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Analytical application of flower-shaped nickel nanomaterial for the preconcentration of manganese in domestic wastewater samples

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Abstract

In this study, detection sensitivity of the conventional flame atomic absorption spectrophotometer (FAAS) for the determination of manganese (Mn2+) was enhanced by employing a preconcentration method from wastewater samples. Flower-shaped Ni(OH)2 nanomaterials were synthesized and used as sorbent material in preconcentration procedure. With the aim of attaining optimum experimental conditions, effective parameters of extraction method were optimized and these included pH of buffer solution, desorption solvent concentration and volume, mixing type and period, nanoflower amount, and sample volume. The detection limit of the optimized method was determined to be 2.2 μg L−1, and this correlated to about 41-fold enhancement in detection power relative to direct FAAS measurement. Domestic wastewater was used to test the feasibility of the proposed method to real samples by performing spike recovery experiments. The wastewater sample was spiked at four different concentrations of manganese, and the percent recoveries determined were in the range of 95–120%.

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Funding

This study was funded by The Scientific and Technological Research Council of Turkey (TÜBİTAK) with project number 1919B012100885.

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Authors and Affiliations

  1. Department of Chemical Engineering, Yildiz Technical University, 34220, Istanbul, Turkey

    Efe Sinan Aydın

  2. Department of Chemistry, Yildiz Technical University, 34220, Istanbul, Turkey

    Buse Tuğba Zaman & Sezgin Bakırdere

  3. Department of Environmental Engineering, Yildiz Technical University, 34220, Istanbul, Turkey

    Gamze Dalgıç Bozyiğit

  4. Turkish Academy of Sciences (TÜBA), Vedat Dalokay Street, No:112, Çankaya, 06670, Ankara, Turkey

    Sezgin Bakırdere

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  1. Efe Sinan Aydın
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  2. Buse Tuğba Zaman
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  4. Sezgin Bakırdere
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Contributions

Efe Sinan Aydın: data curation, formal analysis, investigation, methodology, validation, visualization, writing — original draft. Buse Tuğba Zaman: data curation, formal analysis, methodology, validation, visualization, writing — original draft. Gamze Dalgıç Bozyiğit: data curation, formal analysis, methodology, validation, visualization, writing — original draft. Sezgin Bakırdere: conceptualization, data curation, investigation, methodology, supervision, validation, writing — review and editing.

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Correspondence to Sezgin Bakırdere.

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Aydın, E.S., Zaman, B.T., Bozyiğit, G.D. et al. Analytical application of flower-shaped nickel nanomaterial for the preconcentration of manganese in domestic wastewater samples. Environ Monit Assess 195, 1358 (2023). https://doi.org/10.1007/s10661-023-11989-x

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