Abstract
Cotton gin trash (CGT), a residual lignocellulosic biomass generated during the ginning process of cotton fibres, is proposed for valorization and application in environmental remediation. Taking advantage of its availability and composition, rich in hydroxyl, carboxyl, and carbonyl groups, CGT is studied for its suitability for dye removal. Cotton gin trash films are synthesized using a single-step process with formic acid and tested for methylene blue (MB) adsorption. The morphology, chemical structure, surface area, zeta potential and crystallinity of the films are also reported. The hydroxyl groups in CGT increased by the film preparation and further enhanced the zeta potential of CGT towards the negative direction. Overall, the adsorption process is governed by the physisorption characteristic, where a greater potential difference between CGT and cationic MB improved the dye uptake. The adsorption system is described as favourable, fitting better with Langmuir isotherm model. The maximum adsorption capacity of the CGT films is 209 mg/g, which compares favourably against other reported lignocellulosic materials. Overall, the results indicate the CGT has an enormous potential as an adsorbent material for dye separation from wastewaters.
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Al Faruque MA, Remadevi R, Wang X, Naebe M (2019) Preparation and characterisation of mechanically milled particles from waste alpaca fibres. Powder Technol 342:848–855
Batool F, Akbar J, Iqbal S et al (2018) Study of isothermal, kinetic, and thermodynamic parameters for adsorption of cadmium: an overview of linear and nonlinear approach and error analysis. Bioinorg Chem Appl 2018:3463724. https://doi.org/10.1155/2018/3463724
Cai Z, Remadevi R, Al Faruque MA et al (2019) Fabrication of cost-effective biodegradable lemongrass (Cymbopogon) membrane with antibacterial activity for dye removal. RSC Adv 9:34076–34085. https://doi.org/10.1039/C9RA04729H
Cheng S, Zhang L, Xia H et al (2017) Adsorption behavior of methylene blue onto waste-derived adsorbent and exhaust gases recycling. RSC Adv 7:27331–27341
Chowdhury ZZ, Karim MZ, Ashraf MA, Khalid K (2016) Influence of carbonization temperature on physicochemical properties of biochar derived from slow pyrolysis of durian wood (Durio zibethinus) sawdust. BioResour 11:3356–3372
Dada AO, Latona DF, Ojediran OJ, Nath OO (2016) Adsorption of Cu (II) onto Bamboo Supported Manganese (BS-Mn) nanocomposite: effect of operational parameters, kinetic, isotherms, and thermodynamic studies. J Appl Sci Environ Manag 20:409–422
Dai H, Huang Y, Zhang Y et al (2019) Green and facile fabrication of pineapple peel cellulose/magnetic diatomite hydrogels in ionic liquid for methylene blue adsorption. Cellulose 26:3825–3844
Driemeier C, Oliveira MM, Mendes FM, Gómez EO (2011) Characterization of sugarcane bagasse powders. Powder Technol 214:111–116
French AD (2014) Idealized powder diffraction patterns for cellulose polymorphs. Cellulose 21:885–896
Giusto LAR, Pissetti FL, Castro TS, Magalhães F (2017) Preparation of activated carbon from sugarcane bagasse soot and methylene blue adsorption. Water Air Soil Pollut 228:249
Halysh V, Sevastyanova O, Riazanova AV et al (2018) Walnut shells as a potential low-cost lignocellulosic sorbent for dyes and metal ions. Cellulose 25:4729–4742
Hamdaoui O (2006) Batch study of liquid-phase adsorption of methylene blue using cedar sawdust and crushed brick. J Hazard Mater 135:264–273
Hameed BH, Ahmad AA (2009) Batch adsorption of methylene blue from aqueous solution by garlic peel, an agricultural waste biomass. J Hazard Mater 164:870–875
Haque ANMA, Remadevi R, Naebe M (2018) Lemongrass (Cymbopogon): a review on its structure, properties, applications and recent developments. Cellulose 25:5455–5477
Haque ANMA, Remadevi R, Wang X, Naebe M (2019) Sorption properties of fabricated film from cotton gin trash. Mater Today Proc. https://doi.org/10.1016/j.matpr.2019.11.065(in press)
Haque ANMA, Remadevi R, Wang X, Naebe M (2020a) Mechanically milled powder from cotton gin trash for diverse applications. Powder Technol 361:679–686
