Abstract
Previously undescribed 2-bromo-3,4,4-trichlorobut-3-enoates 1b-23b were synthesized in 84–91% yield from natural alcohols including terpenes and steroids, plant phenols, and oximes of natural carbonyl compounds 1a-23a by reaction of 2-bromo-3,4,4-trichlorobut-3-enoyl chloride in the presence of pyridine.
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S. K. Petkevich, E. A. Dikusar, V. I. Potkin, R. V. Kaberdin, K. L. Moiseichuk, A. P. Yuvchenko, and P. V. Kurman, Zh. Obshch. Khim., 74, 642 (2004).
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Translated from Khimiya Prirodnykh Soedinenii, No. 3, pp. 212–215, May–June, 2006.
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Dikusar, E.A., Potkin, V.I., Kozlov, N.G. et al. 2-Bromo-3,4,4-trichlorobut-3-enoates of certain natural alcohols, phenols, and oximes of carbonyl compounds. Chem Nat Compd 42, 254–258 (2006). https://doi.org/10.1007/s10600-006-0093-7
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DOI: https://doi.org/10.1007/s10600-006-0093-7