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An Easily Prepared Tetraphosphine and Its Use in the Palladium-Catalyzed Suzuki–Miyaura Coupling of Aryl Chlorides

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Abstract

An air-stable tetraphosphine N,N,N′,N′-tetra(diphenylphosphinomethyl)-benzene-1,3-diamine (L3) was easily prepared in two steps from triphenylphosphine, which in combination with [Pd(η3-C3H5)Cl]2 affords an efficient catalyst for Suzuki–Miyaura coupling of activated chloroarenes. Even at high temperature of 130 °C, this catalyst exhibits good stability and longevity, and could allow a high turnover number of 680,000 to be reached.

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Acknowledgments

This work was supported by the National Natural Science Foundation of China (No. 21202104).

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Authors and Affiliations

  1. Key Laboratory of Green Chemistry and Technology, Ministry of Education, Department of Chemistry, Sichuan University, Chengdu, 610064, Sichuan, People’s Republic of China

    Kun Wang, Wei Wang, Heng Luo, Xueli Zheng, Haiyan Fu, Hua Chen & Ruixiang Li

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  1. Kun Wang
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  2. Wei Wang
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  3. Heng Luo
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  4. Xueli Zheng
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  5. Haiyan Fu
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Correspondence to Ruixiang Li.

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Wang, K., Wang, W., Luo, H. et al. An Easily Prepared Tetraphosphine and Its Use in the Palladium-Catalyzed Suzuki–Miyaura Coupling of Aryl Chlorides. Catal Lett 143, 1214–1219 (2013). https://doi.org/10.1007/s10562-013-1028-0

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  • DOI: https://doi.org/10.1007/s10562-013-1028-0

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