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3D hierarchical and porous layered double hydroxide structures: an overview of synthesis methods and applications

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Abstract

Nanostructured layered double hydroxide (LDH) materials with unique diffusion properties, large surface area along with desired functionalities have recently been produced for a number of well-established and advanced fields of applications. In this review, we describe and discuss the main synthetic methods that have been reported for the fabrication of porous LDH with tailored chemical composition and porosity. The efficiency of soft and hard templating approaches is particularly reviewed. A special emphasis is put on the microstructure and porosity of the materials according to the synthetic method involved. Finally, the performance enhancement of the materials due to the presence of porosity, especially macroporosity, in applications such as pollutant removal, catalysis and energy storage and conversion is overviewed.

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Scheme 1
Figure 1

Reproduced from Ref. [32] with permission from The Royal Society of Chemistry

Figure 2

Reproduced from Ref. [61] with permission from The Royal Society of Chemistry

Figure 3

Adapted with permission from [20] Copyright (2016) American Chemical Society

Figure 4
Figure 5

Adapted with permission from [72]. Copyright (2016) American Chemical Society. Reprinted from [74, 75], Copyright (2016), with permission from Elsevier. Reprinted from [73], Copyright (2016), with permission from John Wiley and Sons

Figure 6

Reproduced from Ref. [132] with permission from The Royal Society of Chemistry. Adapted with permission from [126, 139, 142] Copyright (2016) American Chemical Society

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Acknowledgements

Financial support from JSPS-MAE SAKURA program (Grant No. 34148TB) is gratefully acknowledged.

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Authors and Affiliations

  1. Institut de Chimie de Clermont-Ferrand, Université Clermont Auvergne Université Blaise Pascal, BP 10448, 63000, Clermont-Ferrand, France

    Vanessa Prevot

  2. CNRS, UMR 6296, ICCF, 63171, Aubiere, France

    Vanessa Prevot

  3. Department of Materials Science, Graduate School of Engineering, Osaka Prefecture University, Sakai, Osaka, 599-8531, Japan

    Yasuaki Tokudome

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  1. Vanessa Prevot
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Prevot, V., Tokudome, Y. 3D hierarchical and porous layered double hydroxide structures: an overview of synthesis methods and applications. J Mater Sci 52, 11229–11250 (2017). https://doi.org/10.1007/s10853-017-1067-9

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