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Optical and Electromagnetic Properties of LaCoO3:Li+;M2+ (M = Ca, Sr, Ba)

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Journal of Applied Spectroscopy Aims and scope

Lanthanum cobaltates modified by alkaline-earth-metal (0.10 mol%) and lithium (0.05 mol%) ions were synthesized. The samples had an orthorhombic distorted perovskite-like structure according to x-ray diffraction phase analysis. Addition of Li+ and M2+ (M = Ca, Sr, Ba) to the LaCoO3 matrix was shown to increase the unit-cell parameters, the optical band width (Eg), and the average Co oxidation state (Con+). Pure and doped LaCoO3 were characterized by the presence of paramagnetic centers as isolated structural and surface Co2+ ions and adsorption complexes [Co3 + ⋯ O −2 ]· on the surface of the oxide matrix at a concentration that increased in the order Ba > Sr > Ca. The cobaltates were found to possess Mott hopping conduction in the temperature range 77–298 K.

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References

  1. M. Kriener, M. Braden, H. Kierspel, D. Senff, O. Zabara, C. Zobel, and T. Lorenz, Phys. Rev. B: Condens. Matter Mater. Phys., 79, No. 22, 224104(1–9) (2009).

  2. M. Kriener, C. Zobel, A. Reichl, J. Baier, M. Cwik, K. Berggold, H. Kierspel, O. Zabara, A. Freimuth, and T. Lorenz, Phys. Rev. B: Condens. Matter Mater. Phys., 69, No. 9, 094417(1–7) (2004).

  3. O. A. Drozhzhin and S. V. Chernov, Al′tern. Energ. Ekol., 2, 99–105 (2008).

    Google Scholar 

  4. N. N. Oleynikov and V. A. Ketsko, Russ. J. Inorg. Chem., 49, No. 1, 1–21 (2004).

    Google Scholar 

  5. J. Shi, R. Yan, Y. Zhu, and X. Zhang, Talanta, 61, No. 2, 157–164 (2003).

    Article  Google Scholar 

  6. P. R. N. Silva and A. B. Soares, Eclet. Quim., 34, No. 1, 31–38 (2009).

    Article  Google Scholar 

  7. E. A. Lombardo and M. A. Ulla, Res. Chem. Intermed., 24, No. 5, 581–592 (1998).

    Article  Google Scholar 

  8. B. Yang, S. Aggarwal, A. M. Dhote, T. K. Song, R. Ramesh, and J. S. Lee, Appl. Phys. Lett., 71, No. 3, 356–358 (1997).

    Article  ADS  Google Scholar 

  9. T. Saitoh, T. Mizokawa, A. Fujimori, M. Abbate, Y. Takeda, and M. Takano, Phys. Rev. B: Condens. Matter Mater. Phys., 56, No. 3, 1290–1295 (1997).

    Article  ADS  Google Scholar 

  10. J. B. Goodenough, J. Phys. Chem. Solids, 6, Nos. 2–3, 287–297 (1958).

    Article  ADS  Google Scholar 

  11. M. A. Korotin, S. Yu. Ezhov, I. V. Solovyev, V. I. Anisimov, D. I. Khomskii, and G. A. Sawatzky, Phys. Rev. B: Condens. Matter Mater. Phys., 54, No. 8, 5309–5316 (1996).

    Article  ADS  Google Scholar 

  12. V. P. Plakhty, P. J. Brown, B. Grenier, S. V. Shiryaev, S. V. Barilo, S. V. Gavrilov, and E. Ressouche, J. Phys.: Condens. Matter, 18, No. 13, 3517–3525 (2006).

    ADS  Google Scholar 

  13. K. Asai, A. Yoneda, O. Yokokura, J. M. Tranquada, G. Shirane, and K. Kohn, J. Phys. Soc. Jpn., 67, No. 1, 290–296 (1998).

