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Synthesis of Biodiesel via Deoxygenation of Stearic Acid over Supported Pd/C Catalyst

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Abstract

High catalytic activity was achieved in the deoxygenation of stearic acid in dodecane in a temperature range of 270–300 °C under 17 bar helium over palladium on nanocomposite carbon Sibunit. Besides n-heptadecane, which was obtained previously in this reaction with palladium on activated carbon, n-pentadecane was also formed in significant amounts.

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References

  1. Ramadhas AS, Jayaraj S, Muraleedharan C (2004) Renew Energy 29:727

    Article  CAS  Google Scholar 

  2. Addison K Oil yields and characteristics. Journey to forever http://journeytoforever.org/biodiesel_yield.html. Accessed 14 Feb 2008

  3. Ghadge SV, Raheman H (2005) Biomass Bioenergy 28:601

    Article  CAS  Google Scholar 

  4. Gübitz GM, Mittelbach M, Trabi M (1999) Bioresour Technol 67:73

    Article  Google Scholar 

  5. Giannelos PN, Zannikos F, Stournas S, Lois E, Anastopoulos G (2002) Ind Crops Prod 16:1

    Article  CAS  Google Scholar 

  6. Snåre M, Murzin D Yu (2006) Ind Eng Chem Res 45:6875

    Article  CAS  Google Scholar 

  7. Murzin D Yu, Kubickova I, Snåre M, Mäki-Arvela P, Myllyoja J (2006) Method for the manufacture of hydrocarbons, WO 2006075057, p 21

  8. Kubickova I, Snåre M, Eränen K, Mäki-Arvela P, Murzin D Yu (2005) Catal Today 106:197

    Article  CAS  Google Scholar 

  9. Mäki-Arvela P, Kubickova I, Eränen K, Snåre M, Murzin D Yu (2007) Energy Fuels 21:30

    Article  CAS  Google Scholar 

  10. Snåre M, Kubickova I, Mäki-Arvela P, Eränen K, Murzin D Yu (2006) Ind Eng Chem Res 45:5708

    Article  CAS  Google Scholar 

  11. Snåre M, Kubickova I, Mäki-Arvela P, Eränen K, Wärnå J, Murzin D Yu (2007) Chem Eng J 134:29

    Article  CAS  Google Scholar 

  12. Snåre M, Kubickova I, Mäki-Arvela P, Chichova D, Eränen K, Murzin D Yu (2008) Fuel 87:933

    Article  CAS  Google Scholar 

  13. Lima DG, Soares VCV, Ribeiro EB, Caravalho DA, Cardoso ECV, Rassi FC, Mundim KC, Rubim JC, Suarez PAZ (2004) J Anal Appl Pyrol 71:987

    Article  CAS  Google Scholar 

  14. Demirbas A (2005) Prog Energy Comb Sci 31:466

    Article  CAS  Google Scholar 

  15. Simonov PA, Troitskii S Yu, Likholobov VA (2000) Kinet Catal 41:255

    CAS  Google Scholar 

  16. Gurrath M, Kuretzky T, Boehm HP, Okhlopkova LB, Lisitsyn VA, Likholobov VA (2000) Carbon 38:1241

    Article  CAS  Google Scholar 

  17. Markus H, Plomp AJ, Mäki-Arvela P, Bitter JH, Murzin D Yu (2007) Catal Lett 113:141

    Article  CAS  Google Scholar 

  18. Dubois V, Dal Y, Jannes G (2000) Studies in surface science and catalysis, in scientific bases for the preparation of heterogeneous catalysts. In: Gaigneaux E, Grange P, Jacobs PA, Martens JA, Ruiz P, Poncelet G (eds) Proceedings of the 8th international symposium, Elsevier, pp 993–1002

  19. Murphy MJ, Taylor JD, McCormick RL (2004) Compendium of experimental cetane number data. National Renewable Energy Laboratory, Colorado, pp 1–48 NREL/SR-540-36805

    Google Scholar 

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Correspondence to Dmitry Yu Murzin.

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Lestari, S., Simakova, I., Tokarev, A. et al. Synthesis of Biodiesel via Deoxygenation of Stearic Acid over Supported Pd/C Catalyst. Catal Lett 122, 247–251 (2008). https://doi.org/10.1007/s10562-008-9457-x

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  • DOI: https://doi.org/10.1007/s10562-008-9457-x

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