Abstract
Polycrystalline samples of (Ba1-xCax)(Sn0.15Ti0.85)O3 (x = 0, 0.03, 0.06 and 0.09) of perovskite structural family have been prepared by a high-temperature solid-state reaction technique. Preliminary room temperature X-ray study confirmed the formation of single-phase compound with tetragonal structure. The Scanning electron microscope shows the uniform distribution of the grains throughout the surface of the samples. Dielectric studies as a function of frequency at different temperature suggests that the compounds undergo diffuse phase transition (DPT). The d.c. and a.c. conductivities have been investigated over a wide range of temperature and the activation energy was calculated.
Similar content being viewed by others
References
M. E. LINES and A. M. GLASS, “Principles and Applications of Ferroelectrics and Related Materials” (Oxford University Press, Oxford, 1977).
YONGLI WANG, LONGTU LI, JIANQUAN QI and ZHILUN GUI, J. Ceram. Int. 28 (2002) 657.
LANDOLT and BERSTEIN, “Antiferroelectrics and Ferroelectrics” (New York, 1970) p. 423.
E. WU, “POWD, An Anteractive Powder Diffraction Data Interpretation and Indexing program” Ver-2.1 (School of Physical Science, Finder's University of South Australia, Bedford Park).
H. P. KLUNG, and L. B. ALEXANDER, “Xray Diffraction Procedures” (Wiles, New York 1974) p 687.
A. PANNIGRAHI, N. K. SINGH, and R. N. P. CHOUDHARY, J. Phys. Chem. Solids 63 (2002) 213.
L. E. CROSS, Ferroelectrics 76 (1987) 241.
C. SCHMIDT, ibid. 78 (1987) 199.
S. M. PILGRIM, A. E. SUTHERLAND and S. R. WINZER, J. Am.Ceram. Soc, 73 (1990) 3122.
R. C. BUCHANAN, “Ceramic Materials for Electronics” (Marcel Dekker Inc., New York, 1986).
S. BERA, and R. N. P. CHOUDHARY, Ferroelectrics 220 (1995) 85.
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Sen, S., Choudhary, R.N.P. Structural, dielectric and electrical properties of Ca modified BaSn0.15Ti0.85O3 Ceramics. J Mater Sci 40, 5457–5462 (2005). https://doi.org/10.1007/s10853-005-1908-9
Received:
Accepted:
Issue Date:
DOI: https://doi.org/10.1007/s10853-005-1908-9