Abstract
Lithium metal anode has attracted wide attention due to the high specific capacity. Unfortunately, many instabilities in cycling such as the growth of dendrites and volume change have seriously hindered the development of lithium metal anode. We demonstrated a promising structure consisting of clusters of CuO nanorods (CCNs) arrays directly grown on Cu foil is prepared by a simple ice-bath solution method. The structure of clusters of CuO nanorods promotes uniform deposition of lithium ions and accommodates lithium availably, therefore restraining the dendrites. An average Coulombic efficiency of 98% can be maintained for 230 cycles at 0.5 mA cm−2. The ultralong cycling stability over 1000 h at 0.5 mA cm−2 can be reached in the symmetric cell. The excellent electrochemical performance of Cu foil with CCNs arrays demonstrates the importance of rational structural design of the lithium framework to stabilize lithium metal anode.
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Sun YM, Liu N, Cui Y (2016) Promises and challenges of nanomaterials for lithium-based rechargeable batteries. Nat Energy 1(7):16071. https://doi.org/10.1038/NENERGY.2016.71
Ye H, Xin S, Yin YX et al (2017) Advanced porous carbon materials for high-efficient lithium metal anodes. Adv Energy Mater 7(23):1700530. https://doi.org/10.1002/aenm.201700530
Tarascon JM, Armand M (2001) Issues and challenges facing rechargeable lithium batteries. Nature 414(6861):359–367
Xu W, Wang J, Ding F et al (2014) Lithium metal anodes for rechargeable batteries. Energy Environ Sci 7:513–537
Zhang K, Lee GH, Park M et al (2016) Recent developments of the lithium metal anode for rechargeable non-aqueous batteries. Adv Energy Mater 6(20):1600811. https://doi.org/10.1002/aenm.201600811
Peng HJ, Huang JQ, Cheng XB et al (2017) Review on high-loading and high-energy lithium-sulfur batteries. Adv Energy Mater 7(24):1700260. https://doi.org/10.1002/aenm.201700260
Liu YM, Zhang SQ, Qin XY et al (2019) In-plane highly dispersed Cu2O nanoparticles for seeded lithium deposition. Nano Lett 19(7):4601–4607
Lu QW, He YB, Yu QP et al (2017) Dendrite-free, high-rate, long-life lithium metal batteries with a 3D cross-linked network polymer electrolyte. Adv Mater 29(13):1604460
Han XG, Gong YH, Fu K et al (2017) Negating interfacial impedance in garnet-based solid-state Li metal batteries. Nat Mater 16:572–579
Basile A, Bhatt AI, O’Mullane AP (2016) Anion effect on lithium electrodeposition from N-propyl-N-methylpyrrolidinium bis(fluorosulfonyl)imide ionic liquid electrolytes. Electrochim Acta 215:19–28
Zhao CZ, Cheng XB, Zhang R et al (2016) Li2S5-based ternary-salt electrolyte for robust lithium metal anode. Energy Storage Mater 3:77–84
Li WY, Yao HB, Yan K et al (2015) The synergetic effect of lithium polysulfide and lithium nitrate to prevent lithium dendrite growth. Nat Commun 6:7436. https://doi.org/10.1038/ncomms8436
Xu R, Cheng XB, Yan C et al (2019) Artificial interphases for highly stable lithium metal anode. Cell Press 1:317–344
Liu YY, Lin DC, Yuen PY et al (2017) An artificial solid electrolyte interphase with high Li-ion conductivity, mechanical strength, and flexibility for stable lithium metal anodes. Adv Mater 29(10):1605531. https://doi.org/10.1002/adma.201605531
Liang Z, Zheng GY, Liu C et al (2015) Polymer nanofiber-guided uniform lithium deposition for battery electrodes. Nano Lett 15(5):2910–2916
Zhang R, Cheng XB, Zhao CZ et al (2016) Conductive nanostructured scaffolds render low local current density to inhibit lithium dendrite growth. Adv Mater 28(11):2155–2162
Ryou MH, Lee YM, Lee YJ et al (2015) Mechanical surface modification of lithium metal: towards improved Li metal anode performance by directed Li plating. Adv Funct Mater 25(6):834–841
