Abstract
A novel highly compact and b-oriented MFI-type zeolite monolayer was obtained by assembling sec-butanol-modified rounded-coffin-shaped silicalite-1 microcrystals by Langmuir–Blodgett (LB) method. The LB monolayer was subsequently tested as a seed layer for the secondary growth of uniformly b-oriented and defect-free MFI zeolite films on stainless steel substrates and platinum electrodes. Three different methods were evaluated for identifying a suitable synthesis route to suppress the undesired a-oriented twin growth during the synthesis of MFI films. The crystal intergrowth and orientation of the MFI films were characterized by scanning electron microscopy and X-ray diffraction (XRD). The crystallographic preferred orientation indices and preferred orientation coverage values calculated using the XRD data were used to quantitatively determine the preferred orientation and surface coverage of the prepared zeolite films. The experimental results confirm that the low tetrapropylammonium hydroxide (TPAOH) method is the most effective route to suppress the undesired a-oriented twin growth, when the highly b-oriented LB monolayer was used as the seed layer for the secondary growth of the b-oriented MFI film. The highly b-oriented MFI-type zeolite film-modified electrodes were further tested as the working electrodes in electrochemical experiments. Cyclic voltammetry experimental results confirmed that the b-oriented MFI films fabricated at low TPAOH concentration were defect free and possessed a distinct molecular sieving property after calcination. The LB method, a highly reproducible and controllable method for the organization of zeolite crystals, can be further applied as an effective platform for the promotion and development of zeolite-modified electrodes as selective sensors.
Graphical Abstract
Similar content being viewed by others
References
Yu M, Noble RD, Falconer JL (2011) Zeolite membranes: microstructure characterization and permeation mechanisms. Acc Chem Res 44:1196–1206
Carreon MA, Li S, Falconer JL, Noble RD (2008) Alumina-supported SAPO-34 membranes for CO2/CH4 separation. J Am Chem Soc 130:5412–5413
Wen Q, Di J, Jiang L, Yu JH, Xu RR (2013) Zeolite-coated mesh film for efficient oil–water separation. Chem Sci 4:591–595
Choi J, Jeong HK, Snyder MA, Stoeger JA, Masel RI, Tsapatsis M (2009) Grain boundary defect elimination in a zeolite membrane by rapid thermal processing. Science 325:590–593
Gascon J, Kapteijn F, Zornoza B, Sebastian V, Casado C, Coronas J (2012) Practical approach to zeolitic membranes and coatings: state of the art, opportunities, barriers, and future perspectives. Chem Mater 24:2829–2844
McLeary EE, Jansen JC, Kapteijn F (2006) Zeolite based films, membranes and membrane reactors: progress and prospects. Microporous Mesoporous Mater 90:198–220
Pina MP, Mallada R, Arruebo M, Urbiztondo M, Navascués N, De La Iglesia O, Santamaria J (2011) Zeolite films and membranes. Emerging applications. Microporous Mesoporous Mater 144:19–27
Lew CM, Cai R, Yan YS (2009) Zeolite thin films: from computer chips to space stations. Acc Chem Res 43:210–219
Lew CM, Li Z, Li S, Hwang SJ, Liu Y, Medina DI, Sun M, Wang J, Davis ME, Yan YS (2008) Pure-silica-zeolite MFI and MEL low-dielectric-constant films with fluoro-organic functionalization. Adv Funct Mater 18:3454–3460
Pham TCT, Kim HS, Yoon KB (2013) Large increase in the second-order nonlinear optical activity of a hemicyanine-incorporating zeolite film. Angew Chem Int Ed 52:5539–5543
Shaw BR, Creasy KE, Lanczycki CJ, Sargeant JA, Tirhado M (1988) Voltammetric response of zeolite-modified electrodes. J Electrochem Soc 135:869–876
Walcarius A (1999) Zeolite-modified electrodes in electroanalytical chemistry. Anal Chim Acta 384:1–16
Walcarius A, Rozanska S, Bessière J, Wang J (1999) Screen-printed zeolite-modified carbon electrodes. Analyst 124:1185–1190
Azizi SN, Ranjbar S, Raoof JB, Hamidi-Asl E (2013) Preparation of Ag/NaA zeolite modified carbon paste electrode as a DNA biosensor. Sensors Actuat B Chem 181:319–325
Siara LR, de Lima F, Cardoso CAL, Arruda GJ (2015) Electrochemically pretreated zeolite-modified carbon-paste electrodes for determination of linuron in an agricultural formulation and water. Electrochim Acta 151:609–618
Lai ZP, Bonilla G, Diaz I, Nery JG, Sujaoti K, Amat MA, Kokkoli E, Terasaki O, Thompson RW, Tsapatsis M, Vlachos DG (2003) Microstructural optimization of a zeolite membrane for organic vapor separation. Science 300:456–460
Pham TCT, Kim HS, Yoon KB (2011) Growth of uniformly oriented silica MFI and BEA zeolite films on substrates. Science 334:1533–1538
Pham TCT, Nguyen TH, Yoon KB (2013) Gel-free secondary growth of uniformly oriented silica MFI zeolite films and application for xylene separation. Angew Chem Int Ed 52:8693–8698
Zhou M, Korelskiy D, Ye P, Grahn M, Hedlund J (2014) A uniformly oriented MFI membrane for improved CO2 separation. Angew Chem Int Ed 53:3492–3495
