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Ultra-low temperature co-fired CaV2O6-glass composite ceramic substrate for microelectronics

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Abstract

Bivalent calcium metavanadate (CaV2O6) ceramic-glass composite substrates were fabricated using non-aqueous environmental friendly tape casting formulation. 3 wt% of commercial glass was added to the calcined powder of CaV2O6 to achieve a sintering temperature of 650 °C which enables ultra-low temperature co-firing with aluminum electrode. An environmentally benign binder/solvent (Polypropylene carbonate/dimethyl carbonate) system was adopted to prepare the well dispersed slurry for tape casting. The crystal structure and co-fireability of the sintered substrate with Al was verified by X-ray diffraction technique. Thermal, dielectric and morphological analysis of the multilayer were analyzed. The room temperature thermal conductivity of CaV2O6-glass composite sintered at 650 °C is about 2.8 W/m K. Sintered ceramics shows a relatively high linear coefficient of thermal expansion (CTE) of 11.46 ppm/°C, which is favorable for co-firing with high CTE metallic materials. Microwave dielectric properties of CaV2O6-glass composite multilayer fired at 650 °C are εr = 10.6 and tanδ = 3.19 × 10−4 at 15 GHz.

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Acknowledgements

The authors are grateful to the financial support from the brain pool program by KOFST (Grant No. 171S-2-1-1853, 2017) and ceramic strategic technology development program by KICET (Grant No. KPP17004-2, 2018).

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Authors and Affiliations

  1. Korea Institute of Ceramic Engineering and Technology, Jinju, 52851, Republic of Korea

    Arun Sasidharanpillai, Sebastian Mailadil Thomas & Hyo Tae Kim

  2. Department of Materials Engineering and Convergence Technology, RIGET, Gyeongsang National University, Jinju, 52828, Republic of Korea

    Arun Sasidharanpillai & Younki Lee

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  1. Arun Sasidharanpillai
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Correspondence to Hyo Tae Kim.

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Sasidharanpillai, A., Thomas, S.M., Lee, Y. et al. Ultra-low temperature co-fired CaV2O6-glass composite ceramic substrate for microelectronics. J Mater Sci: Mater Electron 30, 7637–7644 (2019). https://doi.org/10.1007/s10854-019-01079-5

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