Skip to main content
Log in

Spatial distribution of heavy metals, source identification, risk assessment and particulate matter in the M4 motorway

  • Research
  • Published:
Environmental Monitoring and Assessment Aims and scope Submit manuscript

Abstract

Metal-containing dust is a potential severe environmental and human health threat. Metals present in dust may originate from car exhausts, tear and wear of tires, and vehicular emissions, which are less manageable. Metal-containing dust from roads can contaminate the soils, and crops alongside motorway. This study aimed to investigate the Pb Cd, Cu, Ni, and Zn concentrations in dust, soil, and vegetation collected from the M4 motorway Faisalabad. The results indicated that average metal concentrations in dust from all sites varies (Pb) 44.01 mg kg−1, (Cd) 1.22 mg kg−1, (Cu) 49.5 mg kg−1, (Ni) 28.3 mg kg−1, and (Zn) 113.7 mg kg−1. The pollution assessment indices CF and PLI of Industrial city and Painsra had comparatively maximum levels of environmental pollution. Moreover, the geo-accumulation index (Igeo) of metals was high at Chak 115 and Painsra, while Igeo at ten sites was in the following descending order: Cd > Pb > Cu > Ni > Zn. Furthermore, it was identified that the maximum ecological risk index (Eir) was in declining order, i.e., Cd > Pb > Cu > Ni > Zn, at all sites. The potential ecological risk was categorized as high risk in all respective sites. The particulate matter fractions PM2.5 and PM10 represented the maximum risk at the Industrial city site, which was unhealthy, although the Painsra site had poor air quality. The total suspended particulate was classified as hazardous at FDA city and Painsra. In contrast, food crops (maize, sugar cane, and sesame) and soil along the M4 motorway have similar Pb, Cd, Cu, Ni, and Zn contamination patterns like dust. However, two crops, maize and sugarcane, along the M4 motorway were found to be more polluted. The level of metals contamination through dust disposition was consistently higher adjacent to roads, possibly indicating depraved impacts on food crops.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8
Fig. 9

Similar content being viewed by others

Data availability

Not applicable.

References 

  • Adamiec, E., Jarosz-Krzemińska, E., & Wieszała, R. (2016). Heavy metals from non-exhaust vehicle emissions in urban and motorway road dusts. Environmental Monitoring and Assessment, 188(6), 1–11.

    Article  CAS  Google Scholar 

  • Ahmad, K., Muhammad, S., Ali, W., Jadoon, I. A. K., & Rasool, A. (2020). Occurrence, source identification and potential risk evaluation of heavy metals in sediments of the Hunza River and its tributaries. Gilgit-Baltistan. Environmental Technology & Innovation, 18, 100700.

    Article  Google Scholar 

  • Akbar, K. F., Hale, W. H. G., Headley, A. D., & Athar, M. (2006). Heavy metal contamination of roadside soils of Northern England. Soil Water Res, 1(4), 158–163.

    Article  Google Scholar 

  • Al-Khashman, O. A. (2007). Determination of metal accumulation in deposited street dusts in Amman. Jordan. Environmental Geochemistry and Health, 29(1), 1–10.

    Article  CAS  Google Scholar 

  • Alloway, B. J. (Ed.) (2013). Sources of heavy metals and metalloids in soils. In Heavy metals in soils: trace metals and metalloids in soils and their bioavailability. Springer, pp. 11–50.

  • Amato, F., Cassee, F. R., van der Gon, H. A. C. D., Gehrig, R., Gustafsson, M., Hafner, W., et al. (2014). Urban air quality: The challenge of traffic non-exhaust emissions. Journal of Hazardous Materials, 275, 31–36.

    Article  CAS  Google Scholar 

  • Apeagyei, E., Bank, M. S., & Spengler, J. D. (2011). Distribution of heavy metals in road dust along an urban-rural gradient in Massachusetts. Atmospheric Environment, 45(13), 2310–2323.

    Article  CAS  Google Scholar 

  • Arslan, H. (2001). Heavy metals in street dust in Bursa, Turkey. Journal of Trace and Microprobe Techniques, 19(3), 439–445.

    Article  CAS  Google Scholar 

  • Butte, W., & Heinzow, B. (2002). Pollutants in house dust as indicators of indoor contamination. Reviews of Environmental Contamination and Toxicology, 175, 1–46.

    CAS  Google Scholar 

  • Centre, C. N. E. M. (1990). Background values of soil elements in China. China Environmental Science, 1(9), 9.

