen, Nanocrystalline Ni0.85Se as efficient non-noble-metal electrocatalyst for hydrogen evolution reaction. Electrochim. Acta 242, 25–30 (2017)

    Article  Google Scholar 

  33. X. Wang, F. Li, W. Li, W. Gao, Y. Tang, R. Li, Hollow bimetallic cobalt-based selenide polyhedrons derived from metal-organic framework: an efficient bifunctional electrocatalyst for overall water splitting. J. Mater. Chem. A 5, 17982–17989 (2017)

    Article  Google Scholar 

  34. Q.S. Jiang, K. Pan, C.S. Lee, G. Hu, Y. Zhou, Cobalt-nickel based ternary selenides as high-efficiency counter electrode materials for dye-sensitized solar cells. Electrochim. Acta 235, 672–679 (2017)

    Article  Google Scholar 

  35. K. Liu, A. Wei, W. Zhang, Z. Xiao, Y. Zhao, J. Liu, Synthesis of vertically aligned CoS prismatic nanorods as counter electrodes for dye-sensitized solar cells. J. Mater. Sci. Mater. Electron. 30, 1541–1546 (2019)

    Article  Google Scholar 

  36. J. Jia, J. Wu, J. Dong, Q. Bao, L. Fan, J. Lin, L. Hu, S.Y. Dai, Influence of deposition voltage of cobalt diselenide preparation on the film quality and the performance of dye-sensitized solar cells. Sol. Energy 151, 61–67 (2017)

    Article  Google Scholar 

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Acknowledgements

This work was financially supported by National Natural Science Foundation of China (No. 61804062, 61801188, 61704063); Jiangsu provincial university natural science research major program, China (No. 17KJA510001); the Science Research Foundation of Huaiyin Institute of Technology (No.17HGZ003); Jiangsu Overseas Visiting Scholar Program for University Prominent Young & Middle-aged Teachers and Presidents.

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Authors and Affiliations

  1. Faculty of Electronic Information Engineering, Huaiyin Institute of Technology, Huai’an, 223003, China

    Qing-Song Jiang, Wenbo Li, Jing Wu, Wenjie Cheng, Jie Zhu, Zhengqing Yan, Xiaoyan Wang & Yongfeng Ju

  2. Jiangsu Engineering Laboratory for Lake Environment Remote Sensing Technologies, Huaiyin Institute of Technology, Huai’an, 223003, China

    Qing-Song Jiang, Xiaoyan Wang & Yongfeng Ju

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  1. Qing-Song Jiang
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Jiang, QS., Li, W., Wu, J. et al. Electrodeposited cobalt and nickel selenides as high-performance electrocatalytic materials for dye-sensitized solar cells. J Mater Sci: Mater Electron 30, 9429–9437 (2019). https://doi.org/10.1007/s10854-019-01273-5

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