Abstract
We discuss a thin film evolution equation for a wetting evaporating liquid on a smooth solid substrate. The model is valid for slowly evaporating small sessile droplets when thermal effects are insignificant, while wettability and capillarity play a major role. The model is first employed to study steady evaporating drops that are fed locally through the substrate. An asymptotic analysis focuses on the precursor film and the transition region towards the bulk drop and a numerical continuation of steady drops determines their fully non-linear profiles. Following this, we study the time evolution of freely evaporating drops without influx for several initial drop shapes. As a result we find that drops initially spread if their initial contact angle is larger than the apparent contact angle of large steady evaporating drops with influx. Otherwise they recede right from the beginning.
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Leizerson I, Lipson SG, Lyushnin AV (2003) When larger drops evaporate faster. Nature 422: 395–396
Samid-Merzel N, Lipson SG, Tannhauser DS (1998) Pattern formation in drying water films. Phys Rev E 57: 2906–2913
Deegan RD (2000) Pattern formation in drying drops. Phys Rev E 61: 475–485
Deegan RD, Bakajin O, Dupont TF, Huber G, Nagel SR, Witten TA (1997) Capillary flow as the cause of ring stains from dried liquid drops. Nature 389: 827–829
Huang J, Kim F, Tao AR, Connor S, Yang P (2005) Spontaneous formation of nanoparticle stripe patterns through dewetting. Nat. Mater. 4: 896–900
Thiele U, Mertig M, Pompe W (1998) Dewetting of an evaporating thin liquid film: heterogeneous nucleation and surface instability. Phys Rev Lett 80: 2869–2872
Ajaev VS (2005) Spreading of thin volatile liquid droplets on uniformly heated surfaces. J Fluid Mech 528: 279–296
Anderson DM, Davis SH (1995) The spreading of volatile liquid droplets on heated surfaces. Phys Fluids 7: 248–265
Cachile M, Benichou O, Cazabat AM (2002) Evaporating droplets of completely wetting liquids. Langmuir 18: 7985–7990
Pomeau Y (2002) Recent progress in the moving contact line problem: a review. C R Mec 330: 207–222
Wayner PC (1993) Spreading of a liquid film with a finite contact angle by the evaporation/condensation process. Langmuir 9: 294–299
Bonn D, Eggers J, Indekeu J, Meunier J, Rolley E (2009) Wetting and spreading. Rev Mod Phys 81: 739–805
Starov VM, Velarde MG, Radke CJ (2007) Wetting and spreading dynamics. Taylor and Francis, Boca Raton
Shahidzadeh-Bonn N, Rafaï S, Azouni A, Bonn D (2006) Evaporating droplets. J Fluid Mech 549: 307–313
Hocking LM (1995) On contact angles in evaporating liquids. Phys. Fluids 7: 2950–2954
Poulard C, Guena G, Cazabat A-M, Boudaoud A, Ben Amar M (2005) Rescaling the dynamics of evaporating drops. Langmuir 21: 8226
Deegan RD, Bakajin O, Dupont TF, Huber G, Nagel SR, Witten TA (2000) Contact line deposits in an evaporating drop. Phys Rev E 62: 756–765
Dunn GJ, Wilson SK, Duffy BR, David S, Sefiane K (2009) The strong influence of substrate conductivity on droplet evaporation. J. Fluid Mech. 623: 329–351
Sefiane K, Wilson SK, David S, Dunn GJ, Duffy BR (2009) On the effect of the atmosphere on the evaporation of sessile droplets of water. Phys Fluids 21: 062101
Lyushnin AV, Golovin AA, Pismen LM (2002) Fingering instability of thin evaporating liquid films. Phys Rev E 65: 021602
Padmakar A, Kargupta K, Sharma A (1999) Instability and dewetting of evaporating thin water films on partially and completely wettable substrates. J Chem Phys 110: 1735–1744
Pismen LM (2004) Spinodal dewetting in a volatile liquid film. Phys Rev E 70: 021601
Rednikov AY, Colinet P (2010) Vapor-liquid steady meniscus at a superheated wall: asymptotics in an intermediate zone near the contact line. Microgravity Sci. Technol. 22: 249–255
Ajaev VS, Gambaryan-Roisman T, Stephan P (2010) Static and dynamic contact angles of evaporating liquids on heated surfaces. J Colloid Interface Sci 342: 550–558
Oron A, Davis SH, Bankoff SG (1997) Long-scale evolution of thin liquid films. Rev Mod Phys 69: 931–980
Thiele U (2010) Thin film evolution equations from (evaporating) dewetting liquid layers to epitaxial growth. J Phys Condens Matter 22: 084019
de Gennes P-G (1985) Wetting: statics and dynamics. Rev Mod Phys 57: 827–863
Israelachvili JN (2010) Intermolecular and surface forces. Academic Press, London
Kalliadasis, S, Thiele, U (eds) (2007) Thin films of soft matter. Springer, Wien
Ruckenstein E, Jain RK (1974) Spontaneous rupture of thin liquid films. J Chem Soc Faraday Trans II 70: 132–147
Sharma A (1993) Relationship of thin film stability and morphology to macroscopic parameters of wetting in the apolar and polar systems. Langmuir 9: 861–869
Thiele U (2007) Structure formation in thin liquid films. In: Kalliadasis S, Thiele U (eds) Thin films of soft matter. Springer, Wien, pp 25–93
Starov VM, Velarde MG (2009) Surface forces and wetting phenomena. J Phys Condes Matter 21: 464121
Morris SJS (2001) Contact angles for evaporating liquids predicted and compared with existing experiments. J Fluid Mech 432: 1–30
Morris SJS (2003) The evaporating meniscus in a channel. J Fluid Mech 494: 297–317
Doedel E, Keller HB, Kernevez JP (1991) Numerical analysis and control of bifurcation problems (I) bifurcation in finite dimensions. Int J Bifurc Chaos 1: 493–520
Doedel E, Keller HB, Kernevez JP (1991) Numerical analysis and control of bifurcation problems (II) bifurcation in infinite dimensions. Int J Bifurc Chaos 1: 745–772
Doedel EJ, Champneys AR, Fairgrieve TF, Kuznetsov YA, Sandstede B, Wang XJ (2000) AUTO97: continuation and bifurcation software for ordinary differential equations. Concordia University, Montreal
Thiele U, Neuffer K, Bestehorn M, Pomeau Y, Velarde MG (2002) Sliding drops on an inclined plane. Colloid Surf A 206: 87–104
John K, Bär M, Thiele U (2005) Self-propelled running droplets on solid substrates driven by chemical reactions. Eur Phys J E 18: 183–199
Thiele U, Knobloch E (2006) On the depinning of a driven drop on a heterogeneous substrate. New J Phys 8(313): 1–37
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Todorova, D., Thiele, U. & Pismen, L.M. The relation of steady evaporating drops fed by an influx and freely evaporating drops. J Eng Math 73, 17–30 (2012). https://doi.org/10.1007/s10665-011-9485-1
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DOI: https://doi.org/10.1007/s10665-011-9485-1