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Catalytic Reduction of NO with NH3 over V2O5-MnOX/TiO2-Carbon Nanotube Composites

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Abstract

A series of V2O5–MnOX/TiO2-CNTs, V2O5/TiO2-CNTs, and MnOX/TiO2-CNTs catalysts were synthesized via solvothermal method and their NOX removal activities were studied. A catalytic performance improvement was observed over catalysts prepared by mechanical mixing MnOX/TiO2-CNTs and V2O5/TiO2-CNTs. XRD, SEM, EDS, TPD, TPR, and BET were employed to analyze the improvement which is ascribed to the separation of Mn and V as well as the increase in reducibility and acidic strength.

Graphical Abstract

The existence of catalytic activity promotion between V2O5 and MnOX was clarified by TOF.

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References

  1. PaÃrvulescu VI, Grange P, Delmon B (1998) Catal Today 46:233

    Article  Google Scholar 

  2. Wang HQ, Wang J, Wu ZB, Liu Y (2010) Catal Lett 134:295

    Article  CAS  Google Scholar 

  3. Lee JH, Schmieg SJ, Oh SH (2008) Appl Catal A 342:78

    Article  CAS  Google Scholar 

  4. Itoha M, Saitoa M, Takeharaa M, Motoki K, Iwamotob J, Machidaa K (2009) J Mol Catal A Chem 304:159

    Article  Google Scholar 

  5. Casagrande L, Lietti L, Nova I, Forzatti P, Baiker A (1999) Appl Catal B 22:63

    Article  CAS  Google Scholar 

  6. Wu ZB, Jiang BQ, Liu Y, Wang HQ, Jin RB (2007) Environ Sci Technol 41:5812

    Article  CAS  Google Scholar 

  7. Kro¨cher O, Elsener M (2008) Ind Eng Chem Res 47:8588

    Article  Google Scholar 

  8. Li JH, Zhu RH, Cheng YS, Lambert C, Yang R (2010) Environ Sci Technol 44:1799

    Article  CAS  Google Scholar 

  9. Jang BW-L, Spivey JJ, Kung MC, Kung HH (1997) Energy Fuels 11:299

    Article  CAS  Google Scholar 

  10. Zhu ZP, Liu ZY, Liu SJ, Niu HX (2001) Appl Catal B 30:267

    Article  CAS  Google Scholar 

  11. Huang B, Huang R, Jin DJ, Ye DQ (2007) Catal Today 126:279

    Article  CAS  Google Scholar 

  12. Jin R, Liu Y, Wu ZB, Wang HQ, Gu TT (2010) Chemosphere 78:1160

    Article  CAS  Google Scholar 

  13. Tang XL, Hao JM, Xu WG, Li JH (2007) Catal Commun 8:329

    Article  CAS  Google Scholar 

  14. Qi G, Yang RT (2004) J Phys Chem B 108:15738

    Article  CAS  Google Scholar 

  15. Lietti L, Forzatti P, Bregani F (1996) Ind Eng Chem Res 35:3884

    Article  CAS  Google Scholar 

  16. Amiridis MD, Duevel RV, Wachs IE (1999) Appl Catal B 20:111

    Article  CAS  Google Scholar 

  17. Phil HH, Reddy MP, Kumar PA, Ju LK, Hyo JS (2008) Appl Catal B 78:301

    Article  CAS  Google Scholar 

  18. Casapu M, Kro¨ cher O, Elsener M (2009) Appl Catal B 88:413

    Article  CAS  Google Scholar 

  19. Rodriguez NM, Kim MS, Baker RTK (1994) J Phys Chem 98:13108

    Article  CAS  Google Scholar 

  20. Planeix JM, Coustel N, Coq B (1994) J Am Chem Soc 116:7935

    Article  CAS  Google Scholar 

  21. Santucci S, Picozzi S, Gregorio FD, Lozzi L (2003) J Chem Phys 119:10904

    Article  CAS  Google Scholar 

  22. Tian W, Yang HS, Fan XY, Zhang XB (2010) Catal Commun 11:1185

    Article  CAS  Google Scholar 

  23. Fan XY, Yang HS, Tian W, Nie AM, Hou TF, Qiu FM, Zhang XB (2011) Catal Lett 141:158

    Article  CAS  Google Scholar 

  24. Guan WJ, Li Y, Chen YQ, Zhang XB, Hu GQ (2005) Biosens Bioelectron 21:508

    Article  CAS  Google Scholar 

  25. Li Y, Zhang XB, Tao XY, Xu JM, Chen F, Huang WZ, Liu F (2004) Chem Phys Lett 386:105

    Article  CAS  Google Scholar 

  26. Gálvez ME, Boyano A, Lázaro MJ, Moliner R (2008) Chem Eng J 144:10

    Article  Google Scholar 

  27. Huang ZG, Zhu ZP, Liu ZY, Liu QY (2003) J Catal 214:213

    Article  CAS  Google Scholar 

  28. Guo XY, Bartholomew C, Hecker W, Baxter LL (2009) Appl Catal B 92:30

    Article  CAS  Google Scholar 

  29. Casapu M, Kro¨cher O, Mehring M, Nachtegaal M, Borca C, Harfouche M, Grolimund D (2010) J Phys Chem C 114:9791

