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Health risk assessment of workers’ exposure to BTEX and PM during refueling in an urban fuel station

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Abstract

The proximity of fuel stations to the roads and the activities inside the station can contribute to PM and VOCs and impose health risks on station workers. The study presents the exposure and health risk assessment of the fuel station personnel to total volatile organic compounds (TVOCs) and particulate matter (PM) during refueling operations. TVOCs and PM monitoring were carried out at a fuel station in Chennai, India, for 1 week in March 2021, covering both weekdays and weekends. The health risks were assessed using EPA’s health impact assessment methodology. Exposure to TVOCs (3177.39 ± 5450.32 μg/m3) exceeded the EPA standard of 5 μg/m3, by more than 500 times, peaking during refueling operations. The average concentrations of PM10, PM2.5, and PM1 were 76.55 ± 23.08 μg/m3, 41.81 ± 9 μg/m3, and 30.38 ± 7.56 μg/m3, respectively. The concentrations were observed to be high during morning and evening hours due to the increased traffic on the adjacent road and inside the fuel station. The synergistic health risks linked with long-term exposure to high concentrations of BTEX and PM were also estimated. At the fuel station, a significant contribution to the SOA formation potential was shown by toluene, followed by m-xylene, p-xylene, o-xylene, ethylbenzene, and benzene. Furthermore, the deposition of airborne particles in the workers’ respiratory tract was calculated using the Multiple Path Particle Dosimetry model while considering the daily average exposure duration of 12 h. The results showed that 59% of PM10 particles were deposited in the head region, whereas 11% and 10% of PM2.5 and PM1 particles were deposited in the pulmonary region. Hence, the health risk assessment indicated no non-cancer risk of exposure to PM (hazard quotient = 0.13) to station personnel exposed regularly for 1 year. However, prolonged exposure to VOCs for more than 1 year can result in both carcinogenic and non-carcinogenic risk (hazard quotient = 0.045 and cancer risk > 10−6) in workers.

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All the data generated and analyzed in this study are presented in the paper and supplementary material.

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Acknowledgements

We appreciate the authorities and employees at the fuel station for their cooperation and support during the monitoring campaign.

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All authors contributed to the study conception and design. Material preparation, data collection and analysis, and manuscript preparation were performed by Sruthi Jayaraj. Shiva Nagendra S.M. commented on previous drafts of the manuscript.

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Correspondence to S.M. Shiva Nagendra.

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This manuscript describes the original research work and is not under consideration by any other journal. We have not submitted this paper to any preprint servers before submitting it to Environmental Monitoring & Assessment. All authors approved the manuscript and this submission.

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Jayaraj, S., Shiva Nagendra, S. Health risk assessment of workers’ exposure to BTEX and PM during refueling in an urban fuel station. Environ Monit Assess 195, 1507 (2023). https://doi.org/10.1007/s10661-023-12130-8

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