    Google Scholar 

  • Chang, S.-H., Wang, K.-S., Chang, H.-F., Ni, W.-W., Wu, B.-J., Wong, R.-H., & Lee, H.-S. (2009). Comparison of source identification of metals in road-dust and soil. Soil and Sediment Contamination, 18(5), 669–683.

    Article  CAS  Google Scholar 

  • Charlesworth, S., Everett, M., McCarthy, R., Ordonez, A., & De Miguel, E. (2003). A comparative study of heavy metal concentration and distribution in deposited street dusts in a large and a small urban area: Birmingham and Coventry, West Midlands. UK. Environment International, 29(5), 563–573.

    Article  CAS  Google Scholar 

  • Chen, Q. Y., Tyrer, M., Hills, C. D., Yang, X. M., & Carey, P. (2009). Immobilisation of heavy metal in cement-based solidification/stabilisation: A review. Waste Management, 29(1), 390–403.

    Article  CAS  Google Scholar 

  • Chen, X., Xia, X., Zhao, Y., & Zhang, P. (2010). Heavy metal concentrations in roadside soils and correlation with urban traffic in Beijing. China. Journal of Hazardous Materials, 181(1–3), 640–646.

    Article  CAS  Google Scholar 

  • de Miguel, E., Llamas, J. F., Chacón, E., Berg, T., Larssen, S., Røyset, O., & Vadset, M. (1997). Origin and patterns of distribution of trace elements in street dust: Unleaded petrol and urban lead. Atmospheric Environment, 31(17), 2733–2740.

    Article  Google Scholar 

  • Deepalakshmi, A. P., Ramakrishnaiah, H., Ramachandra, Y. L., & Kumar, N. N. (2014). Leaves of higher plants as indicators of heavy metal pollution along the urban roadways. Int J Sci Technol, 3(6), 340–346.

    Google Scholar 

  • Duong, T. T. T., & Lee, B.-K. (2011). Determining contamination level of heavy metals in road dust from busy traffic areas with different characteristics. Journal of Environmental Management, 92(3), 554–562.

    Article  CAS  Google Scholar 

  • Duzgoren-Aydin, N. S., Wong, C., Aydin, A., Song, Z., You, M., & Li, X. D. (2006). Heavy metal contamination and distribution in the urban environment of Guangzhou, SE China. Environmental Geochemistry and Health, 28, 375–391.

    Article  CAS  Google Scholar 

  • Faiz, Y., Tufail, M., Javed, M. T., & Chaudhry, M. M. (2009). Road dust pollution of Cd, Cu, Ni, Pb and Zn along Islamabad expressway. Pakistan. Microchemical Journal, 92(2), 186–192.

    Article  CAS  Google Scholar 

  • Gunawardana, C., Goonetilleke, A., Egodawatta, P., Dawes, L., & Kokot, S. (2012). Source characterisation of road dust based on chemical and mineralogical composition. Chemosphere, 87(2), 163–170.

    Article  CAS  Google Scholar 

  • Hakanson, L. (1980). An ecological risk index for aquatic pollution control. A Sedimentological Approach. Water Research, 14(8), 975–1001.

    Google Scholar 

  • Hjortenkrans, D. S. T., Bergbäck, B. G., & Häggerud, A. V. (2008). Transversal immission patterns and leachability of heavy metals in road side soils. Journal of Environmental Monitoring, 10(6), 739–746.

    Article  CAS  Google Scholar 

  • Hseu, Z.-Y., Chen, Z.-S., Tsai, C.-C., Tsui, C.-C., Cheng, S.-F., Liu, C.-L., & Lin, H.-T. (2002). Digestion methods for total heavy metals in sediments and soils. Water, Air, and Soil Pollution, 141(1), 189–205.

    Article  CAS  Google Scholar 

  • Ikenaka, Y., Nakayama, S. M. M., Muzandu, K., Choongo, K., Teraoka, H., Mizuno, N., & Ishizuka, M. (2010). Heavy metal contamination of soil and sediment in Zambia. African Journal of Environmental Science and Technology, 4(11), 729–739.

    CAS  Google Scholar 

  • Jan, F. A., Saleem, S., Faisal, S., Hussain, I., Rauf, A., & Ullah, N. (2021). Road dust as a useful tool for the assessment of pollution characteristics and health risks due to heavy metals: A case study from District Charsadda, Pakistan. Arabian Journal of Geosciences, 14, 1–13.

    Article  Google Scholar 

  • Jian-Hua, M. A., Chun-Jie, C. H. U., Jian, L. I., & Bo, S. (2009). Heavy metal pollution in soils on railroad side of Zhengzhou-Putian section of Longxi-Haizhou railroad. China. Pedosphere, 19(1), 121–128.