Lai ZP, Tsapatsis M, Nicolich JP (2004) Siliceous ZSM-5 membranes by secondary growth of b-oriented seed layers. Adv Funct Mater 14:716–729
Li S, Wang X, Beving D, Chen Z, Yan YS (2004) Molecular sieving in a nanoporous b-oriented pure-silica-zeolite MFI monocrystal film. J Am Chem Soc 126:4122–4123
Li S, Demmelmaier C, Itkis M, Liu Z, Haddon RC, Yan YS (2003) Micropatterned oriented zeolite monolayer films by direct in situ crystallization. Chem Mater 15:2687–2689
Lee GS, Lee YJ, Yoon KB (2001) Layer-by-layer assembly of zeolite crystals on glass with polyelectrolytes as ionic linkers. J Am Chem Soc 123:9769–9779
Lee JS, Lee YJ, Tae EL, Park YS, Yoon KB (2003) Synthesis of zeolite as ordered multicrystal arrays. Science 301:818–821
Lee JS, Ha K, Lee YJ, Yoon KB (2005) Ultrasound-aided remarkably fast assembly of monolayers of zeolite crystals on glass with a very high degree of lateral close packing. Adv Mater 17:837–841
Lee JS, Kim JH, Lee YJ, Jeong NC, Yoon KB (2007) Manual assembly of microcrystal monolayers on substrates. Angew Chem Int Ed 46:3087–3090
Yoon KB (2007) Organization of zeolite microcrystals for production of functional materials. Acc Chem Res 40:29–40
Zhou M, Liu XF, Zhang BQ, Zhu H (2008) Assembly of oriented zeolite monolayers and thin films on polymeric surfaces via hydrogen bonding. Langmuir 24:11942–11946
Zhou M, Hedlund J (2012) Assembly of oriented iron oxide and zeolite crystals via biopolymer films. J Mater Chem 22:24877–24881
Liu Y, Li YS, Yang WS (2009) Fabrication of highly b-oriented MFI monolayers on various substrates. Chem Commun 12:1520–1522
Liu Y, Li YS, Yang WS (2010) Fabrication of highly b-oriented MFI film with molecular sieving properties by controlled in-plane secondary growth. J Am Chem Soc 132:1768–1769
Liu Y, Li YS, Yang WS (2011) Phase-segregation-induced self-assembly of anisotropic MFI microbuilding blocks into compact and highly b-oriented monolayers. Langmuir 27:2327–2333
Lee I, Buday JL, Jeong HK (2009) μ-Tiles and mortar approach: a simple technique for the facile fabrication of continuous b-oriented MFI silicalite-1 thin films. Microporous Mesoporous Mater 122:288–293
Lee I, Jeong HK (2011) Synthesis and gas permeation properties of highly b-oriented MFI silicalite-1 thin membranes with controlled microstructure. Microporous Mesoporous Mater 141:175–183
Wang Z, Yu T, Nian P, Zhang QC, Yao JK, Li S, Gao ZN, Yue XL (2014) Fabrication of a highly b-oriented MFI-type zeolite film by the Langmuir–Blodgett method. Langmuir 30:4531–4534
Li J, Liu XF, Lv XL, Zhang BQ (2014) Reliable fabrication of preferentially b-oriented silicalite-1 monolayers on various substrates using the Langmuir–Blodgett technique. Mater Lett 124:299–301
Rangnekar N, Shete M, Agrawal KV et al (2015) 2D zeolite coatings: Langmuir–Schaefer deposition of 3 nm thick MFI zeolite nanosheets. Angew Chem Int Ed 127:6671–6675
Li XM, Peng Y, Wang ZB, Yan YS (2011) Synthesis of highly b-oriented zeolite MFI films by suppressing twin crystal growth during the secondary growth. Cryst Eng Comm 13:3657–3660
Hedlund J, Mintova S, Sterte J (1999) Controlling the preferred orientation in silicalite-1 films synthesized by seeding. Microporous Mesoporous Mater 28:185–194
Hrabanek P, Zikanova A, Drahokoupil J, Prokopova O, Brabec L, Jirka I, Matejkova M, Fila V, De la Lglesia O, Kocirik M (2013) Combined silica sources to prepare preferentially oriented silicalite-1 layers on various supports. Microporous Mesoporous Mater 174:154–162
Peng Y, Lu H, Wang ZB, Yan YS (2014) Microstructural optimization of MFI-type zeolite membranes for ethanol–water separation. J Mater Chem A 2:16093–16100
Lu XF, Peng Y, Wang ZB, Yan YS (2015) Rapid fabrication of highly b-oriented zeolite MFI thin films using ammonium salts as crystallization-mediating agents. Chem Commun 51:11076–11079
Gora L, Kuhn J, Baimpos T, Nikolakis V, Kapteijn F, Serwicka EM (2009) Selective sensor utilizing a thin monolayer of b-oriented silicalite-1 crystals–magneto-elastic ribbon assembly. Analyst 134:2118–2122
Jirka I, Pachtová O, Novák P, Kočirík M (2002) On the removal of template from silicalite-1 90° intergrowths. A study by X-ray photoelectron spectroscopy. Langmuir 18:1702–1706
Jirka I, Sazama P, Zikanova A, Hrabanek P, Kocirik M (2011) Low-temperature thermal removal of template from high silica ZSM-5 catalytic effect of zeolitic framework. Microporous Mesoporous Mater 137:8–17
Acknowledgements
This study was supported by the National Natural Science Foundation of China (Grant Nos. 21066011, 21263026 and 21366026), the Ningxia Natural Science Foundation (NZ12132), and SRF for ROCS, State Education Ministry.
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Nian, P., Su, M., Yu, T. et al. Fabrication of a highly b-oriented MFI-type zeolite film-modified electrode with molecular sieving properties by Langmuir–Blodgett method. J Mater Sci 51, 3257–3270 (2016). https://doi.org/10.1007/s10853-015-9638-0
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10853-015-9638-0