Abstract
The structure of PAN gel fibres spun by the water-thiocyanate method is investigated. It is shown that in identical spinning conditions, the packing density of the structural elements in gel fibres based on poly(AN-co-MA-co-ItA)terpolymer is lower than in gel fibres based on poly(AN-co-MA-co-AMPS). A structural model of PAN gel fibre is composed and substantiated. It is shown that the lower packaging density of the structural elements in PAN gel fibres is responsible for the higher sorption power with respect to different inorganic and organic compounds and higher rate polymer-analog transformations.
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REFERENCES
B. E. Geller, Some Characteristic of “Wet” Spinning of Carbochain Polymers, Doctoral Dissertation, Leningrad (1964).
F.-G. Nimts, A. A. Geller, B. Kh. Yunusov and B. E. Geller, Khim. Volokna, No. 3, 11–13 (1986).
S. A. Kamalov, F. N. Dautova and B. E. Geller Khim. Volokna, No. 5, 5–7 (1963).
S. J. Law S. K. Mukhopadhyay (1994) J. Appl. Polym. Sci. 65 2131–2137
S. J. Law S. K. Mukhopadhyay (1998) J. Appl. Polym. Sci. 69 1459–1469
Z. Bashir, Ind. J. Fibre Text. Res., No. 1, 4–9 (1998).
Z. Bashir (2001) J. Macromol. Sci. Phys. B40 IssueID1 41–43
A. T. Kalashik, O. N. Panichkina, et al., Khim. Volokna, No. 6, 18–23 (2002).
A. A. Askadskii V. I. Kondrashenko (1999) Computer Modeling of Polymers. Vol. 1. Atomic-Molecular Level Nauchnyi Mir Moscow
A. W. Adamson (1960) Physical Chemistry of Surfaces Interscience New York
S. P. Matveeva, B. E. Geller and A. B. Pakshver, Izv. Vyssh. Uchebn. Zaved., Khim. Khim. Technol., No. 3, 553–558 (1958).
A. A. Geller and B. E. Geller Khim. Volokna, No.3 8–17 (1990).
D. W. Krevelen ParticleVan (1990) Properties of Polymers EditionNumber3rd Ed. Elsevier Amstersdam 875
G. I. Kudryavtsev, Fabrication of Modified Fibres Using Polymer Chain Reactions, Doctoral Dissertation, Leningrad (1966).
G. M. Mubarakshin L. A. Vol’f et al. (1983) Zh. Prikl. Khim. 56 IssueID7 1506–1509
Yu. A. Mikheev L. N. Guseva G. E. Zaikov (1996) Khim. Fiz. 15 IssueID1 7–13
Yu. A. Mikheev G. E. Zaikov (1999) Vysokomolek. Soedin. A41 IssueID5 852–860
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Translated from Khimicheskie Volokna, No. 5, pp. 40–45, September–October, 2004.
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Budkute, I.A., Geller, B.E. & Shcherbina, L.A. Experimental study of the structure of polyacrylonitrile gel fibres. Fibre Chem 36, 358–364 (2004). https://doi.org/10.1007/s10692-005-0009-5
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DOI: https://doi.org/10.1007/s10692-005-0009-5