    Article  Google Scholar 

  • Jiries, A. (2003). Vehicular contamination of dust in Amman. Jordan. Environmentalist, 23(3), 205–210.

    Article  Google Scholar 

  • Kabadayi, F., & Cesur, H. (2010). Determination of Cu, Pb, Zn, Ni Co, Cd, and Mn in road dusts of Samsun City. Environmental Monitoring and Assessment, 168, 241–253.

    Article  CAS  Google Scholar 

  • Kabata-Pendias, A. (2000). Trace elements in soils and plants. CRC Press.

    Book  Google Scholar 

  • Kabir, M. H., Kormoker, T., Shammi, R. S., Tusher, T. R., Islam, M. S., Khan, R., et al. (2022). A comprehensive assessment of heavy metal contamination in road dusts along a hectic national highway of Bangladesh: Spatial distribution, sources of contamination, ecological and human health risks. Toxin Reviews, 41(3), 860–879.

    Article  CAS  Google Scholar 

  • Khoder, M. I., Al Ghamdi, M. A., & Shiboob, M. H. (2012). Heavy metal distribution in street dust of urban and industrial areas in Jeddah, Saudi Arabia. JKAU: Met. Env & Arid Land Agric. Sc, 23, 55–75.

    Google Scholar 

  • Kong, S., Lu, B., Ji, Y., Zhao, X., Chen, L., Li, Z., et al. (2011). Levels, risk assessment and sources of PM10 fraction heavy metals in four types dust from a coal-based city. Microchemical Journal, 98(2), 280–290. https://doi.org/10.1016/j.microc.2011.02.012

    Article  CAS  Google Scholar 

  • Kumari, M., Kumar, A., & Bhattacharya, T. (2023). Assessment of heavy metal contamination in street dust: concentrations, bio accessibility, and human health risks in coal mine and thermal power plant complex. Environmental Geochemistry and Health, 45(10), 7339–7362.

    Article  CAS  Google Scholar 

  • Leghari, S. K., Zaid, M. A., Sarangzai, A. M., Faheem, M., & Shawani, G. R. (2014). Effect of road side dust pollution on the growth and total chlorophyll contents in Vitis vinifera L.(grape). African Journal of Biotechnology, 13(11).

  • Liang, S.-Y., Cui, J.-L., Bi, X.-Y., Luo, X.-S., & Li, X.-D. (2019). Deciphering source contributions of trace metal contamination in urban soil, road dust, and foliar dust of Guangzhou, southern China. Science of the Total Environment, 695, 133596.

    Article  CAS  Google Scholar 

  • Lone, A. H., Lal, E. P., Thakur, S., Ganie, S. A., Wani, M. S., Khare, A., et al. (2013). Accumulation of heavy metals on soil and vegetable crops grown on sewage and tube well water irrigation. Scientific Research and Essays, 8(44), 2187–2193.

    Article  Google Scholar 

  • Lu, X., Pan, H., & Wang, Y. (2017). Pollution evaluation and source analysis of heavy metal in roadway dust from a resource-typed industrial city in Northwest China. Atmospheric Pollution Research, 8(3), 587–595.

    Article  Google Scholar 

  • Mafuyai, G. M., Kamoh, N. M., Kangpe, N. S., Ayuba, S. M., & Eneji, I. S. (2015). Heavy metals contamination in roadside dust along major traffic roads in Jos metropolitan area, Nigeria.

  • Meza-Figueroa, D., De la O-Villanueva, M., & De la Parra, M. L. (2007). Heavy metal distribution in dust from elementary schools in Hermosillo, Sonora. México. Atmospheric Environment, 41(2), 276–288.

    Article  CAS  Google Scholar 

  • Muller, G. (1969). Index of geoaccumulation in sediments of the Rhine River. GeoJournal, 2, 108–118.

    Google Scholar 

  • Norouzi, S., Khademi, H., Cano, A. F., & Acosta, J. A. (2015). Using plane tree leaves for biomonitoring of dust borne heavy metals: A case study from Isfahan, Central Iran. Ecological Indicators, 57, 64–73.

    Article  CAS  Google Scholar 

  • Olukanni, D. O., & Adebiyi, S. A. (2012). Assessment of vehicular pollution of road side soils in Ota Metropolis, Ogun State, Nigeria. International Journal of Civil and Environmental Engineering, 12(4), 40–46.

    Google Scholar 

  • Padoan, E., Ajmone-Marsan, F., Querol, X., & Amato, F. (2018). An empirical model to predict road dust emissions based on pavement and traffic characteristics. Environmental Pollution, 237, 713–720.

