Abstract
The body of work described in this research article outlines the use of titanium microparticles as fillers in the production of a polyether-block-amide (Pebax 5533) based composite for medical applications. Virgin polyether-block-amide was compared with titanium filled composites with loadings of 40 and 60% by weight prepared using twin screw extrusion and compression moulding. The materials were characterised using a range of mechanical, thermal, toxicological and surface analysis techniques. Fourier transform infrared spectroscopy indicated that no chemical interaction occurred between the filler particles and the host polymer matrix. Thermal analysis of the composites indicated that as the blend composition varied, so too did the melting behaviour. The inclusion of the titanium microparticles was observed to increase the flow viscosity, tensile strength, hardness and Young’s modulus of the composites whilst also resulting in a rougher surface with lower surface energy.
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References
Bigg M (1987) Polym Compos 8:115
Coutinho F, Costa T (1999) Polym Test 18:581
Averous L, Quantin J, Crespy A (1998) Compos Sci Technol 58:377
Selvin T, Kuruvilla J, Sabu T (2004) Mater Lett 58:281
Van Noort D (1987) J Mater Sci 22:3801. doi:10.1007/BF01133326
Sul Y, Johansson C, Jeong Y, Albrektsson T (2001) Med Eng Phys 23:329
Coffey A, O’Bradaigh C, Young R (2007) J Mater Sci 42:8053. doi:10.1007/s10853-007-1680-0
Stein B, Hodges W, Tyeryar J (1985) Proceedings of the 26th structures, structural dynamics and materials conference AIAA, paper no. 85-0750-CP
Pollard J, Walker J (1990) Methods in molecular biology, volume v, animal cell culture. Humana Press, New Jersey, pp 65–74
Korzezeniewki C, Callewaert D (1983) J Immunol Methods 64:313
Verreck G, Decorte A, Li H, Tomasko D, Arien A, Peeters J, Rombaut P, Van den Mooter G, Brewster M (2006) J Supercrit Fluids 38:383
Lyons J, Devine D, Kennedy J, Geever L, O’Sullivan P, Higginbotham C (2006) Eur J Pharm Biopharm 64:75
Lyons J, Hallinan M, Kennedy J, Devine D, Geever L, Blackie P, Higginbotham C (2007) Int J Pharm 329:62
Lyons J, Holehonnur H, Kennedy J, Devine D, Geever L, Blackie P, Higginbotham C (2007) Mater Chem Phys 103:419
Lyons J, Blackie P, Higginbotham C (2008) Int J Pharm 351:201
Bagley E (1957) J Appl Phys 28:624
Good R, van Oss C (1991) Modern approaches to wettability: theory and applications. Plenum, New York, pp 1–27
Good R, Chaudhury M, van Oss C (1991) Fundamentals of adhesion. Plenum, New York, pp 153–172
Thorpe A, Nevell T, Young S, Tsibouklis J (1998) Appl Surf Sci 136:99
Drummond C, Chan D (1997) Langmuir 13:3890
Nevell T, Edwards D, Davis A, Pullin R (1996) Biofouling 10:199
Brunette D, Tengvall P, Textor M, Thompsen P (2001) Titanium in medicine. Springer, Germany
Watanabe M, Okada M, Kudo Y, Tonori Y, Niitsuya M, Sato T, Aizawa Y, Kotani M (2002) J Toxicol Environ Health A 65:1047
Kumazawa R, Watari F, Takashi Y, Uo M, Totsku Y (2002) Biomaterials 23:3757
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Lyons, J.G., Kennedy, J.E., Lordan, S. et al. Characterisation of the effects of a titanium micro particle filler on a polyether-block-amide host matrix. J Mater Sci 45, 3204–3214 (2010). https://doi.org/10.1007/s10853-010-4328-4
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DOI: https://doi.org/10.1007/s10853-010-4328-4