Li Q, Zhu SP, Lu YY (2017) 3D porous Cu current collector/Li-metal composite anode for stable lithium-metal batteries. Adv Funct Mater 27(18):1606422. https://doi.org/10.1002/adfm.201606422
Heine J, Krüger S, Hartnig C et al (2014) Coated lithium powder (CLiP) electrodes for lithium-metal batteries. Adv Energy Mater 4(5):1300815. https://doi.org/10.1002/aenm.201300815
Hwang SW, Yom JH, Cho SM et al (2017) Electrochemical behavior of Li–Cu composite powder electrodes in lithium metal secondary batteries. ACS Appl Mater Interfaces 9(27):22530–22538
Lin DC, Zhao J, Sun J et al (2017) Three-dimensional stable lithium metal anode with nanoscale lithium islands embedded in ionically conductive solid matrix. Proc Natl Acad Sci 114(18):4613–4618
Liu YM, Qin XY, Zhang SQ et al (2019) Oxygen and nitrogen co-doped porous carbon granules enabling dendrite-free lithium metal anode. Energy Storage Mater 18:320–327
Liu YM, Qin XY, Zhang SQ et al (2019) A scalable slurry process to fabricate a 3D lithiophilic and conductive framework for a high performance lithium metal anode. Mater Chem A 7:13225–13233
Yan K, Lu ZD, Lee HW et al (2016) Selective deposition and stable encapsulation of lithium through heterogeneous seeded growth. Nat Energy 1(3):16010. https://doi.org/10.1038/NENERGY.2016.10
Wang XS, Pan ZH, Wu Y et al (2018) Infiltrating lithium into carbon cloth decorated with zinc oxide arrays for dendrite-free lithium metal anode. Nano Res 12(3):525–529
Zhang CZ, Lv W, Zhou GM et al (2018) Vertically aligned lithiophilic CuO nanosheets on a Cu collector to stabilize lithium deposition for lithium metal batteries. Adv Energy Mater 8(21):1703404. https://doi.org/10.1002/aenm.201703404
Wu SL, Zhang ZY, Lan MH et al (2018) Lithiophilic Cu–CuO–Ni hybrid structure: advanced current collectors toward stable lithium metal anodes. Adv Mater 30(9):1705830. https://doi.org/10.1002/adma.201705830
Zhang HM, Liao XB, Guan YP et al (2018) Lithiophilic–lithiophobic gradient interfacial layer for a highly stable lithium metal anode. Nat Commun 9:3729. https://doi.org/10.1038/s41467-018-06126-z
Zhang R, Chen X, Shen X et al (2018) Coralloid carbon fiber-based composite lithium anode for robust lithium metal batteries. Joule 2(4):764–777. https://doi.org/10.1016/j.joule.2018.02.001
Hou GM, Ren XH, Ma XX et al (2018) Dendrite-free Li metal anode enabled by a 3D free-standing lithiophilic nitrogen-enriched carbon sponge. J Power Sources 386:77–84
Jin CB, Sheng OW, Luo JM et al (2017) 3D lithium metal embedded within lithiophilic porous matrix for stable lithium metal batteries. Nano Energy 37:177–186
Yang CP, Yin YX, Zhang SF et al (2015) Accommodating lithium into 3D current collectors with a submicron skeleton towards long-life lithium metal anodes. Nat Commun 6:8058. https://doi.org/10.1038/ncomms9058
Lu LL, Ge J, Yang JN et al (2016) Free-standing copper nanowire network current collector for improving lithium anode performance. Nano Lett 16:4431–4437
Zhang Z, Zhang M, Lu P et al (2019) CuO nanorods growth on folded Cu foil as integrated electrodes with high areal capacity for flexible Li-ion batteries. J Alloys Compd 809:151823. https://doi.org/10.1016/j.jallcom.2019.151823
Zhang R, Chen XR, Chen X et al (2017) Lithiophilic sites in doped graphene guide uniform lithium nucleation for dendrite-free lithium metal anodes. Angew Chem Int Ed 56(27):7764–7768
Acknowledgements
This work was supported by the National Natural Science Foundation of China (51502044), Natural Science Foundation of Guangxi (2015GXNSFCA139011).
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Luo, Y., He, G. Clusters of CuO nanorods arrays for stable lithium metal anode. J Mater Sci 55, 9048–9056 (2020). https://doi.org/10.1007/s10853-020-04633-3
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DOI: https://doi.org/10.1007/s10853-020-04633-3