    Article  CAS  Google Scholar 

  • Pal, R., Gupta, A., & Tripathi, A. (2014). Assessment of heavy metals in suspended particulate matter in Moradabad. India. Journal of Environmental Biology, 35(2), 357.

    Google Scholar 

  • Qadeer, A., Saqib, Z. A., Ajmal, Z., Xing, C., Khalil, S. K., Usman, M., et al. (2020). Concentrations, pollution indices and health risk assessment of heavy metals in road dust from two urbanized cities of Pakistan: Comparing two sampling methods for heavy metals concentration. Sustainable Cities and Society, 53, 101959.

    Article  Google Scholar 

  • Rahman, M. S., Khan, M. D. H., Jolly, Y. N., Kabir, J., Akter, S., & Salam, A. (2019). Assessing risk to human health for heavy metal contamination through street dust in the Southeast Asian Megacity: Dhaka, Bangladesh. Science of the Total Environment, 660, 1610–1622.

    Article  Google Scholar 

  • Rasmussen, P. E., Subramanian, K. S., & Jessiman, B. J. (2001). A multi-element profile of house dust in relation to exterior dust and soils in the city of Ottawa Canada. Science of the Total Environment, 267(1–3), 125–140.

    Article  CAS  Google Scholar 

  • Raza Ahmad, H., Mehmood, K., Sardar, M. F., Maqsood, M. A., Ur Rehman, M. Z., Zhu, C., & Li, H. (2020). Integrated risk assessment of potentially toxic elements and particle pollution in urban road dust of megacity of Pakistan. Human and Ecological Risk Assessment: An International Journal, 26(7), 1810–1831.

    Article  CAS  Google Scholar 

  • Roy, A., & Bhattacharya, T. (2022). Ecological and human health risks from pseudo-total and bio-accessible metals in street dusts. Environmental Monitoring and Assessment, 194(2), 101.

    Article  CAS  Google Scholar 

  • Roy, S., Gupta, S. K., Prakash, J., Habib, G., Baudh, K., & Nasr, M. (2019). Ecological and human health risk assessment of heavy metal contamination in road dust in the National Capital Territory (NCT) of Delhi, India. Environmental Science and Pollution Research, 26, 30413–30425.

    Article  CAS  Google Scholar 

  • Roy, A., Bhattacharya, T., & Kumari, M. (2020). Air pollution tolerance, metal accumulation and dust capturing capacity of common tropical trees in commercial and industrial sites. Science of the Total Environment, 722, 137622.

    Article  CAS  Google Scholar 

  • Sayyed, G., & Sayadi, M. H. (2011). Variations in the heavy metal accumulations within the surface soils from the Chitgar industrial area of Tehran. Proceedings of the International Academy of Ecology and Environmental Sciences, 1(1), 36–46.

    Google Scholar 

  • Shabbaj, I. I., Alghamdi, M. A., Shamy, M., Hassan, S. K., Alsharif, M. M., & Khoder, M. I. (2018). Risk assessment and implication of human exposure to road dust heavy metals in Jeddah, Saudi Arabia. International Journal of Environmental Research and Public Health, 15(1), 36.

    Article  Google Scholar 

  • Shah, M. H., Shaheen, N., & Nazir, R. (2012). Assessment of the trace elements level in urban atmospheric particulate matter and source apportionment in Islamabad Pakistan. Atmospheric Pollution Research, 3(1), 39–45.

    Article  CAS  Google Scholar 

  • Shah, K., An, N., Ma, W., Ara, G., Ali, K., & Kamanova, S. (2020). Chronic cement dust load induce novel damages in foliage and buds of Malus domestica. Scientific Reports, 10(1), 1–12.

    Article  Google Scholar 

  • Shehzad, M. T., Sabir, M., Zia-ur-Rehman, M., Zia, M. A., & Naidu, R. (2022). Arsenic concentrations in soil, water, and rice grains of rice-growing areas of Punjab, Pakistan: Multivariate statistical analysis. Environmental Monitoring and Assessment, 194(5), 346.

    Article  CAS  Google Scholar 

  • Shi, G., Chen, Z., Xu, S., Zhang, J., Wang, L., Bi, C., & Teng, J. (2008). Potentially toxic metal contamination of urban soils and roadside dust in Shanghai. China. Environmental Pollution, 156(2), 251–260.

