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Predicting and Correlating Speed of Sound in Long-Chain Alkanes at High Pressure

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Abstract

The purpose of the current study is twofold: first, to propose a group contribution method able to predict speed of sound in high molecular weight n-alkanes based on group decomposition into two groups (pentyl and methylene); second, to present correlations of speed of sound as a function of temperature and pressure for each pure component in the n-alkane series from n-C10 to n-C36 in the temperature range from 293.15 to 423.15 K and for pressures of up to 150 MPa, using available experimental data supplemented by group contribution predictions to make up for the lack of data in the case of some n-alkanes. The uncertainties of the proposed correlations are 0.1% at atmospheric pressure and 0.2% (with a 95% confidence level) across the entire high-pressure range.

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  1. Laboratoire des Fluides Complexes et Leurs Réservoirs, UMR5150, E2S UPPA, CNRS/TOTAL/Univ Pau & Pays Adour, 64000, Pau, France

    Jean-Luc Daridon

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Daridon, JL. Predicting and Correlating Speed of Sound in Long-Chain Alkanes at High Pressure. Int J Thermophys 43, 78 (2022). https://doi.org/10.1007/s10765-022-02999-x

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