Abstract
Al-filler-loaded polymethylsiloxane (PMS) was pyrolysed in air atmosphere at temperatures 400–1700 °C. The effect of the Al amount added to the PMS on phase development, densification behaviour and microstructure evolution was studied by simultaneous thermal analysis, X-ray diffraction, scanning electron microscopy and electron probe microanalysis. The Al/PMS reaction route is complex producing Si, SiO2 (amorphous and cristobalite), Al2O3 (γ-, ι- and α-Al2O3), Al2OC, Al4O4C, Al4SiC4, and AlN, depending on the ratio of Al/PMS in the initial mixture. Increasing the Al content (high Al/PMS ratio) reduces the amount of voids and porosities after PMS degradation. The voids and porosities provide access for the oxygen atmosphere into the inner structure to oxidise the Al particles, Si or SiC and also as channels for the PMS degradation products to escape. Mullite formation was identified in sample containing >73 wt% Al at temperature as low as 1400 °C.
Similar content being viewed by others
References
Wei Q, Pippel E, Woltersdorf J, Scheffler M, Greil P (2002) Mater Chem Phys 73:281
Scheffler M, Wei Q, Pippel E, Woltersdorf J, Greil P (2002) Key Eng Mater 206–213:289
Suttor D, Kleebe HJ, Ziegler G (1997) J Am Ceram Soc 80:2541
Anggono J, Derby B (2005) J Am Ceram Soc 88:2085
Anggono J, Derby B (2006) J Europ Ceram Soc 26:1107
Michalet T, Parlier M, Beclin F, Duclos R, Crampon J (2002) J Eur Ceram Soc 22:143
Cameron WE (1977) Am Mineral 62:747
Burnham CW (1963) Z Kristal 115:127
Fischer RX, Schneider H, Voll D (1996) J Europ Ceram Soc 16:109
Scheffler M, Greil P In: Mueller G (ed) EUROMAT 99, Wiley-VCH Verlag GmbH, Weinheim, G, pp 307–311
Greil P, Seibold M, Erny T (1992) In: Schmidt H, Hirano K (eds) Microcrystalline ceramic composites by active filler controlled reaction pyrolysis of polymers in materials research symposium, vol 274. MRS, Pittsburgh, pp 155–66
Renlund GM, Prochazka S, Doremus RH (1991) J Mater Res 6:2716
Schmidt H, Buhler P, Greil P (1995) In: Galassi C (ed) Pyrolytic conversion of poly(methylsiloxane) to silicon (oxy) carbide ceramics in fourth euro ceramics, vol 1. Gruppo Editoriale Faenza Editrice S.p.A., pp 299–306
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Anggono, J., Derby, B. Pyrolysis of aluminium loaded polymethylsiloxanes: the influence of Al/PMS ratio on mullite formation. J Mater Sci 45, 233–241 (2010). https://doi.org/10.1007/s10853-009-3925-6
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10853-009-3925-6