Abstract
A mathematical model of nonisothermal synthesis in a mechanically activated system with allowance for the phase transition in one reagent is constructed. Results of studying the influence of the phase transition on the kinetics of nonisothermal chemical interaction of a pre-activated mixture for two different limiting synthesis regimes (wave and volume synthesis) are presented.
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V. K. Smolyakov, O. V. Lapshin, and V. V. Boldyrev, “Macroscopic theory of mechanochemical synthesis in heterogeneous systems,” Int. J. SHS, 16, No. 1, 1–11 (2007).
V. K. Smolyakov and O. V. Lapshin, “Macrokinetics of nonisothermal synthesis in mechanically activated heterogeneous systems,” Gorenie Plazmokhim., 3, No. 1, 53–60 (2005).
V. K. Smolyakov, “Combustion of mechanically activated heterogeneous systems,” Combust., Expl., Shock Waves, 41, No. 3, 319–325 (2005).
V. K. Smolyakov, O. V. Lapshin, and Yu.M. Maksimov, “Macrokinetics of mechanosynthesis in solid-gas systems. I. Mathematical simulation,” Combust., Expl., Shock Waves, 41, No. 5, 554–565 (2005).
V. K. Smolyakov, V. I. Itin, N. N. Golobokov, N. G. Kasatskii, O. V. Lapshin, Yu. M. Maksimov, O. G. Terekhova, and O. A. Shkoda, “Macrokinetics of mechanosynthesis in solid-gas systems. II. Experimental studies. Analysis of results,” Combust., Expl., Shock Waves, 41, No. 5, 566–572 (2005).
Yu. P. Butyagin, “Problems and prospects of mechanochemistry evolution,” Usp. Khimii, 63, No. 12, 1031–1043 (1994).
V. K. Smolyakov, “Phase transitions in the gasless combustion wave,” Khim. Fiz., 21, No. 11, 97–105 (2002).
V. G. Prokof’ev and V. K. Smolyakov, “Unsteady combustion of a binary gasless mixture ignited by a hot wall,” Combust., Expl., Shock Waves, 41, No. 2, 158–163 (2005).
T. V. Monasevich and V. I. Itin, “Effect of mechanical activation on the combustion of systems with brittle components (using Mn-Si as an example),” Combust., Expl., Shock Waves, 39, No. 6, 656–658 (2003).
N. N. Mofa, “Specific features of the structure and staged combustion of systems based on quartz modified by mechanical processing,” Gorenie Plazmokhim., 1, No. 1, 89–97 (2003).
Z. A. Mansurov and N. N. Mofa, “SHS composite materials: modified systems based on SiO2, specific features of combustion and phase formation,” Gorenie Plazmokhim., 3, No. 1, 71–80 (2005).
G. I. Ksandopulo, N. N. Mofa, T. A. Ketegenov, O. V. Chervyakova, and O. A. Tyumentseva, “Combustion of quartz-containing oxide systems modified by organic compounds under mechanochemical treatment,” Combust., Expl., Shock Waves, 38, No. 1, 54–59 (2002).
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Translated from Fizika Goreniya i Vzryva, Vol. 45, No. 1, pp. 56–67, January–February, 2009.
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Abdulkarimova, R.G., Ketegenov, T.A., Mansurov, Z.A. et al. Effect of phase transformation on nonisothermal synthesis in mechanically activated heterogeneous systems. Combust Explos Shock Waves 45, 48–58 (2009). https://doi.org/10.1007/s10573-009-0007-7
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DOI: https://doi.org/10.1007/s10573-009-0007-7