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MgO Modifying Al2O3 to Load Cobalt Oxide for Catalytic N2O Decomposition

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Abstract

Alumina modified by MgO as the catalyst support loading Co3O4 for the N2O decomposition were investigated. It was found that MgAl2O4 was formed over the alumina surface by the MgO reacting with Al2O3 after calcination at 900 °C and using the composited support containing 30 wt% MgO loading Co3O4 can effectively suppress undesired CoAl2O4 formation under 700 °C. In the 20Co/30Mg–Al catalyst, it was found that about half of the cobalt is present as (Co,Mg)O solid solution and the rest exists as Co3O4, as characterized by Raman spectroscopy and H2-TPR. The catalyst exhibited much higher and stable activity for the N2O decomposition compared with the 20Co/Al without MgO modification.

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References

  1. Pérez-Ramı́rez J, Kapteijn F, Schöffel K, Moulijn JA (2003) Appl Catal B 44:117–151

    Article  CAS  Google Scholar 

  2. Konsolakis M (2015) Acs Catal 5:6397–6421

    Article  CAS  Google Scholar 

  3. Lee SJ, Ryu IS, Kim BM, Moon SH (2011) Int J Greenh Gas Con 5:167–176

    Article  CAS  Google Scholar 

  4. Ohnishi C, Asano K, Iwamoto S, Chikama K, Inoue M (2007) Catal Today 120:145–150

    Article  CAS  Google Scholar 

  5. Stelmachowski P, Zasada F, Piskorz W, Kotarba A, Paul JF, Sojka Z (2008) Catal Today 137:423–428

    Article  CAS  Google Scholar 

  6. Zhang FF, Wang XP, Zhang XX, Turxun M, Yu HB, Zhao JJ (2014) Chem Eng J 256:365–371

    Article  CAS  Google Scholar 

  7. Zabilskiy M, Erjavec B, Djinović P, Pintar A (2014) Chem Eng J 254:153–162

    Article  CAS  Google Scholar 

  8. Yu HB, Tursun M, Wang XP, Wu XX (2016) Appl Catal B 185:110–118

    Article  CAS  Google Scholar 

  9. Abu-Zied BM, Soliman SA, Abdellah SE (2015) J Ind Eng Chem 21:814–821

    Article  CAS  Google Scholar 

  10. Yu HB, Wang XP, Wu XX, Chen Y (2018) Chem Eng J 334:800–806

    Article  CAS  Google Scholar 

  11. Ivanov DV, Sadovskaya EM, Pinaeva LG, Isupova LA (2009) J Catal 267:5–13

    Article  CAS  Google Scholar 

  12. Wu Y, Ni X, Beaurain A, Dujardin C, Granger P (2012) Appl Catal B 125:149–157

    Article  CAS  Google Scholar 

  13. Ates A (2014) Catal Sci Technol 4:2031–2041

    Article  CAS  Google Scholar 

  14. da Cruz RS, Mascarenhas AJS, Andrade HMC (1998) Appl Catal B 18:223–231

    Article  Google Scholar 

  15. Gudyka S, Grzybek G, Grybos J, Indyka P, Leszczynski B, Kotarba A, Sojka Z (2017) Appl Catal B 201:339–347

    Article  CAS  Google Scholar 

  16. Pietrogiacomi D, Campa MC, Carbone LR, Tuti S, Occhiuzzi M (2016) Appl Catal B 187:218–227

    Article  CAS  Google Scholar 

  17. Grzybek G, Stelmachowski P, Gudyka S, Indyka P, Sojka Z, Guillén-Hurtado N, Rico-Pérez V, Bueno-López A, Kotarba A (2016) Appl Catal B 180:622–629

    Article  CAS  Google Scholar 

  18. Klegová A, Pacultová K, Fridrichová D, Volodarskaja A, Kovanda F, Jirátová K (2017) Chem Eng Technol 40:981–990

    Article  CAS  Google Scholar 

  19. Boissel V, Tahir S, Koh CA (2006) Appl Catal B 64:234–242

    Article  CAS  Google Scholar 

  20. Russo N, Fino D, Saracco G, Specchia V (2007) Catal Today 119:228–232

    Article  CAS  Google Scholar 

  21. Stelmachowski P, Maniak G, Kaczmarczyk J, Zasada F, Piskorz W, Kotarba A, Sojka Z (2014) Appl Catal B 146:105–111

    Article  CAS  Google Scholar 

  22. Grzybek G, Ciura K, Wójcik S, Gryboś J, Indyka P, Inger M, Antoniak-Jurak K, Kowalik P, Kotarba A, Sojka Z (2017) Catal Sci Technol 7:5723–5732

    Article  CAS  Google Scholar 

  23. Ji YG, Zhao Z, Duan AJ, Jiang GY, Liu J (2009) J Phys Chem C 113:7186–7199

    Article  CAS  Google Scholar 

  24. Jongsomjit B, Panpranot J, Goodwin JG Jr (2001) J Catal 204:98–109

    Article  CAS  Google Scholar 

  25. Jongsomjit B, Panpranot J, Goodwin JG Jr (2003) J Catal 215:66–77

    Article  CAS  Google Scholar 

  26. Liotta LF, Pantaleo G, Macaluso A, Di Carlo G, Deganello G (2003) Appl Catal A 245:167–177

    Article  CAS  Google Scholar 

  27. Liotta LF, Pantaleo G, Di Carlo G, Marcı̀ G, Deganello G (2004) Appl Catal B 52:1–10

    Article  CAS  Google Scholar 

  28. Grzybek G, Wójcik S, Ciura K, Gryboś J, Indyka P, Oszajca M, Stelmachowski P, Witkowski S, Inger M, Kotarba A, Sojka Z (2017) Appl Catal B 210:34–44

    Article  CAS  Google Scholar 

  29. Gayán P, de Diego LF, García-Labiano F, Adánez J, Abad A, Dueso C (2008) Fuel 87:2641–2650

    Article  CAS  Google Scholar 

  30. Hadjiev VG, Iliev MN, Vergilov IV (1988) J Phys C 21:L199–L201

    Article  Google Scholar 

  31. Keppler H, Bagdassarov N (1999) Chem Geol 158:105–115

    Article  CAS  Google Scholar 

  32. Kushwaha AK (2010) Phys B 405:2795–2798

    Article  CAS  Google Scholar 

  33. Wang HY, Ruckenstein E (2001) Appl Catal A 209:207–215

    Article  CAS  Google Scholar 

Download references

Acknowledgements

This work was financially supported by the National Natural Science Foundation of China (Grant Nos. 21277019 and 21777015).

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  1. State Key Laboratory of Fine Chemical, School of Environmental Science and Technology, Dalian University of Technology, Dalian, 116024, China

    Ye Li & Xinping Wang

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  1. Ye Li
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  2. Xinping Wang
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Correspondence to Xinping Wang.

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Li, Y., Wang, X. MgO Modifying Al2O3 to Load Cobalt Oxide for Catalytic N2O Decomposition. Catal Lett 149, 1856–1863 (2019). https://doi.org/10.1007/s10562-019-02789-5

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  • DOI: https://doi.org/10.1007/s10562-019-02789-5

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