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Oxidative Dehydrogenation Properties of Novel Nanostructured Polyoxovanadate Based Materials

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Abstract

A comparative study of the catalytic oxidative dehydrogenation of propane by a novel polyoxovanadate based open-framework material (Co-POV)—[Co3V18O42(H2O)12(XO4)]·24H2O (X = V, S), which is composed of nanometer size vanadium oxide clusters interlinked by cobalt oxide {–O–Co–O–} motifs, showed that Co-POV has superior catalytic property as compared to its individual metal oxide constituents, vanadium oxide and cobalt oxide, and their mixture, with high propylene selectivity.

Graphical Abstract

Comparison of oxidative dehydrogenation (ODH) of propane catalytic properties of a nanostructured material—[Co3(H2O)12V18O42(XO4)]·24 H2O (Co-POV) with its building blocks—V2O5 and CoO—shows Co-POV is a better ODH catalyst than its building blocks.

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Acknowledgments

Funding for part of this work from King Abdullah Institute of Nanotechnology, King Saud University, Riyadh, Saudi Arabia is gratefully acknowledged. We thank Rodrigo Lobo, Argonne National Laboratory, for his help with XANES experiments.

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Authors and Affiliations

  1. Department of Biological, Chemical and Physical Sciences, Illinois Institute of Technology, 3101 S Dearborn Street Life Sciences Building Room 178, Chicago, IL, 60616, USA

    M. Ishaque Khan & Kadir Aydemir

  2. Chemistry Department, Science College, King Saud University, Riyadh, 11451, Saudi Arabia

    M. Rafiq H. Siddiqui & Abdulrahman A. Alwarthan

  3. Chemical Sciences and Engineering Division, Argonne National Laboratory, Argonne, IL, 60439, USA

    Christopher L. Marshall

Authors
  1. M. Ishaque Khan
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  2. Kadir Aydemir
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  3. M. Rafiq H. Siddiqui
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  4. Abdulrahman A. Alwarthan
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  5. Christopher L. Marshall
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Correspondence to M. Ishaque Khan.

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Khan, M.I., Aydemir, K., Siddiqui, M.R.H. et al. Oxidative Dehydrogenation Properties of Novel Nanostructured Polyoxovanadate Based Materials. Catal Lett 141, 538–543 (2011). https://doi.org/10.1007/s10562-011-0547-9

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  • DOI: https://doi.org/10.1007/s10562-011-0547-9

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