    Article  ADS  Google Scholar 

  14. A. Podlesnyak, K. Conder, E. Pomjakushina, A. Mirmelstein, P. Allenspach, and D. I. Khomskii, J. Magn. Magn. Mater., 310, No. 2, 1552–1554 (2007).

    Article  ADS  Google Scholar 

  15. S. Yamaguchi, Y. Okimoto, H. Taniguchi, and Y. Tokura, Phys. Rev. B: Condens. Matter Mater. Phys., 53, No. 6, R2926–R2929 (1996).

    Article  ADS  Google Scholar 

  16. D. Bhadur, B. Ram, and B. S. Murthy, Phys. Status Solidi B, 154, No. 1, 297–303 (1989).

    Article  ADS  Google Scholar 

  17. T. He, J. Chen, T. G. Calvarese, and M. A. Subramanian, Solid State Sci., 8, No. 5, 467–469 (2006).

    Article  ADS  Google Scholar 

  18. A. B. Amor, M. Koubaa, W. Cheikhrouhou-Koubaa, and A. Cheikhrouhou, J. Alloys Cmpd., 457, Nos. 1–2, 1–5 (2008).

    Article  Google Scholar 

  19. M. B. Bellakki, C. Madhu, T. Greindl, S. Kohli, P. McCurdy, and V. Manivannan, Rare Met., 29, No. 5, 491–500 (2010).

    Article  Google Scholar 

  20. C. Zhang, H. Hen, N. Wang, H. Chen, and D. Kong, Ceram. Int., 39, No. 4, 3685–3689 (2013).

    Article  Google Scholar 

  21. B. Dong, Z. Li, Z. Li, X. Xu, M. Song, W. Zheng, C. Wang, S. S. Al-Deyab, and M. El-Newehy, J. Am. Ceram. Soc., 93, No. 11, 3587–3590 (2010).

    Article  Google Scholar 

  22. P. Scherrer, Nachr. Ges. Wissen. Gottingen. Math.-Physik. Klasse, 26, 98–100 (1918).

    Google Scholar 

  23. V. A. Kulichenko, S. A. Nedilko, and O. G. Dziazko, Visn. Kiiv. Univ., Khim., 33, 130–132 (1996).

    Google Scholar 

  24. Y. Y. Kim, D. H. Lee, T. Y. Kwon, and S. H. Park, J. Solid State Chem., 112, No. 2, 376–380 (1994).

    Article  ADS  Google Scholar 

  25. N. N. Lubinskii, L. A. Bashkirov, G. S. Petrov, S. V. Shevchenko, I. N. Kandidatova, and M. V. Bushinskii, Glass Ceram., 66, Nos. 1–2, 59–62 (2009).

    Article  Google Scholar 

  26. D. Berger, N. van Landschoot, C. Ionica, F. Papa, and V. Fruth, J. Optoelectron. Adv. Mater., 5, No. 3, 719–724 (2003).

    Google Scholar 

  27. J. Tauc, R. Grigorovici, and A. Vancu, Phys. Status Solidi B, 15, No. 2, 627–637 (1966).

    Article  ADS  Google Scholar 

  28. L. F. Liotta, G. Pantaleo, A. Macaluso, G. Di Carlo, and G. Deganello, Appl. Catal., A, 147, No. 1, 167–177 (2003).

    Article  Google Scholar 

  29. M. B. Bellakki, J. Das, and V. Manivannan, J. Electroceram., 24, No. 4, 319–325 (2010).

    Article  Google Scholar 

  30. S. Ivanova, A. Senyshyn, E. Zhecheva, K. Tenchev, V. Nikolov, R. Stoyanova, and H. Fuess, J. Alloys Cmpd., 480, No. 2, 279–285 (2009).

    Article  Google Scholar 

  31. S. Ivanova, E. Zhecheva, and R. Stoyanova, J. Phys. Chem. Solids, 68, No. 2, 168–174 (2007).

    Article  ADS  Google Scholar 

  32. S. Ivanova, A. Senyshyn, E. Zhecheva, K. Tenchev, R. Stoyanova, and H. Fuess, J. Solid State Chem., 183, No. 4, 940–950 (2010).

