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Cu Nanoparticles in Ionic Liquid: An Easy and Efficient Catalyst for Addition–Elimination Reaction Between Active Methylene Compounds and Imines in an Ionic Liquid

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Abstract

Here, we report a novel preparation of copper nanoparticles in ionic liquid and its use in the addition elimination reaction. Powder X-ray diffraction, transmission electron microscopy and quassi elastic light scattering techniques revealed the formation and size of copper nanoparticles and its use for the addition–elimination reaction between active methylene compounds and imines using an ionic liquid in presence of NEt3 to yield the corresponding products in high yields and in short duration was done.

Graphical Abstract

Here, we report a novel preparation of copper nanoparticles in ionic liquid and its use in the addition elimination reaction. Powder X-ray diffraction, transmission electron microscopy and quassi eleastic light scattering techniques revealed the formation and size of copper nanoparticles and its use for the addition–elimination reaction between active methylene compounds and imines using an ionic liquid in presence of NEt3 to yield the corresponding products in high yields and in short duration was done.

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References

  1. Arana J, De la Piscina PR, Llorca J, Sales J, Homs N, Fierro ILG (2006) Chem Mater 10:1333

    Article  Google Scholar 

  2. Majetich SA, Jin Y (1999) Science 284:470

    Article  CAS  Google Scholar 

  3. Black CT, Murray CB, Sandstrom RL, Sun SH (2000) Science 290:1131

    Article  CAS  Google Scholar 

  4. Gittins DL, Bethell D, Schiffrin DJ, Nichols RJ (2000) Nature 408:67

    Article  CAS  Google Scholar 

  5. Simon U, Flesch R, Wiggers H, Scho¨n G, Schmid G (1998) J Mater Chem 8:517

    Article  CAS  Google Scholar 

  6. Andres RP, Bielefeld JD, Henderson JI, Janes DB, Kolagunta VR, Kubiak CP, Mahoney WJ, Osifchin RG (1996) Science 273:1690

    Article  CAS  Google Scholar 

  7. Rodrı′guez-Sa′nchez L, Blanco MC, Lo′pez-Quintela MA (2000) J Phys Chem B 104:9683

    Article  Google Scholar 

  8. Kurihara K, Kizling J, Stenius P, Fendler JH (1983) J Am Chem Soc 105:2574

    Article  CAS  Google Scholar 

  9. Henglein M, Giersig M (1994) J Phys Chem 98:6931

    Article  CAS  Google Scholar 

  10. Wu ML, Chen DH, Huang TC (2001) Langmuir 17:3877

    Article  CAS  Google Scholar 

  11. Yang S, Liu Q, Kauzlarich SM (2000) Chem Mater 12:983

    Article  CAS  Google Scholar 

  12. Ayyappan S, Gopalan RS, Subbanna GN, Rao CNR (1997) J Mater Res 1:398

    Article  Google Scholar 

  13. Singh P, Katyal A, Kalra R, Chandra R (2008) Mat Lett 62:4164

    Article  CAS  Google Scholar 

  14. Singh P, Katyal A, Kalra R, Chandra R (2008) Tet Lett 49:727

    Article  CAS  Google Scholar 

  15. Singh P, Katyal A, Kalra R, Chandra R (2008) Cat Comm 9:1618

    Article  CAS  Google Scholar 

  16. Singh P, Kumari K, Katyal A, Kalra R, Chandra R (2009) Cat Lett 127:119–124

    Article  CAS  Google Scholar 

  17. Singh P, Kumari K, Katyal A, Kalra R, Chandra R (2009) Spectrochim Acta A (accepted)

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Acknowledgments

This work is dedicated to late Dr. N.N. Ghosh, my mentor and my guide (Prashant Singh)

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Correspondence to Ramesh Chandra.

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Singh, P., Kumari, K., Katyal, A. et al. Cu Nanoparticles in Ionic Liquid: An Easy and Efficient Catalyst for Addition–Elimination Reaction Between Active Methylene Compounds and Imines in an Ionic Liquid. Catal Lett 130, 648–654 (2009). https://doi.org/10.1007/s10562-009-9944-8

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  • DOI: https://doi.org/10.1007/s10562-009-9944-8

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