Skip to main content
Log in

Effect of iron doping on magnetic and electrical properties of BaSnO3 nanostructures

  • Published:
Journal of Materials Science: Materials in Electronics Aims and scope Submit manuscript

Abstract

Structural, magnetic and dielectric properties for the synthesized Fe doped nano barium stannate (BaSnO3) are investigated intently. The nanocuboids, nanoparticles and nanorods of BaSnO3 (BSO) by the influence of Fe ions are seen. Raman measurements shows a blue shift (646 cm−1) for the doped system and the magnetic and electric properties are studied by VSM, dielectric and PE loop measurements. Well saturated ferromagnetism exhibited at room temperature with high saturation magnetization (23.025 m emu g−1) and coercivity (339.3 G) are observed for Fe (5 at.%) doped BaSnO3.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8

Similar content being viewed by others

References

  1. C. Ederer, N.A. Spaldin, Magnetoelectrics: a new route to magnetic ferroelectrics. Nat. Mater. 3, 849 (2004)

    Article  CAS  Google Scholar 

  2. W. Prellier, M. Singh, P. Murugavel, The single-phase multiferroic oxides: from bulk to thin film. J. Phys. Condens. Matter. 17, R803 (2005)

    Article  CAS  Google Scholar 

  3. C.-C. Zhou, B.-C. Luo, K.-X. Jin, X.-S. Cao, C.-L. Chen, Magnetic and dielectric properties of hybrid composite ceramics. Solid State Commun. 150, 1334 (2010)

    Article  CAS  Google Scholar 

  4. N.A. Hill, Why are there so few magnetic ferroelectrics? J. Phys. Chem. B 104, 6694 (2000)

    Article  CAS  Google Scholar 

  5. X. Xie, C. Hu, D. Guo, H. Hua, T. Liu, P. Jiang, Room temperature magnetic properties of Fe/Co-doped barium niobate crystals. J. Phys. Chem. C 116, 23041 (2012)

    Article  CAS  Google Scholar 

  6. W. Eerenstein, N. Mathur, J.F. Scott, Multiferroic and magnetoelectric materials. Nature 442, 759 (2006)

    Article  CAS  Google Scholar 

  7. P. Kumar, Y. Kumar, H.K. Malik, S. Annapoorni, S. Gautam, K.H. Chae, K. Asokan, Possibility of room-temperature multiferroism in Mg-doped ZnO. Appl. Phys. A 114, 453 (2014)

    Article  CAS  Google Scholar 

  8. A.O. Turky, M.M. Rashad, A.M. Hassan, E.M. Elnaggar, M. Bechelany, Optical, electrical and magnetic properties of lanthanum strontium manganite La1−xSrxMnO3 synthesized through the citrate combustion method. Phys. Chem. Chem. Phys. 19, 6878 (2017)

    Article  CAS  Google Scholar 

  9. A.O. Turky, M.M. Rashad, A.M. Hassan, E.M. Elnaggar, H. Zhao, M. Bechelany, Tunable investigation optical, electrical and magnetic behaviors of Gd3+ substituted lanthanum strontium manganite La0.5–xSr0.5GdxMnO3 nanopowders facilely synthesized through citrate precursor technique. J. Alloys Compd. 735, 2175 (2018)

    Article  CAS  Google Scholar 

  10. A.O. Turky, M.M. Rashad, A.M. Hassan, E.M. Elnaggar, M. Bechelany, Tailoring optical, magnetic and electric behavior of lanthanum strontium manganite La1–xSrxMnO3 (LSM) nanopowders prepared via a co-precipitation method with different Sr2+ ion contents. RSC Adv. 6, 17980 (2016)

    Article  CAS  Google Scholar 

  11. K.F. Moura, L. Chantelle, D. Rosendo, E. Longo, I.M.G.D. Santos, Effect of Fe3+ doping in the photocatalytic properties of BaSnO3 perovskite. Mater. Res. (2017). https://doi.org/10.1590/1980-5373-mr-2016-1062

    Article  Google Scholar 

  12. U.S. Alaan, A.T. N’Diaye, P. Shafer, E. Arenholz, Y. Suzuki, Structure and magnetism of Fe-doped BaSnO3 thin films. AIP Adv. 7, 055716 (2017)

    Article  Google Scholar 

  13. Z. Xing, X. Zhu, J. Zhu, Z. Liu, T. Al-Kassab, Structural, Raman, and dielectric studies on multiferroic Mn-doped Bi1–xLaxFeO3 ceramics. J. Am. Ceram. Soc. 97, 2323 (2014)

    Article  CAS  Google Scholar 

  14. H. Nakayama, H. Katayama-Yoshida, Theoretical prediction of magnetic properties of Ba (Ti1–xMx)O3 (M = Sc, V, Cr, Mn, Fe, Co, Ni, Cu). Jpn. J. Appl. Phys. 40, L1355 (2001)

    Article  CAS  Google Scholar 

  15. J. Lee, Z. Khim, Y. Park, D. Norton, N. Theodoropoulou, A. Hebard, J. Budai, L. Boatner, S. Pearton, R. Wilson, Magnetic properties of Co-and Mn-implanted BaTiO3, SrTiO3 and KTaO3. Solid State Electron. 47, 2225 (2003)

