Skip to main content
SpringerLink
Log in

Influence of ferrite phase on electrical properties of the barium zirconium titanate based multiferroic composites

  • Published:
Journal of Electroceramics Aims and scope Submit manuscript

Abstract

Multiferroic composites with general formula Ba(Ti0.95Zr0.05)O3 – Ni0.7Zn0.3Fe2O4, Ba(Ti0.95Zr0.05)O3 – CoFe2O4, Ba(Ti0.95Zr0.05)O3 – Ni0.7Cu0.01Sm0.05Zn0.29Fe1.95O4, (BTZr(95–5) – NZF, BTZr(95–5) – CF, BTZr(95–5) – NCuSmZF) were prepared by mixing chemically obtained different types of ferrites and BTZ(95–5) powders in the planetary mill for 24 h. The optimization of sintering process was performed and powders were pressed and sintered at 1300 °C for obtained composites samples. From the X-ray analysis for single phase and composites ceramics the formation of crystallized structure of ferrites and barium zirconium titanate can be noticed. SEM analyses indicated the formation of two types nanosized grains, polygonal ferromagnetic and rounded ferroelectric grains. The electrical properties of these materials were investigated using impedance spectroscopy and analysis of ferroelectric measurements. Impedance analysis of all investigated samples has shown different relaxation processes that originated from the grain and grain boundary contributions. The results of polarization vs. electric field measurements have shown the influence of magnetic phase type and its concentration on the ferroelectric properties of the composites. Due to high conductivity of ferrite phases and presence of interfacial polarization, the shapes of these curves differed from the conventional ferroelectric materials.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8
Fig. 9
Fig. 10
Fig. 11
Fig. 12
Fig. 13

Similar content being viewed by others

References

  1. H. Schmid, Ferroelectric 132, 317 (1994)

    Article  Google Scholar 

  2. W. Eerenstein, N. Mathur, J. Scott, Nature 442(7104), 759–765 (2006)

    Article  CAS  Google Scholar 

  3. W. Prellier, M. Singh, P. Murugavel, J. Phys. Condens. Matter. 17(30), R803–R832 (2005)

    Article  CAS  Google Scholar 

  4. R. Mondal, B. Murty, V. Murthy, Mater. Chem. Phys. 167, 338–346 (2015)

    Article  CAS  Google Scholar 

  5. T. Kimura, T. Goto, H. Shintani, K. Ishizaka, T. Arima, Y. Tokura, Nature 426(6962), 55–58 (2003)

    Article  CAS  Google Scholar 

  6. A. Dzunuzovic, M. Vijatovic Petrovic, B. Stojadinovic, N. Ilic, J. Bobic, C. Foschini, M. Zaghete, B. Stojanovic, Ceram. Int. 41(10), 13189–13200 (2015)

    Article  CAS  Google Scholar 

  7. R. Pandya, U. Joshi, O. Caltun, Procedia Mater. Sci. 10, 168–175 (2015)

    Article  CAS  Google Scholar 

  8. M. Bernardo, T. Jardiel, M. Peiteado, A. Caballero, M. Villegas, J. Eur. Ceram. Soc. 31(16), 3047–3053 (2011)

    Article  CAS  Google Scholar 

  9. T. Karthik, A. Srinivas, V. Kamaraj, V. Chandrasekeran, Ceram. Int. 38(2), 1093–1098 (2012)

    Article  CAS  Google Scholar 

  10. M. Vijatovic Petrovic, R. Grigalaitis, A. Dzunuzovic, J. Bobic, B. Stojanovic, R. Salasevicius, J. Banys, J. Alloy. Compd. 749, 1043–1053 (2018)

    Article  CAS  Google Scholar 

  11. A. Dzunuzovic, M. Vijatovic Petrovic, J. Bobic, N. Ilic, M. Ivanov, R. Grigalaitis, J. Banys, B. Stojanovic, Ceram. Int. 44(1), 683–694 (2018)

    Article  CAS  Google Scholar 

  12. J. Bobić, M. Ivanov, N. Ilić, A. Dzunuzović, M. Vijatović Petrović, J. Banys, A. Ribic, Z. Despotovic, B. Stojanovic, Ceram. Int. 44(6), 6551–6557 (2018)

