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Mössbauer studies of interactions between titanium atoms dissolved in iron

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Abstract

The room temperature 57Fe Mössbauer spectra for binary iron-based solid solutions Fe1 − x Ti x , with x in the range 0.010 ≤ x ≤ 0.045, were analysed in terms of binding energy E b between two Ti atoms in the Fe-Ti system. The extrapolated values of E b for x = 0 were used for computation of enthalpy of solution of titanium in iron. The results were compared with that resulting from the Miedema’s model of alloys as well as those derived from the heat of formation of the system, obtained with both calorimetric measurements and theoretical calculations. The comparison shows that our Mössbauer spectroscopy findings are in a quite good agreement with all the other results mentioned above.

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Authors and Affiliations

  1. Institute of Experimental Physics, University of Wrocław, pl. M. Borna 9, Wrocław, 50-204, Poland

    Robert Konieczny, Rafał Idczak & Jan Chojcan

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  1. Robert Konieczny
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  2. Rafał Idczak
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  3. Jan Chojcan
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Correspondence to Robert Konieczny.

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Konieczny, R., Idczak, R. & Chojcan, J. Mössbauer studies of interactions between titanium atoms dissolved in iron. Hyperfine Interact 219, 121–127 (2013). https://doi.org/10.1007/s10751-012-0653-0

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