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Novel C@Ni3P Nanoparticles for Highly Selective Hydrogenation of Furfural to Furfuryl Alcohol

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Abstract

A series of Ni3P and C@Ni3P catalyst were prepared by temperature programmed reduction method and characterized by XRD, TEM, N2 adsorption–desorption, H2-chemisorption, FT-IR, XPS and thermogravimetric analysis. Their catalytic performance in the hydrogenation of furfurnal was investigated. The 97% furfural conversion and 96.3% furfuryl alcohol selectivity were obtained over C@Ni3P-1 catalyst at 160 °C and 1.4 MPa H2 for 4 h. Furthermore, C@Ni3P-1 catalyst showed a high stability in reusing experiments and the satisfactory hydrogenation performance for other substrates.

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Acknowledgements

The authors acknowledge the financial supports from the National Key Research and Development Project, Intergovernmental International Science and Technology Innovation Cooperation Key Project (2018YFE0108800).

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Authors and Affiliations

  1. National Center for International Research on Catalytic Technology, Key Laboratory of Functional Inorganic Materials Chemistry (Ministry of Education), Key Laboratory of Chemical Engineering Process & Technology for High-Efficiency Conversion, College of Heilongjiang Province, School of Chemistry and Material Sciences, Heilongjiang University, Harbin, 150080, People’s Republic of China

    Ye Tian, Yazhou Wang, Huiyu Zhang, Linfei Xiao & Wei Wu

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  1. Ye Tian
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  2. Yazhou Wang
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  3. Huiyu Zhang
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  4. Linfei Xiao
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  5. Wei Wu
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Correspondence to Linfei Xiao or Wei Wu.

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Tian, Y., Wang, Y., Zhang, H. et al. Novel C@Ni3P Nanoparticles for Highly Selective Hydrogenation of Furfural to Furfuryl Alcohol. Catal Lett 152, 883–894 (2022). https://doi.org/10.1007/s10562-021-03680-y

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  • DOI: https://doi.org/10.1007/s10562-021-03680-y

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