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Application of a Nickel-Bispidine Complex as Pre-Catalyst for C(sp 2)–C(sp 3) Bond Formations

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Abstract

In the present study, the nickel-catalyzed cross coupling of aryl halides with benzyl zinc bromides or dialkyl zinc reagents to create C(sp 2)–C(sp 3) bonds has been explored. As pre-catalyst the well-defined and easy-accessible (bispidine)Ni(NO3)2 complex has been applied. After investigation of different reaction parameters a broad scope of C(sp 2)–C(sp 3) bond formations were feasible under mild reaction conditions.

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Acknowledgements

Financial support from the Cluster of Excellence “Unifying Concepts in Catalysis” (funded by the Deutsche Forschungsgemeinschaft and administered by the Technische Universität Berlin) is gratefully acknowledged.

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Authors and Affiliations

  1. Department of Chemistry, Cluster of Excellence “Unifying Concepts in Catalysis”, Technische Universität Berlin, Straße des 17. Juni 135/C2, 10623, Berlin, Germany

    Michael Haberberger, Chika I. Someya & Stephan Enthaler

  2. Departament de Química, Universitat de Girona, Campus de Montilivi, E17071, Girona, Catalonia, Spain

    Anna Company

  3. Department of Chemistry: Metalorganics and Inorganic Materials, Technische Universität Berlin, Straße des 17. Juni 135/C2, 10623, Berlin, Germany

    Elisabeth Irran

Authors
  1. Michael Haberberger
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  2. Chika I. Someya
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  3. Anna Company
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  4. Elisabeth Irran
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  5. Stephan Enthaler
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Correspondence to Stephan Enthaler.

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Haberberger, M., Someya, C.I., Company, A. et al. Application of a Nickel-Bispidine Complex as Pre-Catalyst for C(sp 2)–C(sp 3) Bond Formations. Catal Lett 142, 557–565 (2012). https://doi.org/10.1007/s10562-012-0806-4

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  • DOI: https://doi.org/10.1007/s10562-012-0806-4

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