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Synergistic effect in XMoO4 (X: Ni, Zn) nanorods derived from 2D molybdenum-based metal-organic frameworks boosting supercapacitive performance

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Abstract

We present a novel approach for synthesizing XMoO4 (X: Ni, Zn) using metal–organic frameworks as templates. Our findings reveal orthorhombic structure of MoO3 converted to triclinic and monoclinic crystalline phases for ZnMoO4 and NiMoO4, respectively. XMoO4 nanorods have higher band gap than MoO3, with an optical band gap range of 3.20–3.80 eV. The specific surface area was estimated to be 27.6, 44.7 and 63.6 m2 g−1 for MoO3, ZnMoO4, and NiMoO4, respectively. Electrochemical results demonstrated that Ni2+ and Zn2+ incorporation improved the supercapacitive performance of MoO3 and MOF-derived NiMoO4 nanorods disclosed superior specific capacitance of 2302.5 F g−1 at 1 A g−1 with cycling stability of 93% after 5000 cycles. A maximum energy density of 66.4 Wh kg−1 at 749.3 W kg−1 was achieved for NiMoO4//AC ASC. The research established that NiMoO4 nanorods have considerable potential for supercapacitor devices.

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Acknowledgements

The authors would like to thank the Research Council of University of Guilan for the financial support of this work.

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Authors and Affiliations

  1. Department of Physics, Faculty of Science, University of Guilan, Namjoo Avenue, P.O. Box 413351914, Rasht, Iran

    A. Safartoobi, J. Mazloom & F. E. Ghodsi

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  1. A. Safartoobi
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  2. J. Mazloom
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  3. F. E. Ghodsi
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Contributions

Mr. A. Safartoobi contributed to investigation, formal analysis, and writing—original draft preparation, Dr. j. Mazloom contributed to supervision, methodology, validation, writing—review and editing, and Prof. F. E. Ghodsi contributed to review and editing.

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Correspondence to J. Mazloom.

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Safartoobi, A., Mazloom, J. & Ghodsi, F.E. Synergistic effect in XMoO4 (X: Ni, Zn) nanorods derived from 2D molybdenum-based metal-organic frameworks boosting supercapacitive performance. J Mater Sci 59, 3809–3828 (2024). https://doi.org/10.1007/s10853-024-09432-8

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