    Article  CAS  Google Scholar 

  30. Jitianu A, Cacciaguerra T, Benoit R, Delpeux S, Beguin F, Bonnamy S (2004) Carbon 42:1147

    Article  CAS  Google Scholar 

  31. Wang S, Ji LJ, Wu B, Gong QM, Zhu YF, Liang J (2008) Appl Surf Sci 255:3263

    Article  CAS  Google Scholar 

  32. Bordeje EG, Calvillo L, Lazaro MJ, Moliner R (2004) Appl Catal B 50:235

    Article  Google Scholar 

  33. Weckhusen BM, Keller DE (2003) Catal Today 78:25

    Article  Google Scholar 

  34. Huang JH, Tong ZQ, Huang Y, Zhang JF (2008) Appl Catal B 78:309

    Article  CAS  Google Scholar 

  35. Choo ST, Yim SD, Nam IS, Ham SW, Lee JB (2003) Appl Catal B 44:237

    Article  CAS  Google Scholar 

  36. Li JH, Chen JJ, Ke R, Luo CK, Hao JM (2007) Catal Commun 8:1896

    Article  CAS  Google Scholar 

  37. Economidis NV, Peña DA, Smirniotis PG (1999) Appl Catal B 23:130

    Google Scholar 

  38. Lietti L, Svachula J, Forzatti P, Busca G, Ramis G, Bregani F (1993) Catal Today 17:131

    Article  CAS  Google Scholar 

  39. Huang ZG, Liu ZY, Zhang XL, Liu QY (2006) Appl Catal B 63:260

    Article  CAS  Google Scholar 

  40. Reiche MA, Ortelli E, Baiker A (1999) Appl Catal B 23:187

    Article  CAS  Google Scholar 

  41. Baiker A, Dollenmeier P, Glinski M (1987) Appl Catal 35:351

    Article  CAS  Google Scholar 

  42. Liljelind P, Unsworth J, Maaskant O, Marklund S (2001) Chemosphere 42:615

    Article  CAS  Google Scholar 

  43. Tian W, Fan XY, Yang HS, Zhang XB (2010) J Hazard Mater 177:887

    Article  CAS  Google Scholar 

  44. Dumesic JA, Topsøe N-Y, Slabiak T, Morsing P, Clausen BS, Törnqvist E, Topsøe H (1993) Microkinetic analysis of the selective catalytic reduction (SCR) of nitric oxide over vanadia/titania-based catalysts. In: Proceedings of the 10th International Congress on Catalysis, Elsevier, Budapest, 19–24 July 1993, p 1325

  45. Topsøe N-Y, Dumesic JA, Topsøe H (1995) J Catal 151:241

    Article  Google Scholar 

  46. Tronconi E, Nova I, Ciardelli C, Chatterjee D, Weibel M (2007) J Catal 245:1

    Article  CAS  Google Scholar 

  47. Qi GS, Yang RT (2003) J Catal 217:434

    CAS  Google Scholar 

  48. Bertinchamps F, Gregoire C, Gaigneaux EM (2006) Appl Catal B 66:10

    Article  CAS  Google Scholar 

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Acknowledgments

This study was supported by the Environmentally Sustainable Management of Medical Wastes in China (Contract No. C/V/S/10/251); the National Natural Foundation of Zhejiang Province, China, Grant No. Z4080070; the Foundation of Science and Technology Bureau of Zhejiang Province, China, Grant No. 2008C21057; and the Fundamental Research Funds for the Central Universities, Program No.2010QNA4005.

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Authors and Affiliations

  1. Department of Materials Science and Engineering, State Key Laboratory of Silicon Materials, Zhejiang University, Zheda Road 38, Hangzhou, 310027, China

    Qian Li, Hangsheng Yang, Anmin Nie, Xiaoyu Fan & Xiaobin Zhang

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  1. Qian Li
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  2. Hangsheng Yang
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  3. Anmin Nie
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  4. Xiaoyu Fan
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  5. Xiaobin Zhang
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Correspondence to Hangsheng Yang.

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Li, Q., Yang, H., Nie, A. et al. Catalytic Reduction of NO with NH3 over V2O5-MnOX/TiO2-Carbon Nanotube Composites. Catal Lett 141, 1237–1242 (2011). https://doi.org/10.1007/s10562-011-0622-2

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  • DOI: https://doi.org/10.1007/s10562-011-0622-2

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