    Article  CAS  Google Scholar 

  13. L. Mitoseriu, Bol. Soc. Esp. Ceram. 44(3), 177–184 (2005)

    Article  CAS  Google Scholar 

  14. N. Adhlakha, K. Yadav, Smart Mater. Struct. 21(11), 115021 (2012)

    Article  CAS  Google Scholar 

  15. M. Vijatovic Petrovic, A. Radojkovic, J. Bobic, A. Dzunuzovic, N. Ilic, B. Stojanovic, J. Mater. Sci. 54(8), 6038–6052 (2019)

    Article  CAS  Google Scholar 

  16. M. Vijatovic Petrovic, J. Bobic, in Magnetic, ferroelectric, and multiferroic metal oxides, ed. by B. D. Stojanovic. (Elsevier Publisher, Amsterdam, 2018), pp. 35–49

    Chapter  Google Scholar 

  17. N. Binhayeeniyi, P. Sukvisut, C. Thanachayanont, S. Muensit, Mater. Lett. 64(3), 305–308 (2010)

    Article  CAS  Google Scholar 

  18. Z. Yu, C. Ang, R. Guo, A. Bhalla, J. Appl. Phys. 92(3), 1489–1493 (2002)

    Article  CAS  Google Scholar 

  19. F. Moura, A. Simoes, B. Stojanovic, M. Zaghete, E. Longo, J. Varela, J. Alloy. Compd. 462(1-2), 129–134 (2008)

    Article  CAS  Google Scholar 

  20. C. Nan, M. Bichurin, S. Dong, D. Viehland, G. Srinivasan, J. Appl. Phys. 103(3), 031101 (2008)

    Article  CAS  Google Scholar 

  21. N. Hosni, K. Zehani, T. Bartoli, L. Bessais, H. Maghraoui-Meherzi, J. Alloy. Compd. 694, 1295–1301 (2017)

    Article  CAS  Google Scholar 

  22. M. Niyaifar, H. Shalilian, A. Hasanpour, Proceedings of the 4th International Conference on Nanostructures (ICNS4) 12-14 March, 2012, Kish Island, I.R. Iran

  23. V. Jancarik, M. Soka, M. Usakova, R. Dosoudil, J. Electr. Eng. 66, 116 (2015)

    Google Scholar 

  24. M. Soka, J. Slama, A. Gruskova, R. Dosoudil, V. Jancarik, J. Franek, IEEE T. Magn. 48(4), 1573–1576 (2012)

    Article  CAS  Google Scholar 

  25. B. Suryanarayana, K. Chandra Mouli, V. Raghavendra, B.B. Parvateesam, National Conference on Advanced Functional Materials and Computer Applications in Materials Technology (CAMCAT-2014)

  26. L. Gama, A. Diniz, A. Costa, S. Rezende, A. Azevedo, D. Cornejo, Physica B 384(1-2), 97–99 (2006)

    Article  CAS  Google Scholar 

  27. A. Sattar, A. Samy, J. Mater. Sci. 37(20), 4499–4502 (2002)

    Article  CAS  Google Scholar 

  28. A. Dzunuzovic, M. Vijatovic Petrovic, N. Ilic, J. Bobic, B. Stojanovic, Process Appl. Ceram. 13, 113 (2019)

    Article  Google Scholar 

  29. R. Sagar, R. Raibagkar, J. Alloy. Compd. 549, 206–212 (2013)

    Article  CAS  Google Scholar 

  30. A. Mahmood, A. Naeem, Y. Iqbal, Ceram. Int. 42(4), 4860–4865 (2016)

    Article  CAS  Google Scholar 

  31. R. Qindeel, N. Alonizan, Curr. Appl. Phys. 18(5), 519–525 (2018)

    Article  Google Scholar 

  32. C. Ciomaga, A. Neagu, M. Pop, M. Airimioaei, S. Tascu, G. Schileo, C. Galassi, L. Mitoseriu, J. Appl. Phys. 113, 074103 (2013)

    Article  CAS  Google Scholar 

  33. J. Irvine, D. Sinclair, A. West, Adv. Mater. 2(3), 132–138 (1990)

    Article  CAS  Google Scholar 

  34. G. Yang, E. Dickey, C. Randall, D. Barber, P. Pinceloup, M. Henderson, R. Hill, J. Beeson, D. Skamser, J. Appl. Phys. 96(12), 7492–7499 (2004)

