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S‐Benzylisothiourea Complex of Palladium Supported on Modified Mesoporous Magnetic Nanoparticles (Pd-SBTU@Fe3O4@SBA-3) as Sustainable Environmental Catalyst for Suzuki and Stille Reactions

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Abstract

A new and efficient magnetic mesoporous material has been designed and prepared via immobilization of S‐benzylisothiourea complex of palladium on SBA-3 mesoporous silica magnetite nanoparticles. This novel, architecturally interesting magnetic nanocomposite was fully characterized using different analytical techniques such as FT-IR, BET, FE-SEM, ICP-OES and TGA. Catalytic activity of this material was successfully explored in carbon–carbon cross-coupling reactions (Suzuki and Stille reactions). The stability of the catalytic activity was examined using reusability test through four consecutive batch runs. Green conditions of the reactions, easy separation, short reaction times, reusability of the catalyst, and excellent yields of products make the present protocol practical and sustainable among the similar reported cross-coupling reactions.

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Acknowledgements

The authors would like to thank the research facilities of Ilam University and Bu-Ali Sina University for financial support of this research project.

Funding

This study were funded by Bu-Ali Sina University and Ilam University.

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Authors and Affiliations

  1. Department of Chemistry, Faculty of Science, Ilam University, Ilam, Iran

    Zahra Heidarnezhad & Zahra Taherinia

  2. Department of Organic Chemistry, Faculty of Chemistry, Bu-Ali Sina University, 6517838683, Hamedan, Iran

    Arash Ghorbani-Choghamarani

Authors
  1. Zahra Heidarnezhad
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  2. Arash Ghorbani-Choghamarani
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  3. Zahra Taherinia
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Corresponding author

Correspondence to Arash Ghorbani-Choghamarani.

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Heidarnezhad, Z., Ghorbani-Choghamarani, A. & Taherinia, Z. S‐Benzylisothiourea Complex of Palladium Supported on Modified Mesoporous Magnetic Nanoparticles (Pd-SBTU@Fe3O4@SBA-3) as Sustainable Environmental Catalyst for Suzuki and Stille Reactions. Catal Lett 152, 3178–3191 (2022). https://doi.org/10.1007/s10562-021-03871-7

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