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Structural changes induced by Fe2O3 addition in strontium-borate glass matrix

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Abstract

Glasses of the xFe2O3·(100−x)[B2O3·SrO] system, with 0 ≤ x ≤ 30 mol% were studied by X-ray diffraction, density, optical microscopy and FT-IR spectroscopy measurements. The X-ray patterns for the prepared system show that vitreous phase is present only in the sample with x < 40 mol%. For x ≥ 40 mol% in the studied samples is evidenced crystalline phase of Fe2O3. SEM measurements for the sample with x = 40 mol% shows that there are formed Fe2O3 microcrystallites with 10–20 μm dimension. FT-IR spectroscopy measurements shown that BO3 and BO4 are the main structural units of the glass system and the iron ions are located in the glass network.

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Authors and Affiliations

  1. Faculty of Physics, Babes-Bolyai University, Cluj-Napoca, 400084, Romania

    I. Ardelean & R. Lungu

  2. Department of Physics, Techical University, Cluj-Napoca, 400641, Romania

    P. Păşcuţă

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  1. I. Ardelean
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  2. R. Lungu
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  3. P. Păşcuţă
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Correspondence to I. Ardelean.

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Ardelean, I., Lungu, R. & Păşcuţă, P. Structural changes induced by Fe2O3 addition in strontium-borate glass matrix. J Mater Sci: Mater Electron 18, 837–841 (2007). https://doi.org/10.1007/s10854-006-9087-2

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  • DOI: https://doi.org/10.1007/s10854-006-9087-2

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