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Sustainable Synthesis of Biaryls Using Silica Supported Ferrocene Appended N-Heterocyclic Carbene-Palladium Complex

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Abstract

A novel silica supported ferrocene appended N-heterocyclic carbene-palladium complex (SilFemBenzNHC@Pd) has been prepared and characterized by using fourier transform infrared (FT-IR), fourier transform Raman (FT-Raman), X-ray photoelectron spectroscopy (XPS), scanning electron microscopy (SEM), thermogravimetric analysis (TGA) and energy dispersive X-ray analysis (EDX). This novel complex served as a robust heterogeneous catalyst for the synthesis of biaryls via homocoupling of aryl boronic acids under base-free conditions in water. Recyclability experiments were executed successfully for six successive runs.

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Acknowledgement

We gratefully acknowledge Indian Institute of Technology, Madras (IITM) and Indian Institute of Sciences (IISc), Bangalore for providing spectral facilities.

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Authors and Affiliations

  1. Department of Chemistry, Shivaji University, Kolhapur, 416004, M.S, India

    Sharanabasappa Khanapure, Dattaprasad Pore, Megha Jagadale & Gajanan Rashinkar

  2. Vishwakarma Institute of Information Technology, Pune, 411046, M.S, India

    Vaishali Patil

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  1. Sharanabasappa Khanapure
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  2. Dattaprasad Pore
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  4. Vaishali Patil
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Correspondence to Gajanan Rashinkar.

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Khanapure, S., Pore, D., Jagadale, M. et al. Sustainable Synthesis of Biaryls Using Silica Supported Ferrocene Appended N-Heterocyclic Carbene-Palladium Complex. Catal Lett 151, 2237–2249 (2021). https://doi.org/10.1007/s10562-020-03480-w

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