Synthesis and luminescence properties of Pr doped SLS–ZnO glass composite material for red phosphors

Abstract

Praseodymium (Pr) doped SLS–ZnO glass composite material of chemical formula [(SLS)_0.5 (ZnO)_0.5 (Pr)_x] where x = 1 wt% sintered at 600, 700, 800, 900 and 1000 °C were prepared by solid state technique. The structure, morphology and luminescence properties have been characterized by X-ray diffraction (XRD), Fourier transform infrared radiation (FTIR), UV–Vis spectroscopy, photoluminescence spectroscopy (PL), field emission scanning microscopy (FESEM) and energy dispersive X-ray (EDX). The XRD, FTIR and EDX studies reveal the formation of Zn₂SiO₄ from SLS–ZnO host lattice. FESEM shown the particle size distribution would lead to a higher packing density by increasing sintering temperatures. The presence of Pr³⁺ ions into Zn₂SiO₄ was confirmed by EDX analysis. The absorption peaks at 360, 444 and 616 nm originate in the UV and visible range were observed by UV–Vis spectroscopy. The PL spectrums with excitation at 444 nm exhibit two strong red emission peaks at ~613 and ~637 nm were attributed to the transition of ³P_o → ³H₆ and ³P_o → ³F₂. It is found that Pr³⁺ ions substituted into the host lattice could improve to the luminescence properties with increasing sintering temperatures. These results indicate that Pr doped SLS–ZnO exhibits great potential red phosphors in WLEDs application.