Skip to main content
Log in

Investigation of Acid Characteristics of Oxo Complex Catalysts of Isomerization of Pentane—Hexane Fractions

  • KINETICS AND CATALYSIS
  • Published:
Chemistry and Technology of Fuels and Oils Aims and scope

A new catalyst, based on newly synthesized inorganic superacids, was developed for the isomerization of light hydrocarbons. A series of mixed heteropoly anions with a modified Keggin structure containing different transition metals (including platinum group metals) were synthesized for this purpose. The technology for the production of superacidic catalysts with a coating of modified heteropoly complexes of the Keggin series on different supports was developed. The Brønsted and Lewis acid sites of the developed superacidic oxo complex catalyst deposited on various supports were investigated.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1.
Fig. 2.
Fig. 3.
Fig. 4.
Fig. 5.
Fig. 6.
Fig. 7.

Similar content being viewed by others

References

  1. US Patent No. 6297418.

  2. A. N. Shakun, M. L. Fëdorova, Kataliz. v Promyshlennosti, No. 5, 29-37 (2014).

  3. Xuebing Li, J. A. Lercher, Journal of Catalysis, 229, 130-137 (2004).

  4. R. Silva-Rodrigo, E. L. Cruz-Dominguez. F. E. Lugo-del Angel. et al., Catalysis Today,250, 197-208 (2015).

  5. Hua Song, Na Wang, Hua-Lin Song, et al., Catalysis Communications, 59, 61-64 (2015).

  6. Yuandong Xu, Xia Zhang, Hongling Li, Catal. Lett., No. 125, 340-347 (2008).

  7. Yuandong Xu, Xia Zhang, Hongling Li, Catal. Lett., No. 129, 215-221 (2009).

  8. K. R. Gazarov, S. V. Meshcheryakov, Tekhnologiya Nefti i Gaza, No. 6, 13 (2012).

  9. K. R. Gazarov, S. V. Meshcheryakov, R. A. Gazarov, Zashchita Okruzhayushchei Sredy v Neftegazovom. Komplekse, No. 4, 46-49 (2017).

  10. T. Lei, J S. Xu, Z. Gao, Chemistry Letters, 2, 509-511(1999).

  11. A. V. Kiselev, V. I. Lygin, Infrared Spectra of Surface Compound, Nauka, Moscow (1975), p. 175.

  12. A. S. Medin, V. Yu. Borovkov, V. B. Kazansky, Zeolites, 10, 668 (1990).

  13. L. M. Kystov, Topics in Catal., 4, 131-144 (1997).

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to R. A. Gazarov.

Additional information

Translated from Khimiya i Tekhnologiya Topliv i Masel, No. 6, pp. 7 — 12, November —December, 2018.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Gazarov, R.A., Meshcheryakov, S.V., Gazarov, K.R. et al. Investigation of Acid Characteristics of Oxo Complex Catalysts of Isomerization of Pentane—Hexane Fractions. Chem Technol Fuels Oils 54, 676–685 (2019). https://doi.org/10.1007/s10553-019-00975-0

Download citation

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10553-019-00975-0

Key words

Navigation