Haque ANMA, Remadevi R, Wang X, Naebe M (2020b) Physicochemical properties of film fabricated from cotton gin trash. Mater Chem Phys 239:122009. https://doi.org/10.1016/j.matchemphys.2019.122009
Hubbe MA, Azizian S, Douven S (2019) Implications of apparent pseudo-second-order adsorption kinetics onto cellulosic materials: a review. BioResour 14:7582–7626
Islam MA, Ahmed MJ, Khanday WA et al (2017) Mesoporous activated coconut shell-derived hydrochar prepared via hydrothermal carbonization-NaOH activation for methylene blue adsorption. J Environ Manag 203:237–244
Jawad AH, Rashid RA, Mahmuod RMA et al (2016) Adsorption of methylene blue onto coconut (Cocos nucifera) leaf: optimization, isotherm and kinetic studies. Desalin Water Treat 57:8839–8853
Kezerle A, Velić N, Hasenay D, Kovačević D (2018) Lignocellulosic materials as dye adsorbents: adsorption of methylene blue and Congo red on brewers’ spent grain. Croat Chem Acta 91:53–64
Kumar PS, Palaniyappan M, Priyadharshini M et al (2014) Adsorption of basic dye onto raw and surface-modified agricultural waste. Environ Prog Sustain Energy 33:87–98
Lam HQ, Le Bigot Y, Delmas M (2001) Formic acid pulping of rice straw. Ind Crops Prod 14:65–71
Lee Y, Lee H, Jung D et al (2018) Chloride ion adsorption capacity of anion exchange resin in cement mortar. Materials (Basel) 11:560
Miraboutalebi SM, Nikouzad SK, Peydayesh M et al (2017) Methylene blue adsorption via maize silk powder: kinetic, equilibrium, thermodynamic studies and residual error analysis. Process Saf Environ Prot 106:191–202
Özhan A, Şahin Ö, Küçük MM, Saka C (2014) Preparation and characterization of activated carbon from pine cone by microwave-induced ZnCl2 activation and its effects on the adsorption of methylene blue. Cellulose 21:2457–2467
Perez-Ameneiro M, Vecino X, Cruz JM, Moldes AB (2015) Wastewater treatment enhancement by applying a lipopeptide biosurfactant to a lignocellulosic biocomposite. Carbohydr Polym 131:186–196
Perotto G, Ceseracciu L, Simonutti R et al (2018) Bioplastics from vegetable waste via an eco-friendly water-based process. Green Chem 20:894–902
Popescu C-M, Popescu M-C, Singurel G et al (2007) Spectral characterization of eucalyptus wood. Appl Spectrosc 61:1168–1177
Reddy PMK, Verma P, Subrahmanyam C (2016) Bio-waste derived adsorbent material for methylene blue adsorption. J Taiwan Inst Chem Eng 58:500–508
Roy A, Adhikari B, Majumder SB (2013) Equilibrium, kinetic, and thermodynamic studies of azo dye adsorption from aqueous solution by chemically modified lignocellulosic jute fiber. Ind Eng Chem Res 52:6502–6512
Sartova K, Omurzak E, Kambarova G et al (2019) Activated carbon obtained from the cotton processing wastes. Diam Relat Mater 91:90–97
Sharma-Shivappa R, Chen Y (2008) Conversion of cotton wastes to bioenergy and value-added products. Trans ASABE 51:2239–2246
Tanzifi M, Yaraki MT, Kiadehi AD et al (2018) Adsorption of Amido Black 10B from aqueous solution using polyaniline/SiO2 nanocomposite: experimental investigation and artificial neural network modeling. J Colloid Interface Sci 510:246–261
Uddin MT, Islam MA, Mahmud S, Rukanuzzaman M (2009) Adsorptive removal of methylene blue by tea waste. J Hazard Mater 164:53–60
Vadivelan V, Kumar KV (2005) Equilibrium, kinetics, mechanism, and process design for the sorption of methylene blue onto rice husk. J Colloid Interface Sci 286:90–100
Xu N, Zhang W, Ren S et al (2012) Hemicelluloses negatively affect lignocellulose crystallinity for high biomass digestibility under NaOH and H2SO4 pretreatments in Miscanthus. Biotechnol Biofuels 5:58
Zhang M, Qi W, Liu R et al (2010) Fractionating lignocellulose by formic acid: characterization of major components. Biomass Bioenergy 34:525–532
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The authors acknowledge the support from the Deakin Advanced Characterization Facility and Deakin University Postgraduate Research Scholarship (DUPRS) awarded to the first author.
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Haque, A.N.M.A., Remadevi, R., Rojas, O.J. et al. Kinetics and equilibrium adsorption of methylene blue onto cotton gin trash bioadsorbents. Cellulose 27, 6485–6504 (2020). https://doi.org/10.1007/s10570-020-03238-y
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DOI: https://doi.org/10.1007/s10570-020-03238-y