    Article  CAS  Google Scholar 

  35. K. Verma, S. Sharma, Phys. Status Solidi B 249(1), 209–216 (2012)

    Article  CAS  Google Scholar 

  36. O. Reymond, R. Font, N. Almodovac, J. Poetelles, J. Siqueiros, J. Appl. Phys. 97(8), 084107 (2005)

    Article  CAS  Google Scholar 

  37. M.A. Rafiq, M.N. Rafiq, K. Saravanan, Ceram. Int. 41(9), 11436–11444 (2015)

    Article  CAS  Google Scholar 

  38. T. Badapanda, S. Sarangi, B. Behera, S. Anwar, Curr. Appl. Phys. 14(9), 1192–1200 (2014)

    Article  Google Scholar 

  39. P. Kumar, S. Singh, M. Spah, J. Juneja, C. Prekash, K. Raina, J. Alloys Compd. 489(1), 59–63 (2010)

    Article  CAS  Google Scholar 

  40. S. Sen, S.K. Mishra, S.K. Das, A. Tarafdar, J. Alloys Compd. 453(1-2), 395–400 (2008)

    Article  CAS  Google Scholar 

  41. M. Dar, V. Verma, S. Gairola, W. Siddiqui, R. Singh, R. Kotnala, Appl. Surf. Sci. 258(14), 5342–5347 (2012)

    Article  CAS  Google Scholar 

  42. R. Gerhardt, J. Phys. Chem. Solids 55(12), 1491 (1994)

    Article  CAS  Google Scholar 

  43. S. Kumar, K. Varma, Curr. Appl. Phys. 11(2), 203–210 (2011)

    Article  Google Scholar 

  44. M. Vijatovic Petrovic, J. Bobic, H. Ursic, J. Banys, B. Stojanovic, J. Sol-Gel Sci. Technol. 67(2), 267–272 (2013)

    Article  CAS  Google Scholar 

  45. M. Vijatovic Petrovic, J. Bobic, R. Grigalaitis, N. Ilic, A. Dzunuzovic, V. Jankauskaite, J. Banys, B. Stojanovic, Ceram. Int. 41(9), 11365–11371 (2015)

    Article  CAS  Google Scholar 

  46. Y. Tan, J. Zhang, Z. Wu, C. Wang, V. Koval, B. Shi, H. Ye, R. McKinnon, G. Viola, H. Yan, Sci. Rep. 5(1), 9953 (2015)

    Article  CAS  Google Scholar 

  47. P. Pahuja, R. Kontala, R. Tandol, J. Alloy. Compd. 617, 140–148 (2014)

    Article  CAS  Google Scholar 

  48. N. Kitamura, T. Mizoguchi, T. Itoh, Y. Idemoto, J. Solid State Chem. 210, 279 (2014)

    Article  CAS  Google Scholar 

  49. N. Buatip, N. Promsawat, N. Pisitpipathsin, O. Namsar, P. Pawasri, K. Ounsung, K. Phabsimma, S. Rattanachan, P. Janphuang, S. Projprapai, Integr. Ferroelectr. 187(1), 45–52 (2018)

    Article  CAS  Google Scholar 

  50. H. Du, W. Liang, Y. Li, M. Gao, Y. Zhang, C. Chen, Y. Lin, J. Alloy. Compd. 645, 166 (2015)

    Article  CAS  Google Scholar 

  51. V. Janardhanam, Y. Park, K. Ahn, C. Choi, J. Alloy. Compd. 534, 37–41 (2012)

    Article  CAS  Google Scholar 

  52. S. Godara, B. Kumar, Ceram. Int. 41(5), 6912–6919 (2015)

    Article  CAS  Google Scholar 

Download references

Acknowledgments

The authors gratefully acknowledge the financial support of the ministry of Education, Science and Technological Development of the Republic of Serbia (Project III45021).

Author information

Authors and Affiliations

  1. Institute for Multidisciplinary Research, University of Belgrade, Belgrade, Serbia

    Adis S. Dzunuzovic, M. M. Vijatovic Petrovic, J. D. Bobic, N. I. Ilic & B. D. Stojanovic

Authors
  1. Adis S. Dzunuzovic
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. M. M. Vijatovic Petrovic
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. J. D. Bobic
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. N. I. Ilic
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. B. D. Stojanovic
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Adis S. Dzunuzovic.

Additional information

Publisher’s note

Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Dzunuzovic, A.S., Petrovic, M.M.V., Bobic, J.D. et al. Influence of ferrite phase on electrical properties of the barium zirconium titanate based multiferroic composites. J Electroceram 46, 57–71 (2021). https://doi.org/10.1007/s10832-021-00244-9

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10832-021-00244-9

Keywords

Search

Navigation