    Article  ADS  Google Scholar 

  33. C. Oliva, L. Forni, A. D’Ambrosio, F. Navarrini, A. D. Stepanov, Z. D. Kagramanov, and A. I. Mikhailichenko, Appl. Catal., A, 205, Nos. 1–2, 245–252 (2001).

    Article  Google Scholar 

  34. E. V. Makshina, E. A. Zhilinskaya, A. Abukais, and B. V. Romanovskii, Vestn. Mosk. Univ., Ser. 2: Khim., 48, No. 1, 9–11 (2007).

    Google Scholar 

  35. E. V. Makshina, E. A. Zhilinskaya, S. Siffert, G. N. Mazo, A. Aboukais, W. Grunert, and B. V. Romanovskii, J. Exp. Nanosci., 5, No. 5, 427–437 (2010).

    Article  Google Scholar 

  36. K. Tomiyasu, Y. Kubota, S. Shimomura, M. Onodera, S.-I. Koyama, T. Nojima, S. Ishihara, H. Nakao, and Y. Murakami, Phys. Rev. B: Condens. Matter Mater. Phys., 87, No. 22, 224409(1–8) (2013).

  37. A. Podlesnyak, M. Russina, A. Furrer, A. Alfonsov, E. Vavilova, V. Kataev, B, Buchner, T. Strassle, E. Pomjakushina, K. Conder, and D. I. Khomskii, Phys. Rev. Lett., 101, No. 24, 247603(1–4) (2008).

  38. S. Royer, F. Berube, and S. Kaliaguine, Appl. Catal., A, 282, Nos. 1–2, 273–284 (2005).

    Google Scholar 

  39. D. Cordischi, V. Indovina, M. Occhiuzzi, and A. Arieti, J. Chem. Soc. Faraday Trans. 1, 75, 533–544 (1979).

    Article  Google Scholar 

  40. S. Kaliaguine, A. Van Neste, V. Szabo, J. E. Gallot, M. Bassir, and R. Muzychuk, Appl. Catal., A, 209, Nos. 1–2, 345–358 (2001).

    Article  Google Scholar 

  41. A. A. Kozlovskii, V. F. Khirnyi, A. V. Semenov, and V. M. Puzikov, Fiz. Tverd. Tela, 53, No. 4, 660–668 (2011).

    Google Scholar 

  42. Y. Liu and X. Y. Qin, J. Phys. Chem. Solids, 67, No. 8, 1893–1898 (2011).

    Article  ADS  Google Scholar 

  43. J. S. Park, S. Y. Park, H. G. Park, S. M. Kim, and Y. P. Lee, J. Korean Phys. Soc., 41, No. 5, 732–738 (2002).

    Google Scholar 

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Authors and Affiliations

  1. Taras Shevchenko National University of Kyiv, 64/13 Volodymyrska Str., Kyiv, 01601, Ukraine

    I. V. Fesich, A. G. Dziazko & S. A. Nedilko

  2. G. V. Kurdyumov Institute for Metal Physics, National Academy of Sciences of Ukraine, Kyiv, Ukraine

    V. V. Trachevsky

  3. Institute for Sorption and Problems of Endoecology, Kyiv, Ukraine

    A. K. Melnik

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  1. I. V. Fesich
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  2. V. V. Trachevsky
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  3. A. G. Dziazko
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  4. S. A. Nedilko
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Translated from Zhurnal Prikladnoi Spektroskopii, Vol. 81, No. 4, pp. 569–577, July–August, 2014.

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Fesich, I.V., Trachevsky, V.V., Dziazko, A.G. et al. Optical and Electromagnetic Properties of LaCoO3:Li+;M2+ (M = Ca, Sr, Ba). J Appl Spectrosc 81, 624–632 (2014). https://doi.org/10.1007/s10812-014-9980-z

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  • DOI: https://doi.org/10.1007/s10812-014-9980-z

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