Abstract
Preceramic polymers and expansion agents are being investigated to produce composite ceramic coatings for oxidation protection of metallic substrates. In this paper, we present results of a systematic approach to selecting the preceramic polymer and expansion agents and the optimization of the processing parameters to produce composite ceramics. Six commercially available poly(silsesquioxane) polymers and a polysiloxane were studied. In addition, several metals and an intermetallic were considered as potential expansion agents. Based on this study, the most desirable polymer/expansion agent combination and optimal processing parameters have been identified.
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References
Rice RW (1983) Cer Bull 62(8):889
Wynne KJ, Rice RW (1984) Ann Rev Mater Sci 14:297
Greil P (1995) J Am Cer Soc 78(4):835
Riedel R, Dressler W (1996) Cer Int 22:233
Stackpoole M (2002) In: Ph.D. Thesis, Department of Materials Science and Engineering, University of Washington
Suzuki T, Inoue K, Koshi I, Isoda T (1991) In: Proceedings of the 2nd International SAMPE Symposium, December 2001, 11–14, p 216
Raj R, Riedel R, Soraru GD (2001) J Am Cer Soc 84(10):2158
Bill J, Heiman D (1996) J Eur Cer Soc 16:1115
Colombo P, Bernardo E (2003) Compos Sci Technol 63:2353
Zeschky J, Goetz-Neunhoeffer F, Neubauer J, Lo SH, Kummer B, Scheffler M, Greil P (2003) Compos Sci Technol 63:2361
Zeschky J, Lo SH, Scheffler M, Hoeppel H, Arnold M, Greil P (2002) Mater Res Adv Tech 93(8):812
Scheffler M, Greil P, Berger A, Pippel E, Woltersdorf J (2004) Mater Chem Phys 84:131
Liew L, Zhang W, An L, Shah S, Luo R, Lui Y, Cross T, Dunn ML, Bright V, Raj R (2001) Am Cer Soc Bull 80(5):25
Liew L, Zhang W, Bright VM, An L, Dunn ML, Raj R (2001) Sensors Actuat A 89:64
Liew L, Liu Y, Luo R, Cross T, An L, Bright V, Dunn M, Daily J, Raj R (2002) Sensors Actuat A 95:120
Liew L, Saravanan RA, Bright VM, Dunn ML, Daily JW, Raj R (2003) Sensors Actuat A 103:171
Soraru GD, Kleebe H, Ceccato R, Pederiva L (2000) J Eur Cer Soc 20:2509
Michalet T, Parlier M, Beclin F, Duclos R, Crampon J (2002) J Eur Cer Soc 22:143
Greil P (1998) J Eur Cer Soc 18:1905
Lewinsohn CA, Jones RH, Colombo P, Riccardi B (2002) J Nucl Mater 307–311:1232
Baney RH (1999) Poly (phenylsilsesquioxane), In: Polymer data handbook, edited by Mark JE, Oxford University Press, p 734
Erny T, Siebold M, Jarchow O, Greil P (1993) J Am Cer Soc 76(1):207
Blum YD, MacQueen DB (2001) Surf Coat Int Part B: Coat Trans 84(1–90):27
Blum YD (1992) Hydroxysiloxane precursors for ceramic manufacture. US Patent 5,128,494, July 7, 1992
Blum YD, Johnson SM, Gusman MI (1997) Hydridosiloxanes as precursors to ceramic products, US Patent 5,635,250, June 3, 1997
Schwartz SM, Henager CH, Gianuzzi LA (2004) Presented at the 28th International Cocoa Beach Conference & Exposition on Advanced Ceramics and Composites, Cocoa Beach, FL, January 2004
Acknowledgements
The authors would like to thank the DOE Industrial Technologies Program for financial support (Project No. 25630-A-N4). Special thanks also go to Dr. Yigal Blum (SRI, Inc.), Dr. Eric Minford (Air Products), and Dr. Michael Scheffler (University of Washington, Bavarian Center for Applied Energy Research) for their helpful discussions.
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Torrey, J.D., Bordia, R.K., Henager, C.H. et al. Composite polymer derived ceramic system for oxidizing environments. J Mater Sci 41, 4617–4622 (2006). https://doi.org/10.1007/s10853-006-0242-1
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DOI: https://doi.org/10.1007/s10853-006-0242-1