    Article  CAS  Google Scholar 

  16. G. Catalan, J.F. Scott, Physics and applications of bismuth ferrite. Adv. Mater. 21, 2463 (2009)

    Article  CAS  Google Scholar 

  17. K. James, A. Aravind, M. Jayaraj, Structural, optical and magnetic properties of Fe-doped barium stannate thin films grown by PLD. Appl. Surf. Sci. 282, 121 (2013)

    Article  CAS  Google Scholar 

  18. N. Rajamanickam, P. Soundarrajan, V.K. Vendra, J.B. Jasinski, M.K. Sunkara, K. Ramachandran, Efficiency enhancement of cubic perovskite BaSnO3 nanostructures based dye sensitized solar cells. Phys. Chem. Chem. Phys. 18, 8468 (2016)

    Article  CAS  Google Scholar 

  19. A. Kumar, R. Choudhary, Characterization of electrical behaviour of Si modified BaSnO3 electroceramics using impedance analysis. J. Mater. Sci. 42, 2476 (2007)

    Article  CAS  Google Scholar 

  20. H. Zhang, C. Diao, S. Liu, S. Jiang, X. Jing, F. Shi, XRD and Raman study on crystal structures and dielectric properties of Ba [Mg(1 – x)/3ZrxNb2(1 – x)/3] O3 solid solutions. Ceram. Int. 40, 2427 (2014)

    Article  CAS  Google Scholar 

  21. E. Swatsitang, A. Karaphun, S. Phokha, T. Putjuso, Characterization and magnetic properties of BaSn1–xFexO3 nanoparticles prepared by a modified sol–gel method. J. Sol Gel. Sci. Technol. 77, 78 (2016)

    Article  CAS  Google Scholar 

  22. A. Deepa, S. Vidya, P. Manu, S. Solomon, A. John, J. Thomas, Structural and optical characterization of BaSnO3 nanopowder synthesized through a novel combustion technique. J. Alloys Compd. 509, 1830 (2011)

    Article  CAS  Google Scholar 

  23. G.C. Vásquez, M.A. Peche-Herrero, D. Maestre, B. Alemán, J. Ramírez-Castellanos, A. Cremades, J.M. González-Calbet, J. Piqueras, Influence of Fe and Al doping on the stabilization of the anatase phase in TiO2 nanoparticles. J. Mater. Chem. C 2, 10377 (2014)

    Article  Google Scholar 

  24. J. Zhang, X. Chen, Y. Shen, Y. Li, Z. Hu, J. Chu, Synthesis, surface morphology, and photoluminescence properties of anatase iron-doped titanium dioxide nano-crystalline films. Phys. Chem. Chem. Phys. 13, 13096 (2011)

    Article  CAS  Google Scholar 

  25. H. Mizoguchi, P. Chen, P. Boolchand, V. Ksenofontov, C. Felser, P.W. Barnes, P.M. Woodward, Electrical and optical properties of Sb-doped BaSnO3. Chem. Mater. 25, 3858 (2013)

    Article  CAS  Google Scholar 

  26. J. Van Roosmalen, E. Cordfunke, R. Helmholdt, H. Zandbergen, The defect chemistry of LaMnO3±δ: 2. Structural aspects of LaMnO3+δ. J. Solid State Chem. 110, 100 (1994)

    Article  Google Scholar 

  27. K. Balamurugan, N.H. Kumar, J.A. Chelvane, P. Santhosh, Effect of W co-doping on the optical, magnetic and electrical properties of Fe-doped BaSnO3. Physica B 407, 2519 (2012)

    Article  CAS  Google Scholar 

  28. U. Kumar, M.J. Ansaree, A.K. Verma, S. Upadhyay, G. Gupta, Oxygen vacancy induced electrical conduction and room temperature ferromagnetism in system BaSn1 – xNixO3(0 × 0.20). Mater. Res. Express 4, 116304 (2017)

    Article  Google Scholar 

  29. L.B. Kong, T. Zhang, J. Ma, F. Boey, Progress in synthesis of ferroelectric ceramic materials via high-energy mechanochemical technique. Prog. Mater. Sci. 53, 207 (2008)

    Article  CAS  Google Scholar 

  30. G.H. Haertling, Ferroelectric ceramics: history and technology. J. Am. Ceram. Soc. 82, 797 (1999)

    Article  CAS  Google Scholar 

Download references

Acknowledgements

Authors NR and KJ acknowledge SERB (DST) – National Postdoctoral fellowship grant PDF/2015/000689. The author KR acknowledges CSIR, New Delhi, for the financial support given in the form of Emeritus fellowship. The authors would like to thank Dr. V. Vasant Sathe and Dr. Ragavendra Reddy, Scientists, UGC-DAE Consortium for Scientific Research, Indore, for the Raman and P–E loop measurements and CIF, Pondicherry University for providing VSM facilities.

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to N. Rajamanickam.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Rajamanickam, N., Jayakumar, K. & Ramachandran, K. Effect of iron doping on magnetic and electrical properties of BaSnO3 nanostructures. J Mater Sci: Mater Electron 29, 19880–19888 (2018). https://doi.org/10.1007/s10854-018-0118-6

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10854-018-0118-6

Navigation