    Article  CAS  Google Scholar 

  • Soltani, N., Keshavarzi, B., Moore, F., Tavakol, T., Lahijanzadeh, A. R., Jaafarzadeh, N., & Kermani, M. (2015). Ecological and human health hazards of heavy metals and polycyclic aromatic hydrocarbons (PAHs) in road dust of Isfahan metropolis Iran. Science of the Total Environment, 505, 712–723.

    Article  CAS  Google Scholar 

  • Swaileh, K. M., Hussein, R. M., & Abu-Elhaj, S. (2004). Assessment of heavy metal contamination in roadside surface soil and vegetation from the West Bank. Archives of Environmental Contamination and Toxicology, 47, 23–30.

    Article  CAS  Google Scholar 

  • Taylor, S. R., & McLennan, S. M. (1995). The geochemical evolution of the continental crust. Reviews of Geophysics, 33(2), 241–265.

    Article  Google Scholar 

  • Thorpe, A., & Harrison, R. M. (2008). Sources and properties of non-exhaust particulate matter from road traffic: A review. Science of the Total Environment, 400(1–3), 270–282.

    Article  CAS  Google Scholar 

  • Tomlinson, D. L., Wilson, J. G., Harris, C. R., & Jeffrey, D. W. (1980). Problems in the assessment of heavy-metal levels in estuaries and the formation of a pollution index. Helgoländer Meeresuntersuchungen, 33(1), 566–575.

    Article  Google Scholar 

  • Trujillo-González, J. M., Torres-Mora, M. A., Keesstra, S., Brevik, E. C., & Jiménez-Ballesta, R. (2016). Heavy metal accumulation related to population density in road dust samples taken from urban sites under different land uses. Science of the Total Environment, 553, 636–642.

    Article  Google Scholar 

  • U.S. EPA. (2010). National Center for Environmental Research PM Centers. Available at http://www.epa.gov/ncer/science/pm/centers.html. Accessed 2 Dec 2009.

  • Wahab, M. I. A., Abd Razak, W. M. A., Sahani, M., & Khan, M. F. (2020). Characteristics and health effect of heavy metals on non-exhaust road dusts in Kuala Lumpur. Science of the Total Environment, 703, 135535.

    Article  CAS  Google Scholar 

  • Wei, X., Gao, B., Wang, P., Zhou, H., & Lu, J. (2015). Pollution characteristics and health risk assessment of heavy metals in street dusts from different functional areas in Beijing, China. Ecotoxicology and Environmental Safety, 112, 186–192.

    Article  CAS  Google Scholar 

  • WHO. (1996). Permissible limits of heavy metals in soil and plants. Geneva: World Health Organization.

    Google Scholar 

  • Yuen, J. Q., Olin, P. H., Lim, H. S., Benner, S. G., Sutherland, R. A., & Ziegler, A. D. (2012). Accumulation of potentially toxic elements in road deposited sediments in residential and light industrial neighborhoods of Singapore. Journal of Environmental Management, 101, 151–163.

    Article  CAS  Google Scholar 

  • Zhao, L., Hu, G., Yan, Y., Yu, R., Cui, J., Wang, X., & Yan, Y. (2019). Source apportionment of heavy metals in urban road dust in a continental city of eastern China: Using Pb and Sr isotopes combined with multivariate statistical analysis. Atmospheric Environment, 201, 201–211.

    Article  CAS  Google Scholar 

Download references

Acknowledgements

The authors acknowledge the support from University of Agriculture, Faisalabad. We acknowledge editors and reviewers for refining the language of the manuscript.

Author information

Authors and Affiliations

Authors

Contributions

Muhammad Hassan Bashir contributed to planning the experiment, executed the experiment, and completed the analytical work; Hamaad Raza Ahmad supervised the planning of experiment and proof reading of the final draft and submission; Ghulam Murtaza contributed to planning and executing the experiment, co-supervised the research, and proofread the draft; Muhammad Farrakh Nawaz helped in planning and final proof reading of the draft.

Corresponding author

Correspondence to Hamaad Raza Ahmad.

Ethics declarations

Ethical approval

Not applicable.

Consent to participate

Not applicable.

Consent to publish

All the authors are willing and have no conflict in publishing the article in this journal.

Competing interests

The authors declare no competing interests.

Additional information

Publisher's Note

Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.

Rights and permissions

Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Bashir, M.H., Ahmad, H.R., Murtaza, G. et al. Spatial distribution of heavy metals, source identification, risk assessment and particulate matter in the M4 motorway. Environ Monit Assess 195, 1541 (2023). https://doi.org/10.1007/s10661-023-12120-w

Download citation

  • Received:

  • Accepted:

  • Published:

  • DOI: https://doi.org/10.1007/s10661-023-12120-w

Keywords

Navigation