Abstract
A method for creating of a three-dimensional nonlinear optical grating based on the alternation of layers with different nonlinear optical properties has been developed. The spatial structure of the lattice is formed by an active layer from a polymethylmethacrylate (PMMA) matrix with dimethyl amino -4-n-methylstilbazolium-tosylate (DAST) nanocrystals and a photopolymer used as an inactive layer. The absorption and refraction terahertz spectral dependencies of the photopolymerizable composition and the DAST - PMMA nanocomposite have been studied. Obtained results allow us to consider this material as a good candidate for terahertz photonics. The processes of terahertz generation in the DAST - PMMA nanocomposite by the optical rectification of femtosecond laser pulses have been investigated and high generation efficiency have been demonstrated. The nonlinear optical grating based on the indicated components was created and its structure was investigated.
Similar content being viewed by others
Data availability
The data that support the findings of this study are available from the authors on reasonable request.
References
Dhillon S.S., Vitiello M.S., Linfield E.H., Davies A.G., Hoffmann M.C., Booske J., Paoloni C., Gensch M., Weightman P., Williams G.P., Castro-Camus E., Cumming D.R.S., Simoens F., Escorcia-Carranza I., Grant J., Lucyszyn S., Kuwata-Gonokami M., Konishi K., Koch M., Schmuttenmaer C.A., Cocker T.L., Huber R., Markelz A.G., Taylor Z.D., Wallace V.P., Zeitler J.A., Sibik J., Korter T.M., Ellison B., Rea S., Goldsmith P., Cooper K.B., Appleby R., Pardo D., Huggard P.G., Krozer V., Shams H., Fice M., Renaud C., Seeds A., Stöhr A., Naftaly M., Ridler N., Clarke R., Cunningham J.E., Johnston M.B. The 2017 terahertz science and technology roadmap. Journal of Physics D: Applied Physics, 50(5):043001, 2017.
Bespalov V.G., Gorodetskiı̆; A.A., Denisyuk I.Y., Kozlov S.A., Krylov V.N., Lukomskiı̆; G.V., Petrov N.V., and Putilin S.E. Methods of generating superbroadband terahertz pulses with femtosecond lasers. Journal of Optical Technology, 75(10):636–642, 2008.
Xu L., Zhang X.-C., and Auston D.H. Terahertz beam generation by femtosecond optical pulses in electro-optic materials. Applied Physics Letters, 61:1784–1786, 1992.
Lee S.H., Jazbinsek M., Hauri C.P., and Kwon O.P. Recent progress in acentric core structures for highly efficient nonlinear optical crystals and their supramolecular interactions and terahertz applications. CrystEngComm, 18(38):7180–7203, 2016.
Schneider A. and Günter P. Spectrum of terahertz pulses from organic dast crystals. Ferroelectrics, 318(1):83–88, 2005.
Pan F., Knopfle G., Bosshard Ch., Follonier S., Spreiter R., Wong M., and Gunter P. Electro-optic properties of the organic salt 4-n,n-dimethylamino-4-n-methyl-stilbazolium tosylate. Applied Physics Letters, 69(1):13–15, 1996.
Ruiz B., Jazbinsek M., and Gunter P. Crystal growth of dast. Crystal Growth and Design, 8(11):4173–4184, 2008.
Lee Y.S., Meade T., Perlin V., Winful H., Norris T.B., and Galvanauskas A. Generation of narrow-band terahertz radiation via optical rectification of femtosecond pulses in periodically poled lithium niobate. Applied Physics Letters, 76(18):2505–2507, 2000.
Denisyuk I.Y., Ozheredov I., Sinko A., Fokina M., Pogosian T., Ignateva I., Diep Lai N., and Ledoux-Rak I. Optical properties of photobleached dast molecular crystals in terahertz domain. Journal of Infrared, Millimeter, and Terahertz Waves, 41(9):1082–1088, 2020.
Stepanov A.G., Bonacina L., and Wolf J.P. Dast/sio 2 multilayer structure for efficient generation of 6 thz quasi-single-cycle electromagnetic pulses. Optics letters, 37(13):2439–2441, 2012.
Denisyuk I.Y., Fokina M.I., Vorzobova N.D., Burunkova Y.E., and Bulgakova V.G. Microelements with high aspect ratio preparedby self-focusing of light at uv-curing. Molecular Crystals and Liquid Crystals, 497(1):228–235, 2008.
Burunkova J.A., Denisyuk I.Y., and Fokina M.I. Polymer composite based on dast submicron crystals: technology and properties. Molecular Crystals and Liquid Crystals, 159(1):178–182, 2014.
Pogosian T.N., Denisyuk I.Y., and Lai N.D. Influence of dimensional parameters of dast nanocrystals on their linear and nonlinear optical parameters. Optics and Spectroscopy, 126(3):262–264, 2019.
Macchi R., Cariati E., Marinotto D., Roberto D., Tordin E., Ugo R., Bozio R., Cozzuol M., Pedron D., and Mattei G. Stable shg from in situ grown oriented nanocrystals of [(e)- n,n-dimethylamino-n’-methylstilbazolium][p-toluenesulfonate] in a pmma film. Journal of Materials Chemistry, 20:1885–1890, 2010.
Izaddeen Kabir Yakasai, Pg. Emeroylariffion Abas, and Feroza Begum. Review of porous core photonic crystal fibers for terahertz waveguiding. Optik, 229:166294, 2021.
Mottamchetty Venkatesh, K. Thirupugalmani, K. S. Rao, S. Brahadeeswaran, and A. K. Chaudhary. Generation of efficient THz radiation by optical rectification in DAST crystal using tunable femtosecond laser pulses. Indian Journal of Physics, 91(3):319–326, March 2017.
K. Kawase, M. Mizuno, S. Sohma, H. Takahashi, T. Taniuchi, Y. Urata, S. Wada, H. Tashiro, and H. Ito. Difference-frequency terahertz-wave generation from 4-dimethylamino-N-methyl-4-stilbazolium-tosylate by use of an electronically tuned Ti:sapphire laser. Optics Letters, 24(15):1065–1067, 1999.
C. Kealhofer, W. Schneider, D. Ehberger, A. Ryabov, F. Krausz, and P. Baum. All-optical control and metrology of electron pulses. Science, 352(6284):429–433, 2016.
Acknowledgements
The THz spectral measurements and the study of THz generation efficiency were performed according to the Development program of the Interdisciplinary Scientific and Education School of Lomonosov Moscow State University “Photonics and Quantum technologies. Digital medicine”, partially supported by Ministry of Science and Higher Education of the Russian Federation in framework of Agreement No. 075-15-2022-830 from 27 May 2022 (Prolongation of Agreement No. 075-15-2021-1358 from 12 October 2021) and within the State assignment FSRC “Crystallography and Photonics” RAS.
Funding
This work was supported the Russian Foundation for Basic Research projects no. 18-52-16014 and no. 20-32-90234.
Author information
Authors and Affiliations
Corresponding author
Ethics declarations
Conflict of Interest
The authors declare no competing interests.
Additional information
Publisher’s Note
Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.
Rights and permissions
Springer Nature or its licensor holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.
About this article
Cite this article
Denisyuk, I., Ozheredov, I., Fokina, M. et al. Terahertz Properties of Polymers for 2D Nonlinear Grating Formation. J Infrared Milli Terahz Waves 43, 972–982 (2022). https://doi.org/10.1007/s10762-022-00878-